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Article Navigation >  Green Energy&Environment  > 2016  >  1(2): 149-155
Kiyotaka Sugawara, Naoshi Nakamura, Yu Yamane, Shuichi Hayase, Toshiki Nokami, Toshiyuki Itoh. Influence of chirality on the cyclohexene-fused C60 fullerene derivatives as an accepter partner in a photovoltaic cell. Green Energy&Environment, 2016, 1(2): 149-155. doi: 10.1016/j.gee.2016.07.004
Citation: Kiyotaka Sugawara, Naoshi Nakamura, Yu Yamane, Shuichi Hayase, Toshiki Nokami, Toshiyuki Itoh. Influence of chirality on the cyclohexene-fused C60 fullerene derivatives as an accepter partner in a photovoltaic cell. Green Energy&Environment, 2016, 1(2): 149-155. doi: 10.1016/j.gee.2016.07.004
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Influence of chirality on the cyclohexene-fused C60 fullerene derivatives as an accepter partner in a photovoltaic cell

doi: 10.1016/j.gee.2016.07.004
  • a.

    Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University, 4-101 Koyama-Minami, Tottori 680-8552, Japan

  • b.

    Center for Research on Green Sustainable Chemistry, Tottori University, 4-101 Koyama-Minami, Tottori 680-8552, Japan

More Information
  • Corresponding author: E-mail address: titoh@chem.tottori-u.ac.jp (Toshiyuki Itoh)
  • Received date 27 May 2016, Accepted date 22 July 2016, RevRecd date 22 July 2016, Available online 29 July 2016, Publish date 31 July 2016,
    Abstract
  • Organic photovoltaic devices (OPVs) using chiral cyclohexene-fused [C60]-fullerene derivatives that have (l)-menthyl ester moiety have been prepared and their properties evaluated as acceptor molecules with P3HT polymer: racemic cyclohexene-fused [C60] fullenene, (RS)-(1R,2S,5R)- 2a showed higher PCE (2.81%) than that of standard [C60]-PCBM (2.64%) under the same analysis conditions. On the contrary, devices using chiral (R)-(1R,2S,5R)- 2a and (S)-(1R,2S,5R)- 2a , showed PCE as 1.08% and 1.10%, respectively. The main origin of the differences in PCE was found to be their poor JSC values. The results indicate that the aggregation state might influence the interaction state with P3HT and impact the results of the OPV properties, JSC values in particular.

     

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