Volume 8 Issue 3
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Wei Yu, Ming Gao, Guanhe Rim, Tony G. Feric, Mark L. Rivers, Ammar Alahmed, Aqil Jamal, Ah-Hyung Alissa Park. Novel in-capsule synthesis of metal-organic framework for innovative carbon dioxide capture system. Green Energy&Environment, 2023, 8(3): 767-774. doi: 10.1016/j.gee.2021.08.002
Citation: Wei Yu, Ming Gao, Guanhe Rim, Tony G. Feric, Mark L. Rivers, Ammar Alahmed, Aqil Jamal, Ah-Hyung Alissa Park. Novel in-capsule synthesis of metal-organic framework for innovative carbon dioxide capture system. Green Energy&Environment, 2023, 8(3): 767-774. doi: 10.1016/j.gee.2021.08.002
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Novel in-capsule synthesis of metal-organic framework for innovative carbon dioxide capture system

doi: 10.1016/j.gee.2021.08.002

  • a. State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou, 310027, China;

  • b. Lenfest Center for Sustainable Energy, The Earth Institute, Columbia University, 918 S.W. Mudd Hall, Mail Code 4711, 500 W 120th St., New York, NY, 10027, USA;

  • c. Department of Earth and Environmental Engineering, 918 S.W. Mudd Hall, Mail Code 4711, 500 W 120th St., New York, NY, 10027, USA;

  • d. Department of Chemical Engineering, Columbia University, New York, NY, 10027, USA;

  • e. University of Chicago, Chicago, IL, 60637, USA;

  • f. Research and Development Center, Saudi Aramco, Dhahran, 31311, Saudi Arabia

Funds:

The authors acknowledge National Science Foundation (CBET 1927336), Saudi Aramco, and the Lenfest Center for Sustainable Energy at the Earth Institute at Columbia University for financially supporting this work. The microtomography of encapsulated MOFs was performed at GeoSoilEnviroCARS (The University of Chicago, Sector 13), Advanced Photon Source (APS), Argonne National Laboratory. GeoSoilEnviroCARS is supported by the National Science Foundation - Earth Sciences (EAR - 1634415) and the Department of Energy- GeoSciences (DE-FG02-94ER14466). This research used resources of the Advanced Photon Source, a U.S. Department of Energy (DOE) Office of Science User Facility operated for the DOE Office of Science by Argonne National Laboratory under Contract No. DE-AC02-06CH11357.

  • Received date 29 June 2021, Accepted date 20 August 2021, RevRecd date 16 August 2021, Publish date 31 July 2023,
    Abstract
  • Metal-Organic Frameworks (MOFs) have been developed as solid sorbents for CO2 capture applications and their properties can be controlled by tuning the chemical blocks of their crystalline units. A number of MOFs (e.g., HKUST-1) have been developed but the question remains how to deploy them for gas-solid contact. Unfortunately, the direct use of MOFs as nanocrystals would lead to serious problems and risks. Here, for the first time, we report a novel MOF-based hybrid sorbent that is produced via an innovative in-situ microencapsulated synthesis. Using a custom-made double capillary microfluidic assembly, double emulsions of the MOF precursor solutions and UV-curable silicone shell fluid are produced. Subsequently, HKUST-1 MOF is successfully synthesized within the droplets enclosed in the gas permeable microcapsules. The developed MOF-bearing microcapsules uniquely allow the deployment of functional nanocrystals without the challenge of handling ultrafine particles, and further, can selectively reject undesired compounds to protect encapsulated MOFs.

     

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