Metal-organic cage as fluorescent probe for LiPF<sub>6</sub> in lithium batteries

Xi Li; Dehua Xu; Aoxuan Wang; Chengxin Peng; Xingjiang Liu; Jiayan Luo

doi:10.1016/j.gee.2023.06.001

Volume 9 Issue 10

Oct. 2024

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Article Navigation > Green Energy&Environment > 2024 > 9(10): 1592-1600

Xi Li, Dehua Xu, Aoxuan Wang, Chengxin Peng, Xingjiang Liu, Jiayan Luo. Metal-organic cage as fluorescent probe for LiPF6 in lithium batteries. Green Energy&Environment, 2024, 9(10): 1592-1600. doi: 10.1016/j.gee.2023.06.001

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Xi Li, Dehua Xu, Aoxuan Wang, Chengxin Peng, Xingjiang Liu, Jiayan Luo. Metal-organic cage as fluorescent probe for LiPF₆ in lithium batteries. Green Energy&Environment, 2024, 9(10): 1592-1600. doi: 10.1016/j.gee.2023.06.001

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Metal-organic cage as fluorescent probe for LiPF₆ in lithium batteries

doi: 10.1016/j.gee.2023.06.001

Xi Li^a,
Dehua Xu^a,
Aoxuan Wang^a,
Chengxin Peng^{b
,
,},
Xingjiang Liu^{a
,
,},
Jiayan Luo^{c
,
,}

Abstract

Abstract

Lithium hexafluorophosphate (LiPF₆), the most commonly used lithium battery electrolyte salt, is vulnerable to heat and humidity. Quantitative and qualitative determination the variation of LiPF₆ have always relied on advanced equipment. Herein, we develop a fast, convenient, high-selective fluorescence detection method based on metal-organic cages (MOC), whose emission is enhanced by nearly 20 times in the presence of LiPF₆ with good stability and photobleaching resistance. The fluorescent probe can also detect moisture in battery electrolyte. We propose and verify that the luminescence enhancement is due to the presence of hydrogen bond-induced enhanced emission effect in cages. Fluorescent excitation-emission matrix spectra and variable-temperature nuclear magnetic resonance spectroscopy are employed to clarify the role of hydrogen bonds in guest-loaded cages. Density functional theory (DFT) calculation is applied to simulate the structure of host-guest complexes and estimate the adsorption energy involved in the system. The precisely matched lock-and-key model paves a new way for designing and fabricating novel host structures, enabling specific recognition of other target compounds.
- Metal-organic cage,
- Selective fluorescence probe,
- Moisture detection,
- Hydrogen bond,
- Host-guest complex

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References

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Metal-organic cage as fluorescent probe for LiPF₆ in lithium batteries

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Metal-organic cage as fluorescent probe for LiPF6 in lithium batteries

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Metal-organic cage as fluorescent probe for LiPF₆ in lithium batteries