Volume 9 Issue 6
Jun.  2024
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Article Navigation >  Green Energy&Environment  > 2024  >  9(6): 1027-1034
Dan Yang, Ying Yang, Haoran Du, Yongsheng Ji, Mingyuan Ma, Yujun Pan, Xiaoqun Qi, Quan Sun, Kaiyuan Shi, Long Qie. An efficient recycling strategy to eliminate the residual “impurities” while heal the damaged structure of spent graphite anodes. Green Energy&Environment, 2024, 9(6): 1027-1034. doi: 10.1016/j.gee.2022.11.003
Citation: Dan Yang, Ying Yang, Haoran Du, Yongsheng Ji, Mingyuan Ma, Yujun Pan, Xiaoqun Qi, Quan Sun, Kaiyuan Shi, Long Qie. An efficient recycling strategy to eliminate the residual “impurities” while heal the damaged structure of spent graphite anodes. Green Energy&Environment, 2024, 9(6): 1027-1034. doi: 10.1016/j.gee.2022.11.003
shu

An efficient recycling strategy to eliminate the residual “impurities” while heal the damaged structure of spent graphite anodes

doi: 10.1016/j.gee.2022.11.003

  • a. Institute of New Energy for Vehicles, School of Materials Science and Engineering, Tongji University, Shanghai, 201804, China;

  • b. State Key Laboratory of Material Processing and Die & Mold Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan, 430074, China;

  • c. Shuangdeng Group Co., Ltd., Taizhou, 225500, China;

  • d. School of Materials Science and Engineering, Sun Yat-Sen University, Guangzhou, 510275, China

Funds:

This work was supported by the National Key R&

D Program of China (2021YFB2400300), Key R&

D Program of Hubei Province of China (2020BAB088), National Natural Science Foundation of China (52002277), the Fundamental Research Funds for the Central Universities (2021GCRC001), and Guangdong Basic and Applied Basic Reuter Foundation (2021A1515011748).

  • Received date 26 September 2022, Accepted date 15 November 2022, RevRecd date 09 November 2022, Publish date 18 November 2022,
    Abstract
  • The recycling of graphite from spent lithium-ion batteries (LIBs) is overlooked due to its relatively low added value and the lack of efficient recovering methods. To reuse the spent graphite anodes, we need to eliminate their useless components (mainly the degraded solid electrolyte interphase, SEI) and reconstruct their damaged structure. Herein, a facile and efficient strategy is proposed to recycle the spent graphite on the basis of the careful investigation of the composition of the cycled graphite anodes and the rational design of the regeneration processes. The regenerated graphite, which is revitalized by calcination treatment and acid leaching, delivers superb rate performance and a high specific capacity of 370 mAh g-1 (∼99% of its theoretical capacity) after 100 cycles at 0.1 C, superior to the commercial graphite anodes. The improved electrochemical performance could be attributed to unchoked Li+ transport channels and enhanced charge transfer reaction due to the effective destruction of the degraded SEI and the full recovery of the damaged structure of the spent graphite. This work clarifies that the electrochemical performance of the regenerated graphite could be deteriorated by even a trace amount of the residual “impurity” and provides a facile method for the efficient regeneration of graphite anodes.

     

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    • References(43)
  • [1]
    Lithium-ion Battery Market Size, Share & Trends Analysis Report by Product (LCO, LFP, NCA, LMO, LTO, Lithium Nickel Manganese Cobalt), by Application, by Region, and Segment Forecasts, 2021 – 2028, https://www.grandviewresearch.com/industry-analysis/lithium-ion-battery-market.
    [2]
    H.E. Melin, M.A. Rajaeifar, A.Y. Ku, A. Kendall, G. Harper, O. Heidrich, Science 373 (2021) 384-387.
    [3]
    S. Zhao, K. Yan, J. Zhang, B. Sun, G. Wang, Angew. Chem. Int. Ed. 60 (2021) 2208-2220.
    [4]
    X. Ma, M. Chen, Z. Zheng, D. Bullen, J. Wang, C. Harrison, E. Gratz, Y. Lin, Z. Yang, Y. Zhang, F. Wang, D. Robertson, S.-B. Son, I. Bloom, J. Wen, M. Ge, X. Xiao, W.-K. Lee, M. Tang, Q. Wang, J. Fu, Y. Zhang, B.C. Sousa, R. Arsenault, P. Karlson, N. Simon, Y. Wang, Joule 5 (2021) 2955-2970.
    [5]
    M. Chen, X. Ma, B. Chen, R. Arsenault, P. Karlson, N. Simon, Y. Wang, Joule 3 (2019) 2622-2646.
    [6]
    X. Ma, L. Azhari, Y. Wang, Chem 7 (2021) 2843-2847.
    [7]
    E. Fan, L. Li, Z. Wang, J. Lin, Y. Huang, Y. Yao, R. Chen, F. Wu, Chem. Rev. 120 (2020) 7020-7063.
    [8]
    G. Harper, R. Sommerville, E. Kendrick, L. Driscoll, P. Slater, R. Stolkin, A. Walton, P. Christensen, O. Heidrich, S. Lambert, A. Abbott, K. Ryder, L. Gaines, P. Anderson, Nature 575 (2019) 75-86.
    [9]
    J.J. Roy, S. Rarotra, V. Krikstolaityte, K.W. Zhuoran, Y.D.-I. Cindy, X.Y. Tan, M. Carboni, D. Meyer, Q. Yan, M. Srinivasan, Adv. Mater. 34 (2022) 2103346.
    [10]
    R.E. Ciez, J.F. Whitacre, Nat. Sustain. 2 (2019) 148-156.
    [11]
    J. Xiao, J. Li, Z. Xu, Environ. Sci. Technol. 51 (2017) 11960-11966.
    [12]
    H. Dang, B. Wang, Z. Chang, X. Wu, J. Feng, H. Zhou, W. Li, C. Sun, ACS Sustain. Chem. Eng. 6 (2018) 13160-13167.
    [13]
    Z. Liang, C. Cai, G. Peng, J. Hu, H. Hou, B. Liu, S. Liang, K. Xiao, S. Yuan, J. Yang, ACS Sustain. Chem. Eng. 9 (2021) 5750-5767.
    [14]
    L.-P. He, S.-Y. Sun, Y.-Y. Mu, X.-F. Song, J.-G. Yu, ACS Sustain. Chem. Eng. 5 (2016) 714-721.
    [15]
    P. Xu, Z. Yang, X. Yu, J. Holoubek, H. Gao, M. Li, G. Cai, I. Bloom, H. Liu, Y. Chen, K. An, K.Z. Pupek, P. Liu, Z. Chen, ACS Sustain. Chem. Eng. 9 (2021) 4543-4553.
    [16]
    B. Gangaja, S. Nair, D. Santhanagopalan, ACS Sustain. Chem. Eng. 9 (2021) 4711-4721.
    [17]
    B.K. Biswal, U.U. Jadhav, M. Madhaiyan, L. Ji, E.-H. Yang, B. Cao, ACS Sustain. Chem. Eng. 6 (2018) 12343-12352.
    [18]
    Graphite prices show resilience amid growing demand-side concerns, https://www.fastmarkets.com/insights/graphite-prices-show-resilience-amid-growing-demand-side-concerns.
    [19]
    S. Natarajan, V. Aravindan, Adv. Energy Mater. 10 (2020) 2002238.
    [20]
    M. Winter, J.O. Besenhard, M.E. Spahr, P. Novak, Adv. Mater. 10 (1998) 725-763.
    [21]
    J. Asenbauer, T. Eisenmann, M. Kuenzel, A. Kazzazi, Z. Chen, D. Bresser, Sustain. Energ. Fuels 4 (2020) 5387-5416.
    [22]
    E. Peled, D. Golodnitsky, G. Ardel, J. Electrochem. Soc. 144 (1997) L208-L210.
    [23]
    X. Yu, A. Manthiram, Energy Environ. Sci. 11 (2018) 527-543.
    [24]
    X. Meng, Y. Xu, H. Cao, X. Lin, P. Ning, Y. Zhang, Y.G. Garcia, Z. Sun, Green Energy & Environment 5 (2020) 22-36.
    [25]
    D.J. Xiong, L.D. Ellis, K.J. Nelson, T. Hynes, R. Petibon, J.R. Dahn, J. Electrochem. Soc. 163 (2016) A3069-A3077.
    [26]
    M. Metzger, H.A. Gasteiger, Energy Environ. Mater. 5 (2022) 688-692.
    [27]
    S.-Y. Sun, N. Yao, C.-B. Jin, J. Xie, X.-Y. Li, M.-Y. Zhou, X. Chen, B.-Q. Li, X.-Q. Zhang, Q. Zhang, Angew. Chem. Int. Ed. (2022) e202208743.
    [28]
    S.K. Heiskanen, J. Kim, B.L. Lucht, Joule 3 (2019) 2322-2333.
    [29]
    D. Aurbach, E. Zinigrad, Y. Cohen, H. Teller, Solid State Ionics 148 (2002) 405-416.
    [30]
    H. Wang, Y. Huang, C. Huang, X. Wang, K. Wang, H. Chen, S. Liu, Y. Wu, K. Xu, W. Li, Electrochim. Acta 313 (2019) 423-431.
    [31]
    L. Ye, C. Wang, L. Cao, H. Xiao, J. Zhang, B. Zhang, X. Ou, Green Energy & Environment 6 (2021) 725-733.
    [32]
    B. Niu, J. Xiao, Z. Xu, J. Hazard. Mater. 439 (2022).
    [33]
    G.V. Zhuang, K. Xu, H. Yang, T.R. Jow, P.N. Ross, J. Phys. Chem. B 109 (2005) 17567-17573.
    [34]
    F. Wu, S. Fang, M. Kuenzel, A. Mullaliu, J.-K. Kim, X. Gao, T. Diemant, G.-T. Kim, S. Passerini, Joule 5 (2021) 2177-2194.
    [35]
    C. Yan, X.-B. Cheng, Y. Tian, X. Chen, X.-Q. Zhang, W.-J. Li, J.-Q. Huang, Q. Zhang, Adv. Mater. 30 (2018) 1707629.
    [36]
    T. Szabo, O. Berkesi, I. Dekany, Carbon 43 (2005) 3186-3189.
    [37]
    S.J. An, J. Li, C. Daniel, D. Mohanty, S. Nagpure, D.L. Wood, Carbon 105 (2016) 52-76.
    [38]
    S. Rahim, A. Naveed, A. R. Amir, C. Yang, Y. Chen, J. Hu, X. Zhao, Y. Peng, Z. Deng, Acta Phys.-Chim. Sin. 35 (2019) 1382-1390.
    [39]
    A.C. Ferrari, J.C. Meyer, V. Scardaci, C. Casiraghi, M. Lazzeri, F. Mauri, S. Piscanec, D. Jiang, K.S. Novoselov, S. Roth, A.K. Geim, Phys. Rev. Lett. 97 (2006) 187401.
    [40]
    A.C. Ferrari, Solid State Commun. 143 (2007) 47-57.
    [41]
    A.C. Ferrari, J. Robertson, Phys. Rev. B 61 (2000) 14095-14107.
    [42]
    O.N. Shornikova, E.V. Kogan, N.E. Sorokina, V.V. Avdeev, Russ. J. Phys. Chem. A 83 (2009) 1022-1025.
    [43]
    L. Qie, W.-M. Chen, Z.-H. Wang, Q.-G. Shao, X. Li, L.-X. Yuan, X.-L. Hu, W.-X. Zhang, Y.-H. Huang, Adv. Mater. 24 (2012) 2047-2050.
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