Volume 9 Issue 3
Mar.  2024
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Article Navigation >  Green Energy&Environment  > 2024  >  9(3): 556-564
Qiang Han, Lele Cai, Zhaofeng Yang, Yanjie Hu, Hao Jiang, Chunzhong Li. New insights into the pre-lithiation kinetics of single-crystalline Ni-rich cathodes for long-life Li-ion batteries. Green Energy&Environment, 2024, 9(3): 556-564. doi: 10.1016/j.gee.2022.09.003
Citation: Qiang Han, Lele Cai, Zhaofeng Yang, Yanjie Hu, Hao Jiang, Chunzhong Li. New insights into the pre-lithiation kinetics of single-crystalline Ni-rich cathodes for long-life Li-ion batteries. Green Energy&Environment, 2024, 9(3): 556-564. doi: 10.1016/j.gee.2022.09.003
shu

New insights into the pre-lithiation kinetics of single-crystalline Ni-rich cathodes for long-life Li-ion batteries

doi: 10.1016/j.gee.2022.09.003

  • a. Shanghai Engineering Research Center of Hierarchical Nanomaterials, School of Chemical Engineering, East China University of Science and Technology, Shanghai, 200237, China;

  • b. Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai, 200237, China

Funds:

This work was supported by the National Natural Science Foundation of China (21975074, 91834301), the Innovation Program of Shanghai Municipal Education Commission, and the Fundamental Research Funds for the Central Universities.

  • Received date 11 June 2022, Accepted date 02 September 2022, RevRecd date 06 August 2022, Publish date 07 September 2022,
    Abstract
  • Developing single-crystalline Ni-rich cathodes is an effective strategy to improve the safety and cycle life of Li-ion batteries (LIBs). However, the easy-to-loss of Li and O in high-temperature lithiation results in unsatisfactory ordered layered structure and stoichiometry. Herein, we demonstrate the synthesis of highly-ordered and fully-stoichiometric single-crystalline LiNi0.83Co0.12Mn0.05O2 (SC-NCM83) cathodes by the regulation of pre-lithiation kinetics. The well-balanced pre-lithiation kinetics have been proved to greatly improve the proportion of layered phase in the intermediate by inhibiting the formation of metastable spinel phase, which promoted the rapid transformation of the intermediate into highly-ordered layered SC-NCM83 in the subsequent lithiation process. After coating a layer of Li2O–B2O3, the resultant cathodes deliver superior cycling stability with 90.9% capacity retention at 1C after 300 cycles in pouch-type full batteries. The enhancement mechanism has also been clarified. These findings exhibit fundamental insights into the pre-lithiation kinetics process for guiding the synthesis of high-quality single-crystalline Ni-rich cathodes.

     

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