Volume 9 Issue 3
Mar.  2024
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Article Navigation >  Green Energy&Environment  > 2024  >  9(3): 565-572
Huarong Fan, Yubing Si, Yiming Zhang, Fulong Zhu, Xin Wang, Yongzhu Fu. Grapevine-like high entropy oxide composites boost high-performance lithium sulfur batteries as bifunctional interlayers. Green Energy&Environment, 2024, 9(3): 565-572. doi: 10.1016/j.gee.2022.11.001
Citation: Huarong Fan, Yubing Si, Yiming Zhang, Fulong Zhu, Xin Wang, Yongzhu Fu. Grapevine-like high entropy oxide composites boost high-performance lithium sulfur batteries as bifunctional interlayers. Green Energy&Environment, 2024, 9(3): 565-572. doi: 10.1016/j.gee.2022.11.001
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Grapevine-like high entropy oxide composites boost high-performance lithium sulfur batteries as bifunctional interlayers

doi: 10.1016/j.gee.2022.11.001

  • a. College of Chemistry and Center of Green Catalysis, Zhengzhou University, Zhengzhou, 450001, China;

  • b. School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu, 611731, China

Funds:

This work was financially supported by the Certificate of postdoctoral research grant in Henan province, the Natural Science Foundation of Henan province (Grant No. 212300410281) and the National Natural Science Foundation of China (Grant No. 21975225). The authors thank for the support of parallel high-performance computing of National Supercomputing Center in Zhengzhou.

  • Received date 02 September 2022, Accepted date 03 November 2022, RevRecd date 24 October 2022, Publish date 04 November 2022,
    Abstract
  • Lithium-sulfur batteries (LSBs) with high energy densities have been demonstrated the potential for energy-intensive demand applications. However, their commercial applicability is hampered by hysteretic electrode reaction kinetics and the shuttle effect of lithium polysulfides (LiPSs). In this work, an interlayer consisting of high-entropy metal oxide (Cu0.7Fe0.6Mn0.4Ni0.6Sn0.5)O4 grown on carbon nanofibers (HEO/CNFs) is designed for LSBs. The CNFs with highly porous networks provide transport pathways for Li+ and e-, as well as a physical sieve effect to limit LiPSs crossover. In particular, the grapevine-like HEO nanoparticles generate metal-sulfur bonds with LiPSs, efficiently anchoring active materials. The unique structure and function of the interlayer enable the LSBs with superior electrochemical performance, i.e., the high specific capacity of 1381 mAh g-1 at 0.1 C and 561 mAh g-1 at 6 C. This work presents a facile strategy for exploiting high-performance LSBs.

     

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