Volume 9 Issue 3
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Long Cheng, Yuanhui Ji. Photocatalytic activation of sulfite by N-doped porous biochar/MnFe2O4 interface-driven catalyst for efficient degradation of tetracycline. Green Energy&Environment, 2024, 9(3): 481-494. doi: 10.1016/j.gee.2022.07.006
Citation: Long Cheng, Yuanhui Ji. Photocatalytic activation of sulfite by N-doped porous biochar/MnFe2O4 interface-driven catalyst for efficient degradation of tetracycline. Green Energy&Environment, 2024, 9(3): 481-494. doi: 10.1016/j.gee.2022.07.006
shu

Photocatalytic activation of sulfite by N-doped porous biochar/MnFe2O4 interface-driven catalyst for efficient degradation of tetracycline

doi: 10.1016/j.gee.2022.07.006

  • Jiangsu Province Hi-Tech Key Laboratory for Biomedical Research, School of Chemistry and Chemical Engineering, Southeast University, Nanjing, 211189, China

Funds:

The authors gratefully acknowledge the financial support for this research from the National Natural Science Foundation of China (Grant No.: 21978047, 21776046), and the Six Talent Climax Foundation of Jiangsu (Grant No.: XCL-079). We thank Dr. Defang Ouyang in University of Macau for providing the software support on the numerical calculations in this paper.

  • Received date 25 April 2022, Accepted date 22 July 2022, RevRecd date 02 July 2022, Publish date 13 August 2022,
    Abstract
  • A novel photo-catalytic system composed of N-doped biochars (NBCs), MnFe2O4 and sulfite activation under ultraviolet (NBCs/MnFe2O4/sulfite/UV) was constructed to realize the efficient eliminate of tetracycline (TC). As the carrier of MnFe2O4, NBCs were synthesized from alfalfa, which has large specific surface area, graphite like structure and hierarchical porous structure. The adsorption isotherm indicated that NBCs/MnFe2O4-2:1 had the best adsorption performance for TC (347.56 mg g-1). Through synergistic adsorption and photocatalysis, the removal rate of TC reached 84%, which was significantly higher than that of MnFe2O4. Electrochemical impedance spectroscopy (EIS) and Photoluminescence (PL) characterization results showed that the introduction of NBCs improved the separation efficiency of photogenerated electron and hole pairs and enhanced the photocatalytic performance. Moreover, the adsorption, degradation mechanism and degradation path of TC by the catalyst were systematically analyzed by coupling HPLC–MS measurement with the theoretical calculation. Considering the advantages of excellent degradation performance, low cost, easy separation and environmental friendliness of NBCs/MnFe2O4, this work was expected to provide a new path for the practical application of biochar.

     

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