Volume 9 Issue 2
Feb.  2024
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Article Navigation >  Green Energy&Environment  > 2024  >  9(2): 321-332
Shaoyu Yuan, Yushan Yang, Zhangyi Xiong, Peijing Guo, Sufang Sun, Zejiang Li, Jianlong Du, Yongjun Gao. CO2 methanation boosted by support-size-dependent strong metal-support interaction and B–O–Ti component. Green Energy&Environment, 2024, 9(2): 321-332. doi: 10.1016/j.gee.2022.05.010
Citation: Shaoyu Yuan, Yushan Yang, Zhangyi Xiong, Peijing Guo, Sufang Sun, Zejiang Li, Jianlong Du, Yongjun Gao. CO2 methanation boosted by support-size-dependent strong metal-support interaction and B–O–Ti component. Green Energy&Environment, 2024, 9(2): 321-332. doi: 10.1016/j.gee.2022.05.010
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CO2 methanation boosted by support-size-dependent strong metal-support interaction and B–O–Ti component

doi: 10.1016/j.gee.2022.05.010

  • College of Chemistry and Environmental Science, Hebei University, No. 180, Wusidong Road, Baoding, 071002, Hebei, China

Funds:

This work was supported by National Natural Science Foundation of China (21773053) and Advanced Talents Incubation Program of Hebei University (801260201019). Research Innovation Team of College of Chemistry and Environmental Science of Hebei University (hxkytd-py2102). In addition, we also thank the support of the High-Performance Computing Center of Hebei University.

  • Received date 22 April 2022, Accepted date 30 May 2022, RevRecd date 21 May 2022, Publish date 17 June 2022,
    Abstract
  • Strong metal-support interaction (SMSI) has a great impact on the activity and selectivity of heterogeneous catalysts, which was usually adjusted by changing reduction temperature or processing catalyst in different atmosphere. However, few researches concentrate on modulating SMSI through regulating the structure of the support. Herein, we show how changing the surface environment of the anatase TiO2 (B–TiO2) can be used to modulate the SMSI. The moderate TiOx overlayer makes the Ni metal highly dispersed on the high specific surface area of support, resulting in a substantially enhanced CO2 methanation rate. Besides, a novel phenomenon was observed that boron dopants promote the formation of the B–O–Ti interface site, enhancing the catalytic performance of CO2 hydrogenation. DFT calculations confirm that the B–O–Ti structure facilitates the activation of CO2 and further hydrogenation to methane.

     

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