Volume 9 Issue 9
Sep.  2024
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Article Navigation >  Green Energy&Environment  > 2024  >  9(9): 1419-1426
Wang Liu, Yanfei Zhang, Mengya Sun, Xinpeng Zhao, Shenggang Li, Xinqing Chen, Liangshu Zhong, Lingzhao Kong. Li-promoted C3N4 catalyst for efficient isomerization of glucose into fructose at 50℃ in water. Green Energy&Environment, 2024, 9(9): 1419-1426. doi: 10.1016/j.gee.2023.04.005
Citation: Wang Liu, Yanfei Zhang, Mengya Sun, Xinpeng Zhao, Shenggang Li, Xinqing Chen, Liangshu Zhong, Lingzhao Kong. Li-promoted C3N4 catalyst for efficient isomerization of glucose into fructose at 50℃ in water. Green Energy&Environment, 2024, 9(9): 1419-1426. doi: 10.1016/j.gee.2023.04.005
shu

Li-promoted C3N4 catalyst for efficient isomerization of glucose into fructose at 50℃ in water

doi: 10.1016/j.gee.2023.04.005

  • a. CAS Key Laboratory of Low-Carbon Conversion Science and Engineering, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai, 201210, China;

  • b. University of Chinese Academy of Sciences, Beijing, 100049, China;

  • c. School of Physical Science and Technology, Shanghai Tech University, Shanghai, 201203, China;

  • d. School of Environmental Science and Engineering, Suzhou University of Science and Technology, Suzhou, Jiangsu, 215009, China

Funds:

The financial support from the National Natural Science Foundation of China (22278419, 21978316, 22108289, 22172188), the Ministry of Science and Technology of China (2018YFB0604700), Suzhou Key Technology Research (Social Development) Project (2023ss06).

  • Received date 01 February 2023, Accepted date 22 April 2023, RevRecd date 18 April 2023, Publish date 28 April 2023,
    Abstract
  • Efficient and selective glucose-to-fructose isomerization is a crucial step for production of oxygenated chemicals derived from sugars, which is usually catalyzed by base or Lewis acid heterogeneous catalyst. However, high yield and selectivity of fructose cannot be simultaneously obtained under mild conditions which hamper the scale of application compared with enzymatic catalysis. Herein, a Li-promoted C3N4 catalyst was exploited which afforded an excellent fructose yield (40.3 wt%) and selectivity (99.5%) from glucose in water at 50 ℃, attributed to the formation of stable Li-N bond to strengthen the basic sites of catalysts. Furthermore, the so-formed N6-Li-H2O active site on Li-C3N4 catalyst in aqueous phase changes the local electronic structure and strengthens the deprotonation process during glucose isomerization into fructose. The superior catalytic performance which is comparable to biological pathway suggests promising applications of lithium containing heterogeneous catalyst in biomass refinery.

     

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