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Qi Hao, Yijun Liu, Ren Zou, Ge Shi, Shilian Yang, Linxin Zhong, Wu Yang, Xiao Chi, Yunpeng Liu, Shimelis Admassie, Xinwen Peng. g-C3N4 nanosheets coupled with CoSe2 as co-catalyst for efficient photooxidation of xylose to xylonic acid. Green Energy&Environment. doi: 10.1016/j.gee.2024.04.004
Citation: Qi Hao, Yijun Liu, Ren Zou, Ge Shi, Shilian Yang, Linxin Zhong, Wu Yang, Xiao Chi, Yunpeng Liu, Shimelis Admassie, Xinwen Peng. g-C3N4 nanosheets coupled with CoSe2 as co-catalyst for efficient photooxidation of xylose to xylonic acid. Green Energy&Environment. doi: 10.1016/j.gee.2024.04.004
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g-C3N4 nanosheets coupled with CoSe2 as co-catalyst for efficient photooxidation of xylose to xylonic acid

doi: 10.1016/j.gee.2024.04.004

  • a State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510641, Guangdong, China;

  • b Hainan Key Laboratory of Storage&processing of fruits and vegetables, Agricultural Products Processing Research Institute, Chinese Academy of Tropical Agricultural Sciences, Zhanjiang, Guangdong 524001, China;

  • c Department of Chemistry and Centre for Advanced 2D Materials(CA2DM) National University of Singapore 3 Science Drive 3, Singapore 117543, Singapore;

  • d School of Materials Science and Hydrogen Energy, Foshan University, Foshan 528231, Guangdong, China;

  • e Department of Chemistry Addis Ababa University PO BOX 1176, Addis Ababa Ethiopia

Funds:

This work was supported by National Natural Science Foundation of China(52003083, 31971614, 21736003, 32201499 and 32071714), National Program for Support of Top-notch Young Professionals (x2qsA4210090),Hainan Key Laboratory of Storage & Processing of Fruits and Vegetables (HNGS202102),State Key Laboratory of Pulp and Paper Engineering (Grant No. 2022PY02),Outstanding Youth Team Project of Guangdong Natural Science Foundation. (Grant No. 2023B1515040013),Fundamental Research Funds for the Central Universities (Grant No. 2022ZYGXZR019),Guangdong Basic and Applied Basic Research Foundation (Grant No. 2021A1515110205, 2022A1515011801).

  • Received date 22 October 2023, Accepted date 09 April 2024, RevRecd date 20 March 2024, Available online 24 April 2024
    Abstract
  • Photocatalysis has emerged as an effective approach to sustainably convert biomass into value-added products. CoSe2 is a promising non-precious, efficient cocatalyst for photooxidation, which can facilitate the separation of photogenerated electron-holes, increase the reaction rates, and enhance photocatalytic efficiency. In this work, we synthesized a stable and efficient photocatalysis system of CoSe2/g-C3N4 through attaching CoSe2 on g-C3N4 sheets, with a yield of 50.12 % for the selective photooxidation of xylose to xylonic acid. Under light illumination, the photogenerated electrons were prone to migrating from g-C3N4 to CoSe2 due to the higher work function of CoSe2, resulting in the accelerated separation of photogenerated electron-holes and the promoted photooxidation. Herein, this study reveals the unique function of CoSe2, which can significantly promote oxygen adsorption, work as an electron sink and accelerate the generation of · O2-, thereby improving the selectivity toward xylonic acid over other by-products. This work provides useful insights into the design of selective photocatalysts by engineering g-C3N4 for biomass high-value utilization.

     

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