Volume 8 Issue 4
Aug.  2023
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Article Navigation >  Green Energy&Environment  > 2023  >  8(4): 1102-1116
Yanqin Li, Junqi Tian, Zhisong Liu, Zhongqi Liu, Dong Dong, Fu Wang, Wei Wang, Minmin Liu, Jianming Dan, Yongsheng Li, Feng Yu, Bin Dai, Yunbo Yu. Robust photo-assisted removal of NO at room temperature: Experimental and density functional theory calculation with optical carrier. Green Energy&Environment, 2023, 8(4): 1102-1116. doi: 10.1016/j.gee.2022.01.004
Citation: Yanqin Li, Junqi Tian, Zhisong Liu, Zhongqi Liu, Dong Dong, Fu Wang, Wei Wang, Minmin Liu, Jianming Dan, Yongsheng Li, Feng Yu, Bin Dai, Yunbo Yu. Robust photo-assisted removal of NO at room temperature: Experimental and density functional theory calculation with optical carrier. Green Energy&Environment, 2023, 8(4): 1102-1116. doi: 10.1016/j.gee.2022.01.004
shu

Robust photo-assisted removal of NO at room temperature: Experimental and density functional theory calculation with optical carrier

doi: 10.1016/j.gee.2022.01.004

  • a. Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical Engineering, Shihezi University, Shihezi, 832003, China;

  • b. Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, 100085, China;

  • c. FermiTech (Beijing) Co. Ltd., Beijing, 100083, China;

  • d. School of Biomedical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, China;

  • e. Lab of Low-Dimensional Materials Chemistry, Key Laboratory for Ultrafine Materials of Ministry of Education, Shanghai Engineering Research Center of Hierarchical Nanomaterials, School of Materials Science and Engineering, East China University of Science & Technology, Shanghai, 200237, China;

  • f. Bingtuan Industrial Technology Research Institute, Shihezi University, Shihezi, 832003, China

Funds:

The work was supported by Science and Technology Innovation Talents Program of Bingtuan (No. 2019CB025), Major Scientific and Technological Project of Bingtuan (No. 2018AA002) and Project of Regional Innovation in Bingtuan (No. 2021BB005).

  • Received date 05 October 2021, Accepted date 09 January 2022, RevRecd date 28 December 2021, Available online 07 July 2023, Publish date 14 January 2022,
    Abstract
  • Photo-assisted SCR (PSCR) offers a potential solution for removal of NO at room temperature. MnTiOx as PSCR catalyst exhibits superior performance with NO removal of 100% at the room temperature. Electron paramagnetic resonance (EPR) analysis revealed the presence of numerous oxygen vacancies on MnTiOx. Optical carrier density functional theory (DFT) calculations showed that the three-dimensional orbital hybridization of Mn and Ti is significantly enhanced under light irradiation. The MnTiOx catalyst exhibited excellent electron–hole separation ability, which can adsorbe NH3 and dissociate to form NH2 fragments and H atoms. In-situ diffuse reflectance infrared fourier-transform spectroscopy (DRIFTS) indicated that the optical carrier enhanced NH3 adsorption on MnTiOx, which makes it possess excellent PSCR activity. This work provided an additional strategy to NO removal with PSCR catalysts and showed potential for use in photocatalysis.

     

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