Volume 9 Issue 8
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Article Navigation >  Green Energy&Environment  > 2024  >  9(8): 1267-1278
Lin Yuan, Yancheng Hu, Guangyi Li, Fengan Han, Aiqin Wang, Yu Cong, Tao Zhang, Feng Wang, Ning Li. Biomass-based production of trimellitic and trimesic acids. Green Energy&Environment, 2024, 9(8): 1267-1278. doi: 10.1016/j.gee.2023.02.004
Citation: Lin Yuan, Yancheng Hu, Guangyi Li, Fengan Han, Aiqin Wang, Yu Cong, Tao Zhang, Feng Wang, Ning Li. Biomass-based production of trimellitic and trimesic acids. Green Energy&Environment, 2024, 9(8): 1267-1278. doi: 10.1016/j.gee.2023.02.004
shu

Biomass-based production of trimellitic and trimesic acids

doi: 10.1016/j.gee.2023.02.004

  • a. CAS Key Laboratory of Science and Technology on Applied Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China;

  • b. University of Chinese Academy of Sciences, 19 A Yuquan Road, Shijingshan District, Beijing, 100049, China;

  • c. School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou, 221116, Jiangsu, China;

  • d. State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian, 116023, China

Funds:

22078318), DICP (Grant: DICP I201944), the Joint Fund of the Yulin University and the Dalian National Laboratory for Clean Energy (grant: YLU-DNL Fund 2021020).

2022YFB4201802), National Natural Science Foundation of China (no. 21721004

This work was supported by the National Key R&

D Program of China (no. 2022YFA1504902

22178335

21801239

  • Received date 07 November 2022, Accepted date 06 February 2023, RevRecd date 14 January 2023, Publish date 09 February 2023,
    Abstract
  • The production of industrial chemicals with renewable biomass feedstock holds potential to aid the world in pursuing a carbon-neutral society. Trimellitic and trimesic acids are important commodity chemicals in industry that are prepared by the oxidation of petroleum-derived trimethylbenzene. To reduce the dependence on the limited oil source, we develop a potential sustainable alternative towards trimellitic and trimesic acids using biomass-based 2-methyl-2,4-pentandiol (MPD), acrylate and crotonaldehyde as starting materials. The process for trimellitic acid includes dehydration/D-A reaction of MPD and acrylate, flow aromatization over Pd/C catalyst, hydrolysis and catalytic aerobic oxidation (60% overall yield). The challenging regioselectivity issue of D-A reaction is tackled by a matched combination of temperature and deep eutectic solvent ChCl/HCO2H. Crotonaldehyde can also participate in the reaction, followed by Pd/C-catalyzed decarbonylation/dehydrogenation and oxidation to provide trimesic acid in 54% overall yield. Life cycle assessment implies that compared to conventional fossil process, our biomass-based routes present a potential in reducing carbon emissions.

     

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