Volume 9 Issue 3
Mar.  2024
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Article Navigation >  Green Energy&Environment  > 2024  >  9(3): 495-506
Peiwen Wu, Xin Song, Linlin Chen, Lianwen He, Yingcheng Wu, Duanjian Tao, Jing He, Chang Deng, Linjie Lu, Yanhong Chao, Mingqing Hua, Wenshuai Zhu. Few-layered hexagonal boron nitride nanosheets stabilized Pt NPs for oxidation promoted adsorptive desulfurization of fuel oil. Green Energy&Environment, 2024, 9(3): 495-506. doi: 10.1016/j.gee.2022.08.003
Citation: Peiwen Wu, Xin Song, Linlin Chen, Lianwen He, Yingcheng Wu, Duanjian Tao, Jing He, Chang Deng, Linjie Lu, Yanhong Chao, Mingqing Hua, Wenshuai Zhu. Few-layered hexagonal boron nitride nanosheets stabilized Pt NPs for oxidation promoted adsorptive desulfurization of fuel oil. Green Energy&Environment, 2024, 9(3): 495-506. doi: 10.1016/j.gee.2022.08.003
shu

Few-layered hexagonal boron nitride nanosheets stabilized Pt NPs for oxidation promoted adsorptive desulfurization of fuel oil

doi: 10.1016/j.gee.2022.08.003

  • a. School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, China;

  • b. College of Chemical Engineering and Environment, State Key Laboratory of Heavy Oil Processing, China University of Petroleum-Beijing, Beijing, 102249, China;

  • c. College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang, 330022, China;

  • d. College of Science, State Key Laboratory of Heavy Oil Processing, China University of Petroleum-Beijing, Beijing, 102249, China

Funds:

We thank the financial support from the National Natural Science Foundation of China (22178154, 22008094, 21908082, 21878133), Natural Science Foundation of Jiangsu Province (BK20190852, BK20190854), and Natural Science Foundation for Jiangsu Colleges and Universities (19KJB530005).

  • Received date 05 May 2022, Accepted date 03 August 2022, RevRecd date 01 July 2022, Publish date 13 August 2022,
    Abstract
  • A few-layered hexagonal boron nitride nanosheets stabilized platinum nanoparticles (Pt/h-BNNS) is engineered for oxidation-promoted adsorptive desulfurization (OPADS) of fuel oil. It was found that the few-layered structure and the defective sites of h-BNNS not only are beneficial to the stabilization of Pt NPs but also favor the adsorption of aromatic sulfides. By employing Pt/h-BNNS with a Pt loading amount of 1.19 wt% as the active adsorbent and air as an oxidant, a 98.0% sulfur removal over dibenzothiophene (DBT) is achieved along with a total conversion of the DBT to the corresponding sulfones (DBTO2). Detailed experiments show that the excellent desulfurization activity originates from the few-layered structure of h-BNNS and the high catalytic activity of Pt NPs. In addition, the OPADS system with Pt/h-BNNS as the active adsorbent shows remarkable stability in desulfurization performance with the existence of different interferents such as olefin, and aromatic hydrocarbons. Besides, the Pt/h-BNNS can be recycled 12 times without a significant decrease in desulfurization performance. Also, a process flow diagram is proposed for deep desulfurization of fuel oil and recovery of high value-added products, which would promote the industrial application of such OPADS strategy.

     

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