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Article Navigation >  Green Energy&Environment  > 2017  >  2(1): 51-57
Jacqueline González González, Mónica Nájera-Lara, Varinia López-Ramírez, Juan Antonio Ramírez-Vázquez, José J.N. Segoviano-Garfias. Spectrophotometric determination of the formation constants of Calcium(II) complexes with 1,2-ethylenediamine, 1,3-propanediamine and 1,4-butanediamine in acetonitrile. Green Energy&Environment, 2017, 2(1): 51-57. doi: 10.1016/j.gee.2017.01.002
Citation: Jacqueline González González, Mónica Nájera-Lara, Varinia López-Ramírez, Juan Antonio Ramírez-Vázquez, José J.N. Segoviano-Garfias. Spectrophotometric determination of the formation constants of Calcium(II) complexes with 1,2-ethylenediamine, 1,3-propanediamine and 1,4-butanediamine in acetonitrile. Green Energy&Environment, 2017, 2(1): 51-57. doi: 10.1016/j.gee.2017.01.002
shu

Spectrophotometric determination of the formation constants of Calcium(II) complexes with 1,2-ethylenediamine, 1,3-propanediamine and 1,4-butanediamine in acetonitrile

doi: 10.1016/j.gee.2017.01.002
  • a.

    Programa de Maestría en Biociencias, División de Ciencias de la Vida (DICIVA), Universidad de Guanajuato, Campus Irapuato-Salamanca, Ex Hacienda El Copal, Carretera Irapuato-Silao Km. 9, Irapuato, Gto., 36500, Mexico

  • b.

    Colegio del Nivel Medio Superior de Salamanca (ENMS), Prolongación Tampico No. 904, Salamanca, Gto., 36730, Mexico

  • c.

    Departamento de Ingeniería Bioquímica, Instituto Tecnológico Superior de Irapuato (ITESI), Carretera Irapuato-Silao Km. 12.5, Irapuato, Gto., 36821, Mexico

  • d.

    Departamento de Ciencias Ambientales, División de Ciencias de la Vida (DICIVA), Universidad de Guanajuato, Campus Irapuato-Salamanca, Ex Hacienda El Copal, Carretera Irapuato-Silao Km. 9, Irapuato, Gto., 36500, Mexico

More Information
  • Corresponding author: E-mail address: jose.segoviano@gmail.com (José J.N. Segoviano-Garfias)
  • Received date 07 July 2016, Accepted date 09 January 2017, RevRecd date 07 January 2017, Available online 18 January 2017, Publish date 31 January 2017,
    Abstract
  • In this work, with the purpose to explore the coordination chemistry of calcium complexes which could work as a partial model of manganese–calcium cluster, a spectrophotometric study to evaluate the stability of the complexes: Calcium(II)-1,2-ethylendiamine, Calcium(II)-1,3-propanediamine and Calcium(II)-1,4-butanediamine in acetonitrile, were carried on. By processing the spectrophotometric data with the HypSpec program allows the determination of the formation constants. The logarithmic values of the formation constants obtained for Calcium(II)-1,2-ethylendiamine, Calcium(II)-1,3-propanediamine and Calcium(II)-1,4-butanediamine were log β110 = 4.69, log β110 = 5.25 and log β110 = 4.072, respectively.

     

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