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Article Navigation >  Green Energy&Environment  > 2019  >  4(4): 424-431
Yangyang Zhang, Xinli Tong, Linhao Yu, Lingwu Meng, Pengfei Guo, Song Xue. Highly efficient catalytic valorization of biomass-derived hexoses and furfuryl alcohol in the presence of polymer-based catalysts. Green Energy&Environment, 2019, 4(4): 424-431. doi: 10.1016/j.gee.2019.01.006
Citation: Yangyang Zhang, Xinli Tong, Linhao Yu, Lingwu Meng, Pengfei Guo, Song Xue. Highly efficient catalytic valorization of biomass-derived hexoses and furfuryl alcohol in the presence of polymer-based catalysts. Green Energy&Environment, 2019, 4(4): 424-431. doi: 10.1016/j.gee.2019.01.006
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Highly efficient catalytic valorization of biomass-derived hexoses and furfuryl alcohol in the presence of polymer-based catalysts

doi: 10.1016/j.gee.2019.01.006

  • Tianjin Key Laboratory of Organic Solar Cells and Photochemical Conversion, School of Chemistry and Chemical Engineering, Tianjin University of Technology, No. 391 Binshuixi Road, Tianjin 300384, China

More Information
  • Corresponding author: E-mail address: tongxli@sohu.com (Xinli Tong)
  • Received date 18 September 2018, Accepted date 21 January 2019, RevRecd date 12 January 2019, Available online 28 January 2019, Publish date 31 October 2019,
    Abstract
  • The catalytic transformation of furfuryl alcohol and hexose into value-added chemicals have been investigated with a series of polymer-based catalysts including poly(styrenesulfonic acid) (PSS), graphite oxide-doped poly(styrenesulfonic acid) (PSS-GO), and graphite-doped poly(styrenesulfonic acid) (PSS-C). It is found that the selective conversion of furfuryl alcohol to methyl levulinate (MLE) was successfully performed with PSS as the catalyst, in which a 96.4% yield is attained in methanol solvent. Moreover, the efficient dehydration of d-fructose to produce 5-hydroxymethylfurfural (HMF) has also been achieved using PSS-GO as the catalyst, where a 76.5% yield of HMF was obtained in N-methylpyrrodinone solvent. The effects of reaction temperature, time and solvent were investigated. Furthermore, the used catalysts have been respectively characterized by XRD, TG, FTIR, SEM and TEM techniques to reveal the physical properties and structures of these polymeric catalytic materials.

     

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