Volume 8 Issue 1
Feb.  2023
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Article Navigation >  Green Energy&Environment  > 2023  >  8(1): 163-172
Risheng Bai, Yue Song, Ge Tian, Fei Wang, Avelino Corma, Jihong Yu. Titanium-rich TS-1 zeolite for highly efficient oxidative desulfurization. Green Energy&Environment, 2023, 8(1): 163-172. doi: 10.1016/j.gee.2021.03.006
Citation: Risheng Bai, Yue Song, Ge Tian, Fei Wang, Avelino Corma, Jihong Yu. Titanium-rich TS-1 zeolite for highly efficient oxidative desulfurization. Green Energy&Environment, 2023, 8(1): 163-172. doi: 10.1016/j.gee.2021.03.006
shu

Titanium-rich TS-1 zeolite for highly efficient oxidative desulfurization

doi: 10.1016/j.gee.2021.03.006

  • a. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, 130012, China;

  • b. Instituto de Tecnología Química, Universitat Politècnica de València-Consejo Superior de Investigaciones Científicas, Valencia, 46022, Spain;

  • c. State Key Laboratory of Superhard Materials, Jilin University, Changchun, 130012, China;

  • d. International Center of Future Science, Jilin University, Changchun, 130012, China

Funds:

The authors thank the National Natural Science Foundation of China, China (Grant 21920102005, 22288101, and 21835002), the 111 Project, China (B17020), the European Union through the European Research Council, European Union (grant ERC-AdG-2014-671093, SynCatMatch), and the Spanish Government through “Severo Ochoa”, Spain (SEV-2016-0683, MINECO) for supporting this work. R. Bai acknowledges the financial support from China Scholarship Council, China.

  • Received date 12 October 2020, Accepted date 09 March 2021, RevRecd date 27 February 2021, Publish date 11 March 2021,
    Abstract
  • The exploration of highly efficient catalysts based on nano-sized Ti-rich titanosilicate zeolites with controllable active titanium species is of great importance in zeolite catalytic reactions. Herein, we reported an efficient and facile synthesis of nano-sized Ti-rich TS-1 ( MFI ) zeolites by replacing tetrabutyl orthotitanate (TBOT) with tetrabutyl orthotitanate tetramer (TBOT-tetramer) as the titanium source. The introduced TBOT-tetramer slowed down the zeolite crystallization process, and accordingly balanced the rate of incorporating Ti and the crystal growth and inhibited the massive formation of anatase species. Notably, the prepared Ti-rich TS-1 zeolite sample had a Si/Ti as low as 27.6 in contrast to conventional one with a molar ratio of 40. The TBOT-tetramer endowed the titanosilicate zeolites with enriched active titanium species and enlarged external surface area. It also impeded the formation of anatase species, resulting in superior catalytic behavior toward the oxidative desulfurization of dibenzothiophene compared with the conventional TS-1 zeolite counterpart prepared with TBOT.

     

    • • Synthesis of Titanium-rich TS-1 zeolite. • The Ti-rich TS-1 zeolite exhibited abundant active hexa-coordinated titanium species and free of anatase. • The Ti-rich TS-1 zeolite catalyst demonstrated superior activity for oxidative desulfurization of dibenzothiophene.
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