Volume 9 Issue 6
Jun.  2024
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Article Navigation >  Green Energy&Environment  > 2024  >  9(6): 1058-1067
Yi Wang, Yangyang Wang, Chang Liu, Dongjian Shi, Weifu Dong, Baoliang Peng, Liangliang Dong, Mingqing Chen. Biomimetic MXene membranes with negatively thermo-responsive switchable 2D nanochannels for graded molecular sieving. Green Energy&Environment, 2024, 9(6): 1058-1067. doi: 10.1016/j.gee.2023.01.004
Citation: Yi Wang, Yangyang Wang, Chang Liu, Dongjian Shi, Weifu Dong, Baoliang Peng, Liangliang Dong, Mingqing Chen. Biomimetic MXene membranes with negatively thermo-responsive switchable 2D nanochannels for graded molecular sieving. Green Energy&Environment, 2024, 9(6): 1058-1067. doi: 10.1016/j.gee.2023.01.004
shu

Biomimetic MXene membranes with negatively thermo-responsive switchable 2D nanochannels for graded molecular sieving

doi: 10.1016/j.gee.2023.01.004

  • a. The Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu, 214122, China;

  • b. International Research Center for Photo-responsive Molecules and Materials, Jiangnan University, Wuxi, Jiangsu, 214122, China;

  • c. Research Institute of Petroleum Exploration & Development (RIPED), PetroChina;Key Laboratory of Oilfield Chemistry, CNPC, Beijing, 100083, China

Funds:

This study was supported by the National Nature Science Foundation of China (No. 22278179, U23A20688), the National Key Research and Development Program of China (2021YFB3802600), the Fundamental Research Funds for the Central Universities (JUSRP622035), National First-Class Discipline Program of Light Industry Technology and Engineering (LIFE2018-19), MOE &

SAFEA for the 111 Project (B13025), Natural Science Foundation of Xinjiang Uygur Autonomous Region (2022D01D030).

  • Received date 18 November 2022, Accepted date 18 January 2023, RevRecd date 04 January 2023, Publish date 24 January 2023,
    Abstract
  • Negatively thermo-responsive 2D membranes, which mimic the stomatal opening/closing of plants, have drawn substantial interest for tunable molecular separation processes. However, these membranes are still restricted significantly on account of low water permeability and poor dynamic tunability of 2D nanochannels under temperature stimulation. Here, we present a biomimetic negatively thermo-responsive MXene membrane by covalently grafting poly (N-isopropylacrylamide) (PNIPAm) onto MXene nanosheets. The uniformly grafted PNIPAm polymer chains can enlarge the interlayer spacings for increasing water permeability while also allowing more tunability of 2D nanochannels for enhancing the capability of gradually separating multiple molecules of different sizes. As expected, the constructed membrane exhibits ultrahigh water permeance of 95.6 L m-2 h-1 bar-1 at 25 ℃, which is eight-fold higher than the state-of-the-art negatively thermo-responsive 2D membranes. Moreover, the highly temperature-tunable 2D nanochannels enable the constructed membrane to perform excellent graded molecular sieving for dye- and antibiotic-based ternary mixtures. This strategy provides new perspectives in engineering smart 2D membrane and expands the scope of temperature-responsive membranes, showing promising applications in micro/nanofluidics and molecular separation.

     

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