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Article Navigation >  Green Energy&Environment  > 2020  >  5(4): 499-505
Mengyang Dong, Xu Liu, Lixue Jiang, Zhengju Zhu, Yajie Shu, Shan Chen, Yuhai Dou, Porun Liu, Huajie Yin, Huijun Zhao. Cobalt-doped Mn3O4 nanocrystals embedded in graphene nanosheets as a high-performance bifunctional oxygen electrocatalyst for rechargeable Zn–Air batteries. Green Energy&Environment, 2020, 5(4): 499-505. doi: 10.1016/j.gee.2020.06.022
Citation: Mengyang Dong, Xu Liu, Lixue Jiang, Zhengju Zhu, Yajie Shu, Shan Chen, Yuhai Dou, Porun Liu, Huajie Yin, Huijun Zhao. Cobalt-doped Mn3O4 nanocrystals embedded in graphene nanosheets as a high-performance bifunctional oxygen electrocatalyst for rechargeable Zn–Air batteries. Green Energy&Environment, 2020, 5(4): 499-505. doi: 10.1016/j.gee.2020.06.022
shu

Cobalt-doped Mn3O4 nanocrystals embedded in graphene nanosheets as a high-performance bifunctional oxygen electrocatalyst for rechargeable Zn–Air batteries

doi: 10.1016/j.gee.2020.06.022

  • Centre for Clean Environment and Energy, Griffith University, Gold Coast Campus, QLD 4222, Australia

More Information
  • Corresponding author: E-mail address: h.yin@griffith.edu.au (Huajie Yin); E-mail address: h.zhao@griffith.edu.au (Huijun Zhao)
  • Received date 28 April 2020, Accepted date 23 June 2020, RevRecd date 20 June 2020, Available online 01 July 2020, Publish date 31 October 2020,
    Abstract
  • A non-noble-metal bifunctional catalyst with efficient and durable activity towards both the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER) is crucial to the development of rechargeable Zn-air batteries. Herein, a facile one-step hydrothermal method is reported for the synthesis of a high-performance bifunctional oxygen electrocatalyst, cobalt-doped Mn3O4 nanocrystals supported on graphene nanosheets (Co–Mn3O4/G). Compare to pristine Mn3O4, this Co–Mn3O4/G exhibits greatly enhanced electrocatalytic activity, delivering a half-wave potential of 0.866 V for the ORR and a low overpotential of 275 mV at 10 mA cm−2 for the OER. The zinc-air battery built with Co–Mn3O4/G shows a reduced charge–discharge voltage of 0.91 V at 10 mA cm−2, an power density of 115.24 mW cm−2 and excellent stability without any degradation after 945 cycles (315 h), outperforming the state-of-the-art Pt/C–Ir/C catalyst-based device.

     

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