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Yan Liu, Zhen-Yi Gu, Yong-Li Heng, Jin-Zhi Guo, Miao Du, Hao-Jie Liang, Jia-Lin Yang, Kai-Yang Zhang, Kai Li, Xing-Long Wu. Interface defect induced upgrade of K-storage properties in KFeSO4F cathode: from lowered Fe-3d orbital energy level to advanced potassium-ion batteries. Green Energy&Environment. doi: 10.1016/j.gee.2023.10.004
Citation: Yan Liu, Zhen-Yi Gu, Yong-Li Heng, Jin-Zhi Guo, Miao Du, Hao-Jie Liang, Jia-Lin Yang, Kai-Yang Zhang, Kai Li, Xing-Long Wu. Interface defect induced upgrade of K-storage properties in KFeSO4F cathode: from lowered Fe-3d orbital energy level to advanced potassium-ion batteries. Green Energy&Environment. doi: 10.1016/j.gee.2023.10.004
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Interface defect induced upgrade of K-storage properties in KFeSO4F cathode: from lowered Fe-3d orbital energy level to advanced potassium-ion batteries

doi: 10.1016/j.gee.2023.10.004

  • 1. MOE Key Laboratory for UV Light-Emitting Materials and Technology, Northeast Normal University, Changchun, Jilin 130024, P. R. China;

  • 2. Faculty of Chemistry, Northeast Normal University, Changchun, Jilin 130024, P. R. China;

  • 3. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China

Funds:

The authors gratefully acknowledge the financial support from the National Key R&D Program of China (Grant No.2023YFE0202000), National Natural Science Foundation of China (Grant No. 52102213), Science Technology Program of Jilin Province (Grant No. 20230101128JC). The computational time is supported by the High Performance Computing Center of Jilin Province.

  • Received date 11 August 2023, Accepted date 08 October 2023, RevRecd date 20 September 2023, Available online 12 October 2023
    Abstract
  • KFeSO4F (KFSF) is considered a potential cathode due to the large capacity and low cost. However, the inferior electronic conductivity leads to poor electrochemical performance. Defect engineering can facilitate the electron/ion transfer by tuning electronic structure, thus providing favorable electrochemical performance. Herein, through the regulation of surface defect engineering in reduced graphene oxide (rGO), the Fe-C bonds were formed between KFSF and rGO. The Fe-C bonds formed work in regulating the Fe-3d orbital as well as promoting the migration ability of K ions and increasing the electronic conductivity of KFSF. Thus, the KFSF@rGO delivers a high capacity of 119.6 mAh g-1. When matched with a graphite@pitch-derived S-doped carbon anode, the full cell delivers an energy density of 250.5 Wh kg-1 and a capacity retention of 81.5% after 400 cycles. This work offers a simple and valid method to develop high-performance cathodes by tuning defect sites.

     

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