Volume 9 Issue 4
Apr.  2024
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Article Navigation >  Green Energy&Environment  > 2024  >  9(4): 732-747
Hong Qin, Yangzhuo He, Piao Xu, Yuan Zhu, Han Wang, Ziwei Wang, Yin Zhao, Haijiao Xie, Quyang Tian, Changlin Wang, Ying Zeng, Yicheng Li. Carbon-doped CuFe2O4 with C-O-M channels for enhanced Fenton-like degradation of tetracycline hydrochloride: From construction to mechanism. Green Energy&Environment, 2024, 9(4): 732-747. doi: 10.1016/j.gee.2022.09.006
Citation: Hong Qin, Yangzhuo He, Piao Xu, Yuan Zhu, Han Wang, Ziwei Wang, Yin Zhao, Haijiao Xie, Quyang Tian, Changlin Wang, Ying Zeng, Yicheng Li. Carbon-doped CuFe2O4 with C-O-M channels for enhanced Fenton-like degradation of tetracycline hydrochloride: From construction to mechanism. Green Energy&Environment, 2024, 9(4): 732-747. doi: 10.1016/j.gee.2022.09.006
shu

Carbon-doped CuFe2O4 with C-O-M channels for enhanced Fenton-like degradation of tetracycline hydrochloride: From construction to mechanism

doi: 10.1016/j.gee.2022.09.006

  • a. College of Environmental Science and Engineering, Hunan University, Changsha, 410082, China;

  • b. Key Laboratory of Environmental Biology and Pollution Control, Ministry of Education, Hunan University, Changsha, 410082, China;

  • c. Hangzhou Yanqu Information Technology Co., Ltd., Y2, 2nd Floor, Building 2, Xixi Legu Creative Pioneering Park, No. 712 Wen'er West Road, Xihu District, Hangzhou, 310003, China

Funds:

This study was financially supported by the Program for the National Natural Science Foundation of China (52070077, 51879101, 51779090), the National Program for Support of Top-Notch Young Professionals of China (2014), the Program for Changjiang Scholars and Innovative Research Team in University (IRT-13R17), Natural Science Foundation of Hunan Province (2022JJ20013, 2021JJ40098).

  • Received date 19 July 2022, Accepted date 14 September 2022, RevRecd date 30 August 2022, Publish date 20 September 2022,
    Abstract
  • Carbon-doped copper ferrite (C–CuFe2O4) was synthesized by a simple two-step hydrothermal method, which showed enhanced tetracycline hydrochloride (TCH) removal efficiency as compared to the pure CuFe2O4 in Fenton-like reaction. A removal efficiency of 94% was achieved with 0.2 g L-1 catalyst and 20 mmol L-1 H2O2 within 90 min. We demonstrated that 5% C–CuFe2O4 catalyst in the presence of H2O2 was significantly efficient for TCH degradation under the near-neutral pH (5–9) without buffer. Multiple techniques, including SEM, TEM, XRD, FTIR, Raman, XPS Mössbauer and so on, were conducted to investigate the structures, morphologies and electronic properties of as-prepared samples. The introduction of carbon can effectively accelerate electron transfer by cooperating with Cu and Fe to activate H2O2 to generate OH and O2-. Particularly, theoretical calculations display that the p, p, d orbital hybridization of C, O, Cu and Fe can form C–O–Cu and C–O–Fe bonds, and the electrons on carbon can transfer to metal Cu and Fe along the C–O–Fe and C–O–Cu channels, thus forming electron-rich reactive centers around Fe and Cu. This work provides lightful reference for the modification of spinel ferrites in Fenton-like application.

     

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