Volume 9 Issue 8
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Rui Zhang, Biao Chen, Yuhan Ma, Yue Li, Junwei Sha, Liying Ma, Chunsheng Shi, Naiqin Zhao. Armoring lithium metal anode with soft–rigid gradient interphase toward high-capacity and long-life all-solid-state battery. Green Energy&Environment, 2024, 9(8): 1279-1289. doi: 10.1016/j.gee.2023.02.006
Citation: Rui Zhang, Biao Chen, Yuhan Ma, Yue Li, Junwei Sha, Liying Ma, Chunsheng Shi, Naiqin Zhao. Armoring lithium metal anode with soft–rigid gradient interphase toward high-capacity and long-life all-solid-state battery. Green Energy&Environment, 2024, 9(8): 1279-1289. doi: 10.1016/j.gee.2023.02.006
shu

Armoring lithium metal anode with soft–rigid gradient interphase toward high-capacity and long-life all-solid-state battery

doi: 10.1016/j.gee.2023.02.006

  • a. School of Materials Science and Engineering and Tianjin Key Laboratory of Composite and Functional Materials, Tianjin University, Tianjin, 300350, China;

  • b. Collaborative Innovation Centre of Chemical Science and Engineering, Tianjin, 300072, China;

  • c. Joint School of National University of Singapore and Tianjin University, International Campus of Tianjin University, Fuzhou, 350207, China;

  • d. Department of Chemical and Biomolecular Engineering, National University of Singapore, 119077, Singapore

Funds:

The authors acknowledge the financial support by the National Natural Science Foundation of China (grant no. 51772206).

  • Received date 17 November 2022, Accepted date 09 February 2023, RevRecd date 22 January 2023, Publish date 15 February 2023,
    Abstract
  • Solid polymer electrolytes (SPEs) are highly promising for realizing high-capacity, low-cost, and safe Li metal batteries. However, the Li dendritic growth and side reactions between Li and SPEs also plague these systems. Herein, a fluorinated lithium salt coating (FC) with organic-inorganic gradient and soft–rigid feature is introduced on Li surface as an artificial protective layer by the in-situ reaction between Li metal and fluorinated carboxylic acid. The FC layer can improve the interface stability and wettability between Li and SPEs, assist the transport of Li ions, and guide Li nucleation, contributing to a dendrite-free Li deposition and long-lifespan Li metal batteries. The symmetric cell with FC-Li anodes exhibits a high areal capacity of 1 mAh cm-2 at 0.5 mA cm-2, and an ultra-long lifespan of 2000 h at a current density of 0.1 mA cm-2. Moreover, the full cell paired with the LiFePO4 cathode exhibits improved cycling stability, remaining 83.7% capacity after 500 cycles at 1 C. When matching with the S cathode, the FC layer can prevent the shuttle effect, contributing to stable and high-capacity Li–S battery. This work provided a promising way for the construction of stable all-solid-state lithium metal batteries with prolonged lifespan.

     

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