Volume 9 Issue 9
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Article Navigation >  Green Energy&Environment  > 2024  >  9(9): 1449-1458
Shijie Li, Wei-Li Song, Xue Han, Qingqing Cui, Yan-li Zhu, Shuqiang Jiao. Low-temperature graphitization of lignin via Co-assisted electrolysis in molten salt. Green Energy&Environment, 2024, 9(9): 1449-1458. doi: 10.1016/j.gee.2023.04.006
Citation: Shijie Li, Wei-Li Song, Xue Han, Qingqing Cui, Yan-li Zhu, Shuqiang Jiao. Low-temperature graphitization of lignin via Co-assisted electrolysis in molten salt. Green Energy&Environment, 2024, 9(9): 1449-1458. doi: 10.1016/j.gee.2023.04.006
shu

Low-temperature graphitization of lignin via Co-assisted electrolysis in molten salt

doi: 10.1016/j.gee.2023.04.006

  • a. Institute of Advanced Structure Technology, Beijing Institute of Technology, Beijing, 100081, China;

  • b. State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Beijing, 100083, China;

  • c. State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology Beijing, 100081, China

Funds:

This work was supported by National Key R&

D Program of China (No. 2022YFC2906100), National Natural Science Foundation of China (Nos. 52074036, 51725401, 51874019 and 52022013), Fundamental Research Funds for the Central Universities (No. FRF-TP-17-002C2) and BIT Teli Young Fellow. The authors would like to thank Da Sheng Shi and Yong Hui Wang from SCI-GO (www.sci-go.com) for the DFT calculations.

  • Received date 10 February 2023, Accepted date 23 April 2023, RevRecd date 31 March 2023, Publish date 03 May 2023,
    Abstract
  • The ever-growing energy demand and environmental issues have stimulated the development of sustainable energy technologies. Herein, an efficient and environmentally friendly electrochemical transformation technology was proposed to prepare highly graphitized carbon materials from an abundant natural resource-lignin (LG). The preparation process mainly includes pyrolytic carbonization of raw LG material and electrochemical conversion of amorphous carbon precursor. Interestingly, with the assistance of Co catalyst, the graphitization degree of the products was significantly improved, in which the mechanism was the removal of heteroatoms in LG and the rearrangement of carbon atoms into graphite lattice. Furthermore, tunable microstructures (nanoflakes) under catalytic effects could also be observed by controlling the electrolytic parameters. Compared with the products CN1 (without catalyst) and CN5 (with 10% catalyst), the specific surface area are 158.957 and 202.246 m2 g-1, respectively. When used as the electrode material for lithium-ion batteries, CN5 delivered a competitive specific capacity of ~350 mAh g-1 (0.5 C) compared with commercial graphite. The strategy proposed in this work provides an effective way to extract value-added graphite materials from lignin and can be extended to the graphitization conversion of any other amorphous carbon precursor materials.

     

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