Volume 8 Issue 3
Jul.  2023
Turn off MathJax
Article Contents
Article Navigation >  Green Energy&Environment  > 2023  >  8(3): 785-797
Weiyao Yang, Mengchen Fu, Chenyu Yang, Yiwen Zhang, Chun Shen. Auδ--Ov-Ti3+: Active site of MOx-Au/TiO2 catalysts for the aerobic oxidation of 5-hydroxymethylfurfural. Green Energy&Environment, 2023, 8(3): 785-797. doi: 10.1016/j.gee.2021.09.006
Citation: Weiyao Yang, Mengchen Fu, Chenyu Yang, Yiwen Zhang, Chun Shen. Auδ--Ov-Ti3+: Active site of MOx-Au/TiO2 catalysts for the aerobic oxidation of 5-hydroxymethylfurfural. Green Energy&Environment, 2023, 8(3): 785-797. doi: 10.1016/j.gee.2021.09.006
shu

Auδ--Ov-Ti3+: Active site of MOx-Au/TiO2 catalysts for the aerobic oxidation of 5-hydroxymethylfurfural

doi: 10.1016/j.gee.2021.09.006

  • a. Beijing Key Laboratory of Bioprocess, College of Life Science and Technology, Beijing University of Chemical Technology, No. 15 of North Three-Ring East Road, Chaoyang District, Beijing, 100029, China;

  • b. The State Key Laboratory of Chemical Engineering, Department of Chemical Engineering, Tsinghua University, Beijing, 100084, China

Funds:

We gratefully acknowledge the support of State Key Laboratory of Chemical Engineering (No. SKL-ChE-20A02), and the support of International Clean Energy Talent Program by China Scholarship Council.

  • Received date 31 May 2021, Accepted date 27 September 2021, RevRecd date 04 September 2021, Publish date 31 July 2023,
    Abstract
  • Despite wide applications of noble metal-based catalysts in 5-hydroxymethylfurfural (HMF) oxidation, promoting the catalytic performance at low loading amounts still remains a significant challenge. Herein, a series of metal oxide modified MO-Au/TiO2 (M = Fe, Co, Ni) catalysts with low Au loading amount of 0.5 wt% were synthesized. Addition of transition metal oxides promotes electron transfer and generation of the Au-Ov-Ti3+ interface. A combination study reveals that the dual-active site (Au-Ov-Ti3+) governs the catalytic performance of the rate-determining step, namely hydroxyl group oxidation. Au site facilitates chemisorption and activation of O2 molecules. At the same time, Ov-Ti3+ site acts as the role of “killing two birds with one stone”: enhancing adsorption of both reactants, accelerating the activation and dissociation of H2O, and facilitating activation of the adsorbed O2. Besides, superoxide radicals instead of base is the active oxygen species during the rate-determining step. On this basis, a FDCA yield of 71.2% was achieved under base-free conditions, complying with the “green chemistry” principle. This work provides a new strategy for the transition metal oxides modification of Au-based catalysts, which would be constructive for the rational design of other heterogeneous catalysts.

     

    • FullText(HTML)
  • loading
    • References(72)
  • [1]
    Y. Jing, Y. Guo, Q. Xia, X. Liu, Y. Wang. Chem. 5 (2019) 2520-2546.
    [2]
    P. Sudarsanam, R. Zhong, S. Van Den Bosch, S.M. Coman, V.I. Parvulescu, B.F. Sels. Chem. Soc. Rev. 47 (2018) 8349-8402.
    [3]
    M. Sajid, X. Zhao, D. Liu. Green Chem. 20 (2018) 5427-5453.
    [4]
    T. Su, Q. Liu, H. Lu, F. Ali Alasmary, D. Zhao, C. Len. Mol. Catal. 502 (2021) 111374.
    [5]
    D. Zhao, D. Rodriguez-Padron, R. Luque, C. Len. ACS Sustain. Chem. Eng. 8 (2020) 8486-8495.
    [6]
    Z. Zhang, K. Deng. ACS Catal. 5 (2015) 6529-6544.
    [7]
    S. Hameed, L. Lin, A. Wang, W. Luo. Catalysts 10 (2020) 120-145.
    [8]
    T. Su, D. Zhao, Y. Wang, L. Hongying, R.S. Varma, C. Len. ChemSusChem 14 (2021) 266-280.
    [9]
    D. Zhao, D. Rodriguez-Padron, K. S. Triantafyllidis, Y. Wang, R. Luque, C. Len. ACS Sustain. Chem. Eng. 8 (2020) 3091-3102.
    [10]
    D. Zhao, T. Su, Y. Wang, R.S. Varma, C. Len. Mol. Catal. 495 (2020) 111133.
    [11]
    X. Huang, J. Song, M. Hua, Z. Xie, S. Liu, T. Wu, G. Yang, B. Han. Green Chem. 22 (2020) 843-849.
    [12]
    R. Chen, J. Xin, D. Yan, H. Dong, X. Lu, S. Zhang. ChemSusChem 12 (2019) 2715-2724.
    [13]
    D. Yan, G. Wang, K. Gao, X. Lu, J. Xin, S. Zhang. Ind. Eng. Chem. Res. 57 (2018) 1851-1858.
    [14]
    L. Wang, J. Zhang, Y. Zhu, S. Xu, C. Wang, C. Bian, X. Meng, F.S. Xiao. ACS Catal. 7 (2017) 7461-7465.
    [15]
    Z. Zhang, J. Zhen, B. Liu, K. Lv, K. Deng. Green Chem. 17 (2015) 1308-1317.
    [16]
    P.V. Rathod, V.H. Jadhav. ACS Sustain. Chem. Eng. 6 (2018) 5766-5771.
    [17]
    D. Lei, K. Yu, M.R. Li, Y. Wang, Q. Wang, T. Liu, P. Liu, L.L. Lou, G. Wang, S. Liu. ACS Catal. 7 (2017) 421-432.
    [18]
    J. Shen, H. Chen, K. Chen, Y. Qin, X. Lu, P. Ouyang, J. Fu. Ind. Eng. Chem. Res. 57 (2018) 2811-2818.
    [19]
    C. Zhou, W. Deng, X. Wan, Q. Zhang, Y. Yang, Y. Wang. ChemCatChem 7 (2015) 2853-2863.
    [20]
    X. Han, C. Li, Y. Guo, X. Liu, Y. Zhang, Y. Wang. Appl. Catal. A Gen. 526 (2016) 1-8.
    [21]
    O.R. Schade, K.F. Kalz, D. Neukum, W. Kleist, J.D. Grunwaldt. Green Chem. 20 (2018) 3530-3541.
    [22]
    X. Wan, C. Zhou, J. Chen, W. Deng, Q. Zhang, Y. Yang, Y. Wang. ACS Catal. 4 (2014) 2175-2185.
    [23]
    G. Papanikolaou, P. Lanzafame, S. Perathoner, G. Centi, D. Cozza, G. Giorgianni, M. Migliori, G. Giordano. Catal. Commun. 149 (2021).
    [24]
    Rabee, A.I.M., S.D. Le, K. Higashimine, S. Nishimura. ACS Sustain. Chem. Eng. 8 (2020) 7150-7161.
    [25]
    O. Casanova, S. Iborra, A. Corma. ChemSusChem 2 (2009) 1138-1144.
    [26]
    J. Cai, H. Ma, J. Zhang, Q. Song, Z. Du, Y. Huang, J. Xu. Chem. Eur. J. 19 (2013) 14215-14223.
    [27]
    Y.Y. Gorbanev, S.K. Klitgaard, J.M. Woodley, C.H. Christensen, A. Riisager. ChemSusChem 2 (2009) 672-675.
    [28]
    P. Kandasamy, P. Gogoi, A. T. Venugopalan, T. Raja. Catal. Today 375 (2021) 145-154.
    [29]
    S. Siankevich, G. Savoglidis, Z. Fei, G. Laurenczy, D. T. L. Alexander, N. Yan, P. J. Dyson. J. Catal. 315 (2014) 67-74.
    [30]
    D. Yan, J. Xin, Q. Zhao, K. Gao, X. Lu, G. Wang, S. Zhang. Catal. Sci. Technol. 8 (2018) 164-175.
    [31]
    B.N. Zope, S.E. Davis, R.J. Davis. Top. Catal. 55 (2012) 24-32.
    [32]
    S.E. Davis, A.D. Benavidez, R.W. Gosselink, J.H. Bitter, K.P. De Jong, A.K. Datye, R.J. Davis. J. Mol. Catal. A-Chem. 388-389 (2014) 123-132.
    [33]
    Y. Liu, H.Y. Ma, D. Lei, L.L. Lou, S. Liu, W. Zhou, G.C. Wang, K. Yu. ACS Catal. 9 (2019) 8306-8315.
    [34]
    H. Tang, Y. Su, B. Zhang, A.F. Lee, M.A. Isaacs, K. Wilson, L. Li, Y. Ren, J. Huang, M. Haruta, B. Qiao, X. Liu, C. Jin, D. Su, J. Wang, T. Zhang. Sci. Adv. 3 (2017) 1-9.
    [35]
    A. Berko, N. Balazs, G. Kassab, L. Ovari. J. Catal. 289 (2012) 179-189.
    [36]
    O.H. Laguna, F. Romero Sarria, M.A. Centeno, J.A. Odriozola. J. Catal. 276 (2010) 360-370.
    [37]
    K. Li, H. Wang, Y. Wei, D. Yan. Chem. Eng. J. 156 (2010) 512-518.
    [38]
    N. Zhang, X. Feng, D. Rao, X. Deng, L. Cai, B. Qiu, R. Long, Y. Xiong, Y. Lu, Y. Chai. Nat. Commun. 11 (2020) 1-11.
    [39]
    F. Lupo, R. Kamalakaran, A. Gulino. J. Phys. Chem. C 113 (2009) 15533-15537.
    [40]
    Wang, J. Q.; Shen, M. Q.; Wang, J.; Gao, J. D.; Ma, J.; Liu, S. X. CeO2-CoOx Mixed Oxides: Structural Characteristics and Dynamic Storage/Release Capacity. Catal. Today 2011, 175, 65-71. DOI: 10.1016/j.cattod.2011.03.004
    [41]
    Z. Li, Y. Cui, Z. Wu, C. Milligan, L. Zhou, G. Mitchell, B. Xu, E. Shi, J.T. Miller, F.H. Ribeiro, Y. Wu. Nat. Catal. 1 (2018) 349-355.
    [42]
    J. Ftouni, A. Munoz-Murillo, A. Goryachev, J.P. Hofmann, E.J.M. Hensen, L. Lu, C.J. Kiely, P.C.A. Bruijnincx, B.M. Weckhuysen. ACS Catal. 6 (2016) 5462-5472.
    [43]
    H. Xie, N. Li, X. Chen, J. Jiang, X. Zhao. Appl. Surf. Sci. 511 (2020).
    [44]
    L. Rizzo, D. Sannino, V. Vaiano, O. Sacco, A. Scarpa, D. Pietrogiacomi. Appl. Catal. B Environ. 144 (2014) 369-378.
    [45]
    F. Meng, S. Zhang, X. Li, Y. Zeng, Q. Zhong. Mol. Catal. 473 (2019) 2-9.
    [46]
    C. Xie, D. Yan, H. Li, S. Du, W. Chen, Y. Wang, Y. Zou, R. Chen, S. Wang. ACS Catal. 10 (2020) 11082-11098.
    [47]
    V. M. Shinde, G. Madras. Int. J. Hydrog. Energy 37 (2012) 18798-18814.
    [48]
    H. Wang, L. Wang, J. Zhang, C. Wang, Z. Liu, X. Gao, X. Meng, S. J. Yoo, J. G. Kim, W. Zhang, F. S. Xiao. ChemSusChem 11 (2018) 3965-3974.
    [49]
    M. Xu, S. He, H. Chen, G. Gui, L. Zheng, B. Wang, M. Wei. ACS Catal. 7 (2017) 7600-7609.
    [50]
    E. Pakrieva, E. Kolobova, G. Mamontov, N. Bogdanchikova, M.H. Farias, L. Pascual, V. Cortes Corberan, S. Martinez Gonzalez, S.A.C. Carabineiro, A. Pestryakov. ChemCatChem 11 (2019) 1615-1624.
    [51]
    S. Mo, Q. Zhang, J. Li, Y. Sun, Q. Ren, S. Zou, Q. Zhang, J. Lu, M. Fu, D. Mo, J. Wu, H. Huang, D. Ye. Appl. Catal. B Environ. 264 (2020) 118464.
    [52]
    B. Chen, B. Wu, L. Yu, M. Crocker, C. Shi. ACS Catal. 10 (2020) 6176-6187.
    [53]
    J. Xiong, K. Wu, J. Yang, P. Liu, L. Song, J. Zhang, M. Fu, L. Chen, H. Huang, J. Wu, D. Ye. Appl. Surf. Sci. 539 (2021) 148211.
    [54]
    Y. Li, X. Chen, C. Wang, C. Zhang, H. He. ACS Catal. 8 (2018) 11377-11385.
    [55]
    H. Huang, D.Y.C. Leung. ACS Catal. 1 (2011) 348-354.
    [56]
    H.F. Li, N. Zhang, P. Chen, M.F. Luo, J.Q. Lu. Appl. Catal. B Environ. 110 (2011) 279-285.
    [57]
    Q. Wang, L. Chen, S. Guan, X. Zhang, B. Wang, X. Cao, Z. Yu, Y. He, D.G. Evans, J. Feng, D. Li. ACS Catal. 8 (2018) 3104-3115.
    [58]
    S. Bates, M. Gillan, G. Kresse. J. Phys. Chem. B 102 (1998) 2017-2026.
    [59]
    E. Farfan-Arribas, R.J. Madix. J. Phys. Chem. B 106 (2002) 10680-10692.
    [60]
    Z. Zhang, O. Bondarchuk, J.M. White, B.D. Kay, Z. Dohnalek. J. Am. Chem. Soc. 128 (2006) 4198-4199.
    [61]
    A. Lolli, R. Amadori, C. Lucarelli, M.G. Cutrufello, E. Rombi, F. Cavani, S. Albonetti. Microporous Mesoporous Mater. 226 (2016) 466-475.
    [62]
    M. Kim, Y. Su, A. Fukuoka, E.J.M. Hensen, K. Nakajima. Angew. Chem. Int. Ed. 57 (2018) 8235-8239.
    [63]
    H. Zhou, H. Xu, Y. Liu. Appl. Catal. B Environ. 244 (2019) 965-973
    [64]
    Z. Qiao, Z. Wang, C. Zhang, S. Yuan, Y. Zhu, J. Wang. AIChE J. 59 (2012) 215-228.
    [65]
    C.G. Rotaru, G. Postole, M. Florea, F. Matei-Rutkovska, V.I. Parvulescu, P. Gelin. Appl. Catal. A Gen. 494 (2015) 29-40.
    [66]
    J. Wan, W. Chen, C. Jia, L. Zheng, J. Dong, X. Zheng, Y. Wang, W. Yan, C. Chen, Q. Peng, D. Wang, Y. Li. Adv. Mater. 30 (2018) 1-8.
    [67]
    P. Panagiotopoulou, D.I. Kondarides. J. Catal. 267 (2009) 57-66.
    [68]
    K. Yu, L.L. Lou, S. Liu, W. Zhou. Adv. Sci. 7 (2020) 1-8.
    [69]
    M. Shekhar, J. Wang, W.S. Lee, W.D. Williams, S.M. Kim, E.A. Stach, J.T. Miller, W.N. Delgass, F.H. Ribeiro. J. Am. Chem. Soc. 134 (2012) 4700-4708.
    [70]
    K. Sun, M. Kohyama, S. Tanaka, S. Takeda. J. Phys. Chem. C. 121 (2017) 12178-12187.
    [71]
    M. Yang, L. F. Allard, M. Flytzani-stephanopoulos. J. Am. Chem. Soc. 135 (2013) 3768-3771.
    [72]
    C. Megias-Sayago, K. Chakarova, A. Penkova, A. Lolli, S. Ivanova, S. Albonetti, F. Cavani, J.A. Odriozola. ACS Catal. 8 (2018) 11154-11164.
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Get Citation
    PDF
    XML

    Article Metrics

    Article views (133) PDF downloads(18) Cited by()
    Proportional views

    Publish With GEE

    Contact

    • Email：gee@ipe.ac.cn
    • Tel：010-82627075
    • Address：North 2nd street, Zhongguancun, Haidian District, Beijing, China

    Links

    京ICP备10002620号-1京公网安备 11010802039050号

    Supported by: Beijing Renhe Information Technology Co. Ltd    

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return