Volume 9 Issue 2
Feb.  2024
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Article Navigation >  Green Energy&Environment  > 2024  >  9(2): 311-320
Rui Li, Qixuan Lin, Junli Ren, Xiaobao Yang, Yingxiong Wang, Lingzhao Kong. Dealuminated Hβ zeolite for selective conversion of fructose to furfural and formic acid. Green Energy&Environment, 2024, 9(2): 311-320. doi: 10.1016/j.gee.2022.06.003
Citation: Rui Li, Qixuan Lin, Junli Ren, Xiaobao Yang, Yingxiong Wang, Lingzhao Kong. Dealuminated Hβ zeolite for selective conversion of fructose to furfural and formic acid. Green Energy&Environment, 2024, 9(2): 311-320. doi: 10.1016/j.gee.2022.06.003
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Dealuminated Hβ zeolite for selective conversion of fructose to furfural and formic acid

doi: 10.1016/j.gee.2022.06.003

  • a. State Key Laboratory of Pulp and Paper Engineering, School of Light Industry and Engineering, South China University of Technology, Guangzhou, 510640, China;

  • b. Institute of Coal Chemistry, Chinese Academy of Sciences, 27 South Taoyuan Road, Taiyuan, 030001, China;

  • c. CAS Key Laboratory of Low-Carbon Conversion Science and Engineering, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai, 201210, China;

  • d. School of Environmental Science and Technology Suzhou University of Science and Technology Suzhou, Jiangsu, 215009, China

Funds:

This work was supported by Program for National Natural Science Foundation of China (Nos. 22178135, 21978104 and 22278419), the National Key Research and Development Program of China (No. 2021YFC2101601). The authors would like to thank Shiyanjia Lab (www.Shiyanjia.com) for the support of TPD test.

  • Received date 09 April 2022, Accepted date 07 June 2022, RevRecd date 23 May 2022, Publish date 11 June 2022,
    Abstract
  • The fructose-to-furfural transformation is facing major challenges in the selectivity and high efficiency. Herein, we have developed a simple and effective approach for the selective conversion of fructose to furfural using Hβ zeolite modified by organic acids for dealuminization to regulate its textural and acidic properties. It was found that citric acid-dealuminized Hβ zeolite possessed high specific surface areas, wide channels and high Brønsted acid amount, which facilitated the selective conversion of fructose to furfural with a maximum yield of 76.2% at 433 K for 1 h in the γ-butyrolactone (GBL)-H2O system, as well as the concomitant formation of 83.0% formic acid. The 13C-isotope labelling experiments and the mechanism revealed that the selective cleavage of C1–C2 or C5–C6 bond on fructose was firstly occurred to form pentose or C5 intermediate by weak Brønsted acid, which was then dehydrated to furfural by strong Brønsted acid. Also this dealuminized Hβ catalyst showed the great recycling performance and was active for the conversion of glucose and mannose.

     

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