Cyclic Ethers-Based Solid Electrolyte Derived from In Situ Ring-Opening Polymerization Strategy

Although solid-state polymer electrolytes (SPEs) are expected to solve the safety hazards and limited energy density in the energy storage systems, they still encounter an inferior electrode/electrolyte interface when prepared via an ex situ manner. Recently, in situ polymerization of SPEs favors high interfacial infiltrability, improved interface contact, and reduced interface resistance, owing to the formation of a "super-conformal" interface between electrode and electrolyte. Especially, in situ strategies employing ring-opening polymerization (ROP) are emerging as a dazzling star, further enabling moderate polymerization conditions, controllable molecular structure, and reduced interfacial side reaction. As the main monomers which can be in situ polymerized via ROP strategy, cyclic ethers have been used to construct the CE-SPEs with many merits including good battery electrochemical performances and simple assembly process. Here, as a systematic summarization to the existing reports, this review focuses the polymerization mechanism of ROP, the design principles of CE-SPEs electrolytes, and recent application of in situ CE-SPEs. In particular, this review thoroughly discusses the selection of different cyclic monomers, initiators and various modification approaches in in situ fabricating CE-SPEs. Ending with offering the future challenges and perspectives, this review envisions shedding light on the profound understanding and scientific guidance for further development of high-performance in situ CE-SPEs.