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Article Navigation >  Green Energy&Environment  > 2023  > Accepted Manuscript
Yisen Yang, Zhonghao Tan, Jianling Zhang, Jie Yang, Renjie Zhang, Sha Wang, Yi Song, Zhuizhui Su. Nitrogen-doping boosts *CO utilization and H2O activation on copper for improving CO2 reduction to C2+ products. Green Energy&Environment. doi: 10.1016/j.gee.2023.09.002
Citation: Yisen Yang, Zhonghao Tan, Jianling Zhang, Jie Yang, Renjie Zhang, Sha Wang, Yi Song, Zhuizhui Su. Nitrogen-doping boosts *CO utilization and H2O activation on copper for improving CO2 reduction to C2+ products. Green Energy&Environment. doi: 10.1016/j.gee.2023.09.002
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Nitrogen-doping boosts *CO utilization and H2O activation on copper for improving CO2 reduction to C2+ products

doi: 10.1016/j.gee.2023.09.002

  • a Beijing National Laboratory for Molecular Sciences, CAS Laboratory of Colloid and Interface and Thermodynamics, CAS Research/Education Center for Excellence in Molecular Sciences, Center for Carbon Neutral Chemistry, Institute of Chemist Chinese Academy of Sciences, Beijing 100190, P. R. China;

  • b Key Laboratory of Photochemistry, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China;

  • c School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100190, P. R. China

Funds:

The work was supported by National Natural Science Foundation of China (22033009, 22121002, 22238011).

  • Received date 25 July 2023, Accepted date 25 September 2023, RevRecd date 15 September 2023, Available online 07 October 2023
    Abstract

  • To improve the electrocatalytic transformation of carbon dioxide (CO2) to multi-carbon (C2+) products is of great importance. Here we developed a nitrogen-doped Cu catalyst, by which the maximum C2+ Faradaic efficiency can reach 72.7% in flow-cell system, with the partial current density reaching 0.62 A cm-2. The in situ Raman spectra demonstrate that the *CO adsorption can be strengthened on such a N doped Cu catalyst, thus promoting the *CO utilization in the subsequent C-C coupling step. Simultaneously, the water activation can be well enhanced by N doping on Cu catalyst. Owing to the synergystic effects, the selectivity and activity for C2+ products over the N-deoped Cu catalyst are much improved.

     

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