Volume 9 Issue 4
Apr.  2024
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Article Navigation >  Green Energy&Environment  > 2024  >  9(4): 723-731
Xiaodi Liu, Yufeng Tang, Dan Zhang, Guangyin Liu, Xinwei Luo, Yi Shang, Xiu Li, Jianmin Ma. F-doped orthorhombic Nb2O5 exposed with 97% (100) facet for fast reversible Li+-Intercalation. Green Energy&Environment, 2024, 9(4): 723-731. doi: 10.1016/j.gee.2022.09.009
Citation: Xiaodi Liu, Yufeng Tang, Dan Zhang, Guangyin Liu, Xinwei Luo, Yi Shang, Xiu Li, Jianmin Ma. F-doped orthorhombic Nb2O5 exposed with 97% (100) facet for fast reversible Li+-Intercalation. Green Energy&Environment, 2024, 9(4): 723-731. doi: 10.1016/j.gee.2022.09.009
shu

F-doped orthorhombic Nb2O5 exposed with 97% (100) facet for fast reversible Li+-Intercalation

doi: 10.1016/j.gee.2022.09.009

  • a. College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang, 473061, China;

  • b. School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu, 611731, China

Funds:

This work was supported by the National Natural Science Foundation of China (No. 51802163), the Natural Science Foundation of Henan Province of China (No. 222300420252), and the Natural Science Foundation of Henan Department of Education (No. 20A480004).

  • Received date 08 June 2022, Accepted date 15 September 2022, RevRecd date 04 September 2022, Publish date 20 September 2022,
    Abstract
  • Orthorhombic Nb2O5 (T-Nb2O5) is attractive for fast-charging Li-ion batteries, but it is still hard to realize rapid charge transfer kinetics for Li-ion storage. Herein, F-doped T-Nb2O5 microflowers (F-Nb2O5) are rationally synthesized through topotactic conversion. Specifically, F-Nb2O5 are assembled by single-crystal nanoflakes with nearly 97% exposed (100) facet, which maximizes the exposure of the feasible Li+ transport pathways along loosely packed 4g atomic layers to the electrolytes, thus effectively enhancing the Li+-intercalation performance. Besides, the band gap of F-Nb2O5 is reduced to 2.87 eV due to the doping of F atoms, leading to enhanced electrical conductivity. The synergetic effects between tailored exposed crystal facets, F-doping, and ultrathin building blocks, speed up the Li+/electron transfer kinetics and improve the pseudocapacitive properties of F-Nb2O5. Therefore, F-Nb2O5 exhibit superior rate capability (210.8 and 164.9 mAh g-1 at 1 and 10 C, respectively) and good long-term 10 C cycling performance (132.7 mAh g-1 after 1500 cycles).

     

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