Volume 9 Issue 2
Feb.  2024
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Article Navigation >  Green Energy&Environment  > 2024  >  9(2): 390-402
Ruijia Hu, Ming Li, Tao Shen, Xin Wang, Zhuohua Sun, Xinning Bao, Kequan Chen, Kai Guo, Lei Ji, Hanjie Ying, Pingkai Ouyang, Chenjie Zhu. A sustainable process to 100% bio-based nylons integrated chemical and biological conversion of lignocellulose. Green Energy&Environment, 2024, 9(2): 390-402. doi: 10.1016/j.gee.2022.11.004
Citation: Ruijia Hu, Ming Li, Tao Shen, Xin Wang, Zhuohua Sun, Xinning Bao, Kequan Chen, Kai Guo, Lei Ji, Hanjie Ying, Pingkai Ouyang, Chenjie Zhu. A sustainable process to 100% bio-based nylons integrated chemical and biological conversion of lignocellulose. Green Energy&Environment, 2024, 9(2): 390-402. doi: 10.1016/j.gee.2022.11.004
shu

A sustainable process to 100% bio-based nylons integrated chemical and biological conversion of lignocellulose

doi: 10.1016/j.gee.2022.11.004

  • a. College of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, Nanjing, China;

  • b. National Engineering Research Center for Biotechnology, Nanjing Tech University, Nanjing, China;

  • c. Beijing Key Laboratory of Lignocellulosic Chemistry, Beijing Forestry University, Beijing, China

Funds:

The authors thank the financial support by National Key Research and Development Program of China (Grant No.: 2023YFA0913604)

Program of National Natural Science Foundation of China (Grant No.: 22178170,22378195)

Program of National Natural Science Foundation of China (Grant No. 22208155)

Six talent peaks project in Jiangsu Province (SWYY-045)

Jiangsu Province Natural Science Foundation for Young Scholars (Grant No. BK20210552).

  • Received date 06 October 2022, Accepted date 22 November 2022, RevRecd date 15 November 2022, Publish date 25 November 2022,
    Abstract
  • Considerable progress has been made in recent years to the development of sustainable polymers from bio-based feedstocks. In this study, 100% bio-based nylons were prepared via an integrated chemical and biological process from lignocellulose. These novel nylons were obtained by the melt polymerization of 3-propyladipic acid derived from lignin and 1,5-pentenediamine/1,4-butanediamine derived from carbohydrate sugar. Central to the concept is a three-step noble metal free catalytic chemical funnelling sequence (Raney Ni mediated reductive catalytic fractionation - reductive funnelling - oxidative funnelling), which allowed for obtaining a single component 3-propyladipic acid from lignin with high efficiency. The structural and thermodynamic properties of the obtained nylons have been systematically investigated, and thus obtained transparent bio-based nylons exhibited higher Mw (>32,000) and excellent thermal stability (Td5% > 265 ℃). Considering their moderate Tg and good melt strength, these transparent bio-based nylons could serve as promising functional additives or temperature-responsive materials.

     

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