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Yiwen Wang, Yan Wang, Puyang Zhou, Chenchao Hu, Jia Yan, Yilin Deng, Yu Gan, Meng Xie, Liying Huang, Yuanguo Xu. Multi-Order Built-In Electric Field Engineering in Vo-ZF@TCN Heterojunctions for Efficient PMS Activation in Photo-Fenton-Like Reactions. Green Energy&Environment. doi: 10.1016/j.gee.2025.12.003
Citation: Yiwen Wang, Yan Wang, Puyang Zhou, Chenchao Hu, Jia Yan, Yilin Deng, Yu Gan, Meng Xie, Liying Huang, Yuanguo Xu. Multi-Order Built-In Electric Field Engineering in Vo-ZF@TCN Heterojunctions for Efficient PMS Activation in Photo-Fenton-Like Reactions. Green Energy&Environment. doi: 10.1016/j.gee.2025.12.003
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Multi-Order Built-In Electric Field Engineering in Vo-ZF@TCN Heterojunctions for Efficient PMS Activation in Photo-Fenton-Like Reactions

doi: 10.1016/j.gee.2025.12.003

  • a. School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, P.R. China;

  • b. School of Mechanical and Power Engineering, Henan Polytechnic University, Jiaozuo 454000, P.R. China;

  • c. Institute for Energy Research, Jiangsu University, Zhenjiang, 212013, P. R. China;

  • d. School of Pharmacy, Jiangsu University, Zhenjiang 212013, P. R. China

Funds:

This work is financially supported by the National Natural Science Foundation of China (Grant No. 22076068, 22106053). the Senior Talent Fund of Jiangsu University (23JDG012).

  • Received date 26 June 2025, Accepted date 10 December 2025, RevRecd date 09 October 2025, Available online 18 December 2025
    Abstract
  • The adsorption of PMS and the associated transfer of photogenerated carriers are prerequisites for photo-Fenton activation. In this work, we constructed an S-scheme Vo-ZF@TCN heterojunction with the characteristics of interlayer and in-plane multi-level built-in electric fields (BIEF). It was found that the BIEF amplitude of the in-plane heterojunction was ∼2.7 times that of a traditional heterojunction. The strong BIEF promotes the directional, rapid, and efficient transfer of photogenerated charge carriers, enabling the photostimulated synergistic activation of PMS for the degradation of organic pollutants. The rational design of redox ends promotes the formation of electron-deficient Vo-Fe, which creates Lewis acid adsorption sites. This design constructs a composite site for PMS adsorption and carrier transfer. We elucidated that the directional migration of electrons and holes cause spatial separation of PMS radical and non-radical activation sites and regulates the activation pathways by altering the migration direction of PMS through adsorption. This study provides new insights into the regulation of PMS activation pathways and enriches the design strategies for efficient photogenerated carrier transport and transfer.

     

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