Volume 9 Issue 4
Apr.  2024
Turn off MathJax
Article Contents
Article Navigation >  Green Energy&Environment  > 2024  >  9(4): 771-776
Lu Wang, Feifei Wang, Zhe Ding, Yingxin Liu, Ziyi Zhang, Chunpeng Yang, Kian Ping Loh, Quan-Hong Yang. Bilayer separator enabling dendrite-free zinc anode with ultralong lifespan >5000 h. Green Energy&Environment, 2024, 9(4): 771-776. doi: 10.1016/j.gee.2022.09.013
Citation: Lu Wang, Feifei Wang, Zhe Ding, Yingxin Liu, Ziyi Zhang, Chunpeng Yang, Kian Ping Loh, Quan-Hong Yang. Bilayer separator enabling dendrite-free zinc anode with ultralong lifespan >5000 h. Green Energy&Environment, 2024, 9(4): 771-776. doi: 10.1016/j.gee.2022.09.013
shu

Bilayer separator enabling dendrite-free zinc anode with ultralong lifespan >5000 h

doi: 10.1016/j.gee.2022.09.013

  • a. Joint School of National University of Singapore and Tianjin University, International Campus of Tianjin University, Fuzhou, 350207, China;

  • b. Nanoyang Group, State Key Laboratory of Chemical Engineering, School of Chemical Engineering and Technology, Tianjin University, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300072, China;

  • c. Haihe Laboratory of Sustainable Chemical Transformations, Tianjin, 300192, China;

  • d. Department of Chemistry, National University of Singapore, 117543, Singapore;

  • e. Institute of Process Engineering, Chinese Academy of Sciences, Beijing, 100190, China

Funds:

This work was supported by grants from the National Key Research and Development Program of China (No. 2021YFF0500600), the Haihe Laboratory of Sustainable Chemical Transformations, and the Fundamental Research Funds for the Central Universities. We appreciate Neware Technology Co., Ltd for their battery test systems in the TJU Nanoyang-Neware Joint Laboratory for Energy Innovation.

  • Received date 28 June 2022, Accepted date 29 September 2022, RevRecd date 19 September 2022, Publish date 03 October 2022,
    Abstract
  • Aqueous zinc (Zn) batteries with Zn metal anodes are promising clean energy storage devices with intrinsic safety and low cost. However, Zn dendrite growth severely restricts the use of Zn anodes. To effectively suppress Zn dendrite growth, we propose a bilayer separator consisting of commercial butter paper and glass fiber membrane. The dense cellulose-based butter paper (BP) with low zincophilicity and high mechanical properties prevents the pore-filling behavior of deposited Zn and related separator piercing, effectively suppressing the Zn dendrite growth. As a result, the bilayer separators endow the Zn||Zn symmetrical batteries with a superlong cycling life of Zn anodes (over 5000 h) at 0.5 mA cm-2 and the full batteries enhanced capacity retention, demonstrating the advancement of the bilayer separator to afford excellent cyclability of aqueous metal batteries.

     

    • FullText(HTML)
  • loading
    • References(44)
  • [1]
    J. Huang, Z. Guo, Y. Ma, D. Bin, Y. Wang, Y. Xia, Small Methods 3 (2019) 1800272.
    [2]
    D.L. Chao, W.H. Zhou, F.X. Xie, C. Ye, H. Li, M. Jaroniec, S.Z. Qiao, Sci. Adv. 6 (2020) eaba4098.
    [3]
    H. Kim, J. Hong, K.Y. Park, H. Kim, S.W. Kim, K. Kang, Chem. Rev. 114 (2014) 11788-11827.
    [4]
    B. Tang, L. Shan, S. Liang, J. Zhou, Energy Environ. Sci. 12 (2019) 3288-3304.
    [5]
    D. Kundu, B.D. Adams, V. Duffort, S.H. Vajargah, L.F. Nazar, Nat. Energy 1 (2016) 16119.
    [6]
    J. Zheng, Q. Zhao, T. Tang, J. Yin, C.D. Quilty, G.D. Renderos, X. Liu, Y. Deng, L. Wang, D.C. Bock, C. Jaye, D. Zhang, E.S. Takeuchi, K.J. Takeuchi, A.C. Marschilok, L.A. Archer, Science 366 (2019) 645-648.
    [7]
    J.F. Parker, C.N. Chervin, I.R. Pala, M. Machler, D.R.J.S. Rolison, Science 356 (2017) 415-418.
    [8]
    G. Fang, J. Zhou, A. Pan, S. Liang, ACS Energy Lett. 3 (2018) 2480-2501.
    [9]
    N. Wang, S. Zhai, Y. Ma, X. Tan, K. Jiang, W. Zhong, W. Zhang, N. Chen, W. Chen, S. Li, G. Han, Z. Li, Energy Storage Mater. 43 (2021) 585-594.
    [10]
    S. Zhai, N. Wang, X. Tan, K. Jiang, Z. Quan, Y. Li, Z. Li, Adv. Funct. Mater. 31 (2021) 2008894.
    [11]
    Z. Cao, P. Zhuang, X. Zhang, M. Ye, J. Shen, P.M. Ajayan, Adv. Energy Mater. 10 (2020) 2001599.
    [12]
    Q. Yang, Q. Li, Z. Liu, D. Wang, Y. Guo, X. Li, Y. Tang, H. Li, B. Dong, C. Zhi, Adv. Mater. 32 (2020) 2001854.
    [13]
    C. Li, X. Xie, S. Liang, J. Zhou, Energy Environ. Mater. 3 (2020) 146-159.
    [14]
    L. Ma, M.A. Schroeder, O. Borodin, T.P. Pollard, M.S. Ding, C. Wang, K. Xu, Nat. Energy 5 (2020) 743-749.
    [15]
    T. Foroozan, V. Yurkiv, S. Sharifi-Asl, R. Rojaee, F. Mashayek, R. Shahbazian-Yassar, ACS Appl. Mater. Interfaces 11 (2019) 44077-44089.
    [16]
    Z. Yi, G. Chen, F. Hou, L. Wang, J. Liang, Adv. Energy Mater. 11 (2021) 2003065.
    [17]
    X. Jia, C. Liu, Z.G. Neale, J. Yang, G. Cao, Chem. Rev. 120 (2020) 7795-7866.
    [18]
    Q. Zhang, J. Luan, Y. Tang, X. Ji, H. Wang, Angew. Chem. Int. Ed. 59 (2020) 13180-13191.
    [19]
    G. Liang, J. Zhu, B. Yan, Q. Li, A. Chen, Z. Chen, X. Wang, B. Xiong, J. Fan, J. Xu, C. Zhi, Energy Environ. Sci. 15 (2022) 1086-1096.
    [20]
    F. Wang, H. Lu, H. Li, J. Li, L. Wang, D. Han, J. Gao, C. Geng, C. Cui, Z. Zhang, Z. Weng, C. Yang, J. Lu, F. Kang, Q.-H. Yang, Energy Storage Mater. 50 (2022) 641-647.
    [21]
    D. Han, C. Cui, K. Zhang, Z. Wang, J. Gao, Y. Guo, Z. Zhang, S. Wu, L. Yin, Z. Weng, F. Kang, Q.-H. Yang, Nat. Sustain. 5 (2021) 205-213.
    [22]
    F. Wang, O. Borodin, T. Gao, X. Fan, W. Sun, F. Han, A. Faraone, J.A. Dura, K. Xu, C. Wang, Nat. Mater. 17 (2018) 543-549.
    [23]
    Z. Kang, C. Wu, L. Dong, W. Liu, J. Mou, J. Zhang, Z. Chang, B. Jiang, G. Wang, F. Kang, C. Xu, ACS Sustain. Chem. Eng. 7 (2019) 3364-3371.
    [24]
    Y. Zeng, X. Zhang, R. Qin, X. Liu, P. Fang, D. Zheng, Y. Tong, X. Lu, Adv. Mater. 31 (2019) 1903675.
    [25]
    M.F. Lagadec, R. Zahn, V. Wood, Nat. Energy 4 (2019) 16-25.
    [26]
    H. Lee, M. Yanilmaz, O. Toprakci, K. Fu, X. Zhang, Energy Environ. Sci. 7 (2014) 3857-3886.
    [27]
    B.-S. Lee, S. Cui, X. Xing, H. Liu, X. Yue, V. Petrova, H.-D. Lim, R. Chen, P. Liu, ACS Appl. Mater. Interfaces 10 (2018) 38928-38935.
    [28]
    Y. Zhang, X. Li, L. Fan, Y. Shuai, N. Zhang, Cell Reports Physical Science 3 (2022) 100824.
    [29]
    Y. Qin, P. Liu, Q. Zhang, Q. Wang, D. Sun, Y. Tang, Y. Ren, H. Wang, Small 16 (2020) 2003106.
    [30]
    Y. Zhang, G. Yang, M.L. Lehmann, C. Wu, L. Zhao, T. Saito, Y. Liang, J. Nanda, Y. Yao, Nano Lett. 6 (2021) 10446-10452.
    [31]
    D. Zhou, X. Tang, X. Guo, P. Li, D. Shanmukaraj, H. Liu, X. Gao, Y. Wang, T. Rojo, M. Armand, G. Wang, Angew. Chem. Int. Ed. 59 (2020) 16725-16734.
    [32]
    Q. Ni, B. Kim, C. Wu, K. Kang, Adv. Mater. 34 (2022) 2108206.
    [33]
    Y. Liang, D. Ma, N. Zhao, Y. Wang, M. Yang, J. Ruan, G. Yang, H. Mi, C. He, P. Zhang, Adv. Funct. Mater. 32 (2022) 2112936.
    [34]
    C. Li, Z. Sun, T. Yang, L. Yu, N. Wei, Z. Tian, J. Cai, J. Lv, Y. Shao, M.H. Rummeli, J. Sun, Z. Liu, Adv. Mater. 32 (2020) 2003425.
    [35]
    Z. Hou, Y. Gao, H. Tan, B. Zhang, Nat. Commun. 12 (2021) 3083.
    [36]
    W. Zhou, M. Chen, Q. Tian, J. Chen, X. Xu, C.-P. Wong, Energy Storage Mater. 44 (2022) 57-65.
    [37]
    L. Jabbour, R. Bongiovanni, D. Chaussy, C. Gerbaldi, D. Beneventi, Cellulose 20 (2013) 1523-1545.
    [38]
    Y. Guo, W. Cai, Y. Lin, Y. Zhang, S. Luo, K. Huang, H. Wu, Y. Zhang, Energy Storage Mater. 50 (2022) 580-588.
    [39]
    Y. Zhu, K. Cao, W. Cheng, S. Zeng, S. Dou, W. Chen, D. Zhao, H. Yu, EcoMat 3 (2021) e12126.
    [40]
    R. Qin, Y. Wang, M. Zhang, Y. Wang, S. Ding, A. Song, H. Yi, L. Yang, Y. Song, Y. Cui, J. Liu, Z. Wang, S. Li, Q. Zhao, F. Pan, Nano Energy 80 (2021) 105478.
    [41]
    X.-B. Cheng, T.-Z. Hou, R. Zhang, H.-J. Peng, C.-Z. Zhao, J.-Q. Huang, Q. Zhang, Adv. Mater. 28 (2016) 2888-2895.
    [42]
    X. Zhou, C. He, J. Mater. Chem. A 6 (2018) 607-615.
    [43]
    J. Chen, K. Fang, Q. Chen, J. Xu, C.-P. Wong, Nano Energy 53 (2018) 337-344.
    [44]
    Z. Hou, Y. Gao, R. Zhou, B. Zhang, Adv. Funct. Mater. 32 (2022) 2107584.
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Get Citation
    PDF
    XML

    Article Metrics

    Article views (127) PDF downloads(15) Cited by()
    Proportional views

    Publish With GEE

    Contact

    • Email：gee@ipe.ac.cn
    • Tel：010-82627075
    • Address：North 2nd street, Zhongguancun, Haidian District, Beijing, China

    Links

    京ICP备10002620号-1京公网安备 11010802039050号

    Supported by: Beijing Renhe Information Technology Co. Ltd    

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return