Recent advances in cellulose-based separators for zinc-based batteries: performances, mechanism and perspectives

Zinc-based batteries have attracted widespread attention due to their inherent safety, notable cost-effectiveness and consistent performance, etc. However, the advancement of zinc-based battery technology encounters significant challenges, including the formation of zinc dendrites and irreversible side reactions. Separators are vital in batteries due to its role in preventing electrode contact and facilitating rapid movement of ions within the electrolyte. The incorporation of cellulose in battery enables uniform ion transport and a stable electric field, attributed to its excellent hydrophilicity, strong mechanical strength, and abundant active sites. Herein, the latest research progress of cellulose-based separators on various zinc-based batteries is systematically summarized. To begin with, the accomplishments and inherent limitations of traditional separators are clarified. Next, it underscores the advantages of cellulose-based materials in battery technology, thoroughly examining their utilization and merits as separators in zinc-based batteries. Lastly, the review offers prospective insights into the future trajectory of cellulose-based separators in zinc-based batteries. Through a comprehensive analysis of the present landscape, the review establishes a framework for the future design and enhancement of cellulose-based separators, thereby fostering the progression of associated industries.