Volume 2 Issue 2
. 
Turn off MathJax
Article Contents
Article Navigation >  Green Energy&Environment  > 2017  >  2(2): 119-123
Zheng Xi, Adriana Mendoza-Garcia, Huiyuan Zhu, MiaoFang Chi, Dong Su, Daniel P. Erdosy, Junrui Li, Shouheng Sun. NixWO2.72 nanorods as an efficient electrocatalyst for oxygen evolution reaction. Green Energy&Environment, 2017, 2(2): 119-123. doi: 10.1016/j.gee.2017.01.001
Citation: Zheng Xi, Adriana Mendoza-Garcia, Huiyuan Zhu, MiaoFang Chi, Dong Su, Daniel P. Erdosy, Junrui Li, Shouheng Sun. NixWO2.72 nanorods as an efficient electrocatalyst for oxygen evolution reaction. Green Energy&Environment, 2017, 2(2): 119-123. doi: 10.1016/j.gee.2017.01.001
shu

NixWO2.72 nanorods as an efficient electrocatalyst for oxygen evolution reaction

doi: 10.1016/j.gee.2017.01.001
  • a.

    Department of Chemistry, Brown University, Providence, RI, 02912, United States

  • b.

    Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, United States

  • c.

    Center for Nanophase Materials Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, United States

  • d.

    Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, NY, 11973, United States

More Information
  • Corresponding author: E-mail address: ssun@brown.edu (Shouheng Sun)
  • Received date 17 December 2016, Accepted date 07 January 2017, RevRecd date 04 January 2017, Available online 13 January 2017, Publish date 30 April 2017,
    Abstract
  • NixWO2.72 nanorods (NRs) are synthesized by a one-pot reaction of Ni(acac)2 and WCl4. In the rod structure, Ni(II) intercalates in the defective perovskite-type WO2.72 and is stabilized. The NixWO2.72 NRs show the x-dependent electrocatalysis for the oxygen evolution reaction (OER) in 0.1 M KOH with Ni0.78WO2.72 being the most efficient, even outperforming the commercial Ir-catalyst. The synthesis is not limited to NixWO2.72 but can be extended to MxWO2.72 (M = Co, Fe) as well, providing a new class of oxide-based catalysts for efficient OER and other energy conversion reactions.

     

    • These authors contributed equally.
    FullText(HTML)
  • loading
    • References(35)
  • [1]
    C.G.Morales-Guio, L.A.Stern, X.Hu Chem. Soc. Rev., 43 (2014),pp. 6555-6569
    [2]
    R.Subbaraman, D.Tripkovic, D.Strmcnik, et al. Science, 334 (2011),p. 1256
    [3]
    Y.H.Fang, Z.P.Liu J. Am. Chem. Soc., 132 (2010),pp. 18214-18222
    [4]
    L.Wu, Q.Li, C.H.Wu, et al. J. Am. Chem. Soc., 137 (2015),pp. 7071-7074
    [5]
    R.D.Smith, M.S.Prevot, R.D.Fagan, et al. Science, 340 (2013),pp. 60-63
    [6]
    M.Huynh, C.Shi, S.J.Billinge, et al. J. Am. Chem. Soc., 137 (2015),pp. 14887-14904
    [7]
    M.Zhang, M.de Respinis, H.Frei Nat. Chem., 6 (2014),pp. 362-367
    [8]
    M.W.Louie, A.T.Bell J. Am. Chem. Soc., 135 (2013),pp. 12329-12337
    [9]
    L.Trotochaud, S.L.Young, J.K.Ranney, et al. J. Am. Chem. Soc., 136 (2014),pp. 6744-6753
    [10]
    D.Friebel, M.W.Louie, M.Bajdich, et al. J. Am. Chem. Soc., 137 (2015),pp. 1305-1313
    [11]
    M.Gorlin, P.Chernev, J.Ferreira de Araujo, et al. J. Am. Chem. Soc., 138 (2016),pp. 5603-5614
    [12]
    J.Suntivich, K.J.May, H.A.Gasteiger, et al. Science, 334 (2011),pp. 1383-1385
    [13]
    A.Vojvodic, J.K.Norskov Science, 334 (2011),pp. 1355-1356
    [14]
    A.Mendoza-Garcia, H.Zhu, Y.Yu, et al. Angew. Chem., 54 (2015),pp. 9642-9645
    [15]
    A.Mendoza-Garcia, D.Su, S.Sun Nanoscale, 8 (2016),pp. 3244-3247
    [16]
    D.Li, H.Baydoun, C.N.Verani, et al. J. Am. Chem. Soc., 138 (2016),pp. 4006-4009
    [17]
    R.Subbaraman, D.Tripkovic, K.C.Chang, et al. Nat. Mater., 11 (2012),pp. 550-557
    [18]
    M.R.Gao, W.C.Sheng, Z.B.Zhuang, et al. J. Am. Chem. Soc., 136 (2014),pp. 7077-7084
    [19]
    A.Ponzoni, E.Comini, G.Sberveglieri, et al. Appl. Phys. Lett., 88 (2006),p. 203101
    [20]
    M.H.Yaacob, M.Breedon, K.Kalantar-Zadeh, et al. Sens. Actuators B Chem., 137 (2009),pp. 115-120
    [21]
    Y.F.Dong, L.Y.Li, W.F.Jiang, et al. Phys. E, 41 (2009),pp. 711-714
    [22]
    S.Cong, Y.Y.Tian, Q.W.Li, et al. Adv. Mater., 26 (2014),pp. 4260-4267
    [23]
    R.Abe, H.Takami, N.Murakami, et al. J. Am. Chem. Soc., 130 (2008),pp. 7780-7781
    [24]
    M.Remskar, J.Kovac, M.Virsek, et al. Adv. Funct. Mater., 17 (2007),pp. 1974-1978
    [25]
    K.Manthiram, A.P.Alivisatos J. Am. Chem. Soc., 134 (2012),pp. 3995-3998
    [26]
    S.Cong, Y.Y.Yuan, Z.G.Chen, et al. Nat. Commun., 6 (2015)
    [27]
    R.Wu, J.F.Zhang, Y.M.Shi, et al. J. Am. Chem. Soc., 137 (2015),pp. 6983-6986
    [28]
    B.Zhang, X.Zheng, O.Voznyy, et al. Science, 352 (2016),pp. 333-337
    [29]
    X.W.Lou, H.C.Zeng Inorg. Chem., 42 (2003),pp. 6169-6171
    [30]
    G.Xi, S.Ouyang, P.Li, et al. Angew. Chem., 51 (2012),pp. 2395-2399
    [31]
    C.Guo, S.Yin, Q.Dong, et al. RSC Adv., 2 (2012),pp. 5041-5043
    [32]
    M.Zhou, H.Chai, D.Jia, et al. New J. Chem., 38 (2014),pp. 2320-2326
    [33]
    Y.Lu, Y.Jiang, X.Gao, et al. J. Am. Chem. Soc., 136 (2014),pp. 11687-11697
    [34]
    C.C.McCrory, S.Jung, I.M.Ferrer, et al. J. Am. Chem. Soc., 137 (2015),pp. 4347-4357
    [35]
    D.K.Bediako, B.Lassalle-Kaiser, Y.Surendranath, et al. J. Am. Chem. Soc., 134 (2012),pp. 6801-6809
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Get Citation
    PDF
    XML

    Article Metrics

    Article views (190) PDF downloads(19) Cited by()
    Proportional views

    Publish With GEE

    Contact

    • Email：gee@ipe.ac.cn
    • Tel：010-82627075
    • Address：North 2nd street, Zhongguancun, Haidian District, Beijing, China

    Links

    京ICP备10002620号-1京公网安备 11010802039050号

    Supported by: Beijing Renhe Information Technology Co. Ltd    

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return