Volume 9 Issue 7
Jul.  2024
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Article Navigation >  Green Energy&Environment  > 2024  >  9(7): 1112-1121
Yajie Bai, Zhenyuan Fang, Yong Lei, Lijing Liu, Huaiquan Zhao, Hongye Bai, Weiqiang Fan, Weidong Shi. FCF-LDH/BiVO4 with synergistic effect of physical enrichment and chemical adsorption for efficient reduction of nitrate. Green Energy&Environment, 2024, 9(7): 1112-1121. doi: 10.1016/j.gee.2023.05.011
Citation: Yajie Bai, Zhenyuan Fang, Yong Lei, Lijing Liu, Huaiquan Zhao, Hongye Bai, Weiqiang Fan, Weidong Shi. FCF-LDH/BiVO4 with synergistic effect of physical enrichment and chemical adsorption for efficient reduction of nitrate. Green Energy&Environment, 2024, 9(7): 1112-1121. doi: 10.1016/j.gee.2023.05.011
shu

FCF-LDH/BiVO4 with synergistic effect of physical enrichment and chemical adsorption for efficient reduction of nitrate

doi: 10.1016/j.gee.2023.05.011

  • a. School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, China;

  • b. Institute of Physics & IMN MacroNano, Technische Universitä

  • t Ilmenau, Ilmenau, 98693, Germany;

  • c. School of Chemistry, Beihang University, Beijing, 100191, China

Funds:

The authors are grateful for National Natural Science Foundation of China (22075112), Jiangsu Province and Education Ministry Co-Sponsored Synergistic Innovation Center of Modern Agricultural Equipment (XTCX2027), Jiangsu Province Innovation Support Program International Science and Technology Cooperation Project (BZ2022045).

  • Received date 17 January 2023, Accepted date 29 May 2023, RevRecd date 28 April 2023, Available online 18 June 2024, Publish date 31 July 2024,
    Abstract
  • Photoelectrochemical NO3- reduction (PEC NITRR) not only provides a promising solution for promoting the global nitrogen cycle, but also converts NO3- to the important chemicals (NH3). However, it is still a great challenge to prepare catalysts with excellent NO3- adsorption/activation capacity to achieve high NITRR. Herein, we designed a novel Fe2+Cu2+Fe3+LDH/BiVO4 (FCF-LDH/BVO) catalyst with synergistic effect of chemical adsorption and physical enrichment. Fe2+ in FCF-LDH/BVO provides the rich Lewis acid sites for the adsorption of NO3-, and the appropriate layer spacing of FCF-LDH further promotes the physical enrichment of NO3- in its interior, thus realizing the effective contact between NO3- and active sites (Fe2+). FCF-LDH/BVO showed excellent NH3 production performance (FENH3= 66.1%, rNH3 = 13.8 μg h-1 cm-2) and selectivity (FENO2- = 2.5%, rNO2- = 4.9 μg h-1 cm-2) in 0.5 mol L-1 Na2SO4 electrolyte. In addition, FCF-LDH/BVO maintains the desirable PEC stability for six cycle experiments, showing great potential for practical application. The 14NO3- and 15NO3- isotope test provides strong evidence for further verification of the origin of N in the generated NH3. This LDH catalyst has a great potential in PEC removal of NO3- from groundwater.

     

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