Volume 9 Issue 10
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Article Navigation >  Green Energy&Environment  > 2024  >  9(10): 1601-1609
Zhe Wang, Zhuo Li, Jialong Fu, Sheng Zheng, Rui Yu, Xiaoyan Zhou, Guanjie He, Xin Guo. All-fluorinated electrolyte for non-flammable batteries with ultra-high specific capacity at 4.7 V. Green Energy&Environment, 2024, 9(10): 1601-1609. doi: 10.1016/j.gee.2023.06.002
Citation: Zhe Wang, Zhuo Li, Jialong Fu, Sheng Zheng, Rui Yu, Xiaoyan Zhou, Guanjie He, Xin Guo. All-fluorinated electrolyte for non-flammable batteries with ultra-high specific capacity at 4.7 V. Green Energy&Environment, 2024, 9(10): 1601-1609. doi: 10.1016/j.gee.2023.06.002
shu

All-fluorinated electrolyte for non-flammable batteries with ultra-high specific capacity at 4.7 V

doi: 10.1016/j.gee.2023.06.002

  • a. State Key Laboratory of Material Processing and Die & Mould Technology, Laboratory of Solid State Ionics, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan, 430074, China;

  • b. Electrochemical Innovation Lab, Department of Chemical Engineering, University College London, 20 Gordon Street, London WC1E 7JE, UK

Funds:

All Authors would like to express their appreciation to the National Natural Science Foundation of China and the Israeli Science Foundation for funding this research within the framework of the joint NSFC-ISF grant # 51961145302. This work is also supported by China Postdoctoral Science Foundation funded project (Grant # 2020M682403).

  • Received date 03 February 2023, Accepted date 11 June 2023, RevRecd date 26 May 2023, Publish date 13 June 2023,
    Abstract
  • Li metal batteries (LMBs) with LiNi0.8Mn0.1Co0.1O2 (NMC811) cathodes could release a specific energy of >500 Wh kg-1 by increasing the charge voltage. However, high-nickel cathodes working at high voltages accelerate degradations in bulk and at interfaces, thus significantly degrading the cycling lifespan and decreasing the specific capacity. Here, we rationally design an all-fluorinated electrolyte with addictive tri(2,2,2-trifluoroethyl) borate (TFEB), based on 3, 3, 3-fluoroethylmethylcarbonate (FEMC) and fluoroethylene carbonate (FEC), which enables stable cycling of high nickel cathode (LiNi0.8Co0.1Mn0.1O2, NMC811) under a cut-off voltage of 4.7 V in Li metal batteries. The electrolyte not only shows the fire-extinguishing properties, but also inhibits the transition metal dissolution, the gas production, side reactions on the cathode side. Therefore, the NMC811||Li cell demonstrates excellent performance by using limited Li and high-loading cathode, delivering a specific capacity > 220 mA h g-1, an average Coulombic efficiency > 99.6% and capacity retention > 99.7% over 100 cycles.

     

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