Volume 9 Issue 8
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Liu Han, Cheng-wei Wang, Shan-shan Luo, Ying-tang Zhou, Bing Li, Ming Liu. Facet effects on bimetallic ZnSn hydroxide microcrystals for selective electrochemical CO2 reduction. Green Energy&Environment, 2024, 9(8): 1314-1320. doi: 10.1016/j.gee.2023.04.004
Citation: Liu Han, Cheng-wei Wang, Shan-shan Luo, Ying-tang Zhou, Bing Li, Ming Liu. Facet effects on bimetallic ZnSn hydroxide microcrystals for selective electrochemical CO2 reduction. Green Energy&Environment, 2024, 9(8): 1314-1320. doi: 10.1016/j.gee.2023.04.004
shu

Facet effects on bimetallic ZnSn hydroxide microcrystals for selective electrochemical CO2 reduction

doi: 10.1016/j.gee.2023.04.004

  • a. School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Heilongjiang Province, 150000, China;

  • b. National Engineering Research Center for Marine Aquaculture, Marine Science and Technology College, Zhejiang Ocean University, Zhoushan, Zhejiang Province, 316004, China

Funds:

This work was conducted under the Fundamental Research Funds for the Central Universities and the Fundamental Science Research of Harbin Institute of Technology (No. AUGA2160100119

AUGA5710001120).

AUGA9803100120

  • Received date 11 January 2023, Accepted date 09 April 2023, RevRecd date 06 March 2023, Publish date 11 April 2023,
    Abstract
  • Employing crystal facets to regulate the catalytic properties in electrocatalytic carbon dioxide reduction reaction (eCO2RR) has been well demonstrated on electrocatalysts containing single metals but rarely explored for bimetallic systems. Here, we synthesize ZnSn(OH)6 (ZSO) microcrystals (MCs) with distinct facets and investigate the facet effects in eCO2RR. Electrochemical studies and in situ Fourier Transform Infrared Spectroscopy (in situ-FTIR) reveal that ZSO MCs produce mainly C1 products of HCOOH and CO. The {111} facet of the ZSO MCS exhibits higher selectivity and faradaic efficiency (FE) than that of the {100} facet over a wide range of potentials (-0.9 V ∼ -1.3 V versus RHE). Density Functional Theory (DFT) calculations elucidate that the {111} facet is favorable to the adsorption/activation of CO2 molecules, the formation of intermediate in the rate-determining step, and the desorption of C1 products of CO and HCOOH molecules.

     

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