Volume 9 Issue 1
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Xinxin Li, Linchuan Cong, Haibo Lin, Fangbing Liu, Xiangxue Fu, Hai-Chao Xu, Nan Lin. Linear paired electrolysis of furfural to furoic acid at both anode and cathode in a multiple redox mediated system. Green Energy&Environment, 2024, 9(1): 104-113. doi: 10.1016/j.gee.2022.05.009
Citation: Xinxin Li, Linchuan Cong, Haibo Lin, Fangbing Liu, Xiangxue Fu, Hai-Chao Xu, Nan Lin. Linear paired electrolysis of furfural to furoic acid at both anode and cathode in a multiple redox mediated system. Green Energy&Environment, 2024, 9(1): 104-113. doi: 10.1016/j.gee.2022.05.009
shu

Linear paired electrolysis of furfural to furoic acid at both anode and cathode in a multiple redox mediated system

doi: 10.1016/j.gee.2022.05.009

  • a. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, Jilin, China;

  • b. State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China

Funds:

This study is supported by the National Key Research and Development Program of China (2017YFB0307500).

  • Received date 02 April 2022, Accepted date 24 May 2022, RevRecd date 11 May 2022, Available online 23 November 2023, Publish date 02 June 2022,
    Abstract
  • Implementing a new energy-saving electrochemical synthesis system with high commercial value is a strategy of the sustainable development for upgrading the bulk chemicals preparation technology in the future. Here, we report a multiple redox-mediated linear paired electrolysis system, combining the hydrogen peroxide mediated cathode process with the I2 mediated anode process, and realize the conversion of furfural to furoic acid in both side of the divided flow cell simultaneously. By reasonably controlling the cathode potential, the undesired water splitting reaction and furfural reduction side reactions are avoided. Under the galvanostatic electrolysis, the two-mediated electrode processes have good compatibility, which reduce the energy consumption by about 22% while improving the electronic efficiency by about 125%. This system provides a green electrochemical synthesis route with commercial prospects.

     

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    • References(38)
  • [1]
    J. Bodisova, T. Sotak, M. Naumowicz, R. Sokolova, M. Hronec, J. Hives and M. Gal, J Electroanal Chem, 2018, 821, 126-130.
    [2]
    C. Van Nguyen, J. R. Boo, C.-H. Liu, T. Ahamad, S. M. Alshehri, B. M. Matsagar and K. C. W. Wu, Catalysis Science & Technology, 2020, 10, 1498-1506.
    [3]
    G. Papanikolaou, P. Lanzafame, S. Perathoner, G. Centi, D. Cozza, G. Giorgianni, M. Migliori and G. Giordano, Catalysis Communications, 2021, 149.
    [4]
    N. S. Bhat, R. Kumar, A. Jana, S. S. Mal and S. Dutta, Biomass Conversion and Biorefinery, 2021, DOI: 10.1007/s13399-021-01297-0.
    [5]
    Y. Kwon, K. J. P. Schouten, J. C. van der Waal, E. de Jong and M. T. M. Koper, Acs Catal, 2016, 6, 6704-6717.
    [6]
    K. Li and Y. Sun, Chemistry, 2018, 24, 18258-18270.
    [7]
    S. Jung and E. J. Biddinger, Acs Sustain Chem Eng, 2016, 4, 6500-6508.
    [8]
    D. S. a. Y. S. Qingyong Tian, Molecules, 2008, 13, 948-957.
    [9]
    N. M. Philippe Verdeguer, Antoine Gaset, Applied Catalysis A: General, 1994, 112, 1-11.
    [10]
    N. M. Philippe Verdeguer, Luc Rigal & Antoine Gaset, Journal of Chemical Technology and Biotechnology, 1994, 61, 97-102.
    [11]
    A. M. Roman, J. C. Hasse, J. W. Medlin and A. Holewinski, Acs Catal, 2019, 9, 10305-10316.
    [12]
    S. R. Kubota and K. S. Choi, Acs Sustain Chem Eng, 2018, 6, 9596-9600.
    [13]
    D. Yang, C. Ma, B. Peng, J. Xu and Y.-C. He, Industrial Crops and Products, 2020, 153.
    [14]
    L. Gong, N. Agrawal, A. Roman, A. Holewinski and M. J. Janik, J Catal, 2019, 373, 322-335.
    [15]
    B. Y. Liu, S. J. Xu, M. Zhang, X. Li, D. Decarolis, Y. Q. Liu, Y. C. Wang, E. K. Gibson, C. R. A. Catlow and K. Yan, Green Chem, 2021, 23, 4034-4043.
    [16]
    R. Li, K. Xiang, Z. Peng, Y. Zou and S. Wang, Advanced Energy Materials, 2021, DOI: 10.1002/aenm.202102292.
    [17]
    B. A. F.-U. Jorge G. Ibanez, and Ruben Vasquez-Medrano, Journal of the Mexican Chemical Society, 2016, 60.
    [18]
    S. Choi, M. Balamurugan, K. G. Lee, K. H. Cho, S. Park, H. Seo and K. T. Nam, J Phys Chem Lett, 2020, 11, 2941-2948.
    [19]
    B. G, K. Rambabu, A. Hai, N. Ponpandian, J. E. Schmidt, D. D. Dionysiou, M. Abu Haija and F. Banat, Applied Catalysis B: Environmental, 2021, 298.
    [20]
    P. Zhang, X. Sheng, X. Chen, Z. Fang, J. Jiang, M. Wang, F. Li, L. Fan, Y. Ren, B. Zhang, B. J. J. Timmer, M. S. G. Ahlquist and L. Sun, Angew Chem Int Ed Engl, 2019, 58, 9155-9159.
    [21]
    S. Tian, X. Jia, L. Wang, B. Li, S. Liu, L. Ma, W. Gao, Y. Wei and J. Chen, Chem Commun (Camb), 2019, 55, 12104-12107.
    [22]
    D. Habibi, N. Pakravan and D. Nematollahi, Electrochemistry Communications, 2014, 49, 65-69.
    [23]
    H. Liu, T.-H. Lee, Y. Chen, E. W. Cochran and W. Li, Green Chem, 2021, 23, 5056-5063.
    [24]
    X. H. Chadderdon, D. J. Chadderdon, T. Pfennig, B. H. Shanks and W. Li, Green Chem, 2019, 21, 6210-6219.
    [25]
    J. Strehl, M. L. Abraham and G. Hilt, Angew Chem Int Ed Engl, 2021, 60, 9996-10000.
    [26]
    D. F. G. Chamoulaud, C. Moinet, C. Lamy, E.M. Belgsir, Electrochim Acta, 2001, 46.
    [27]
    P. Parpot, A. P. Bettencourt, G. Chamoulaud, K. B. Kokoh and E. M. Beigsir, Electrochim Acta, 2004, 49, 397-403.
    [28]
    X. Zhang, M. Han, G. Liu, G. Wang, Y. Zhang, H. Zhang and H. Zhao, Applied Catalysis B: Environmental, 2019, 244, 899-908.
    [29]
    Y. N. Ogibin, M. N. Elinson and G. I. Nikishin, Russian Chemical Reviews, 2009, 78, 89-140.
    [30]
    E. Steckhan, Angew Chrm Inr Ed Engl, 1986, 25, 683-701.
    [31]
    E. Steckhan, Electrochemistry I, 1987.
    [32]
    U. Leffrang, U. Galla and H. Schmieder, Separation Science and Technology, 1997, 32, 447-457.
    [33]
    R. Francke and R. D. Little, Chem Soc Rev, 2014, 43, 2492-2521.
    [34]
    E. Steckhan, Angewandte Chemie, 1986, 98, 681-699.
    [35]
    K. Liu, C. Song and A. Lei, Org Biomol Chem, 2018, 16, 2375-2387.
    [36]
    H. Gao, Z. Zha, Z. Zhang, H. Ma and Z. Wang, Chem Commun (Camb), 2014, 50, 5034-5036.
    [37]
    P. Su, M. Zhou, X. Lu, W. Yang, G. Ren and J. Cai, Applied Catalysis B: Environmental, 2019, 245, 583-595.
    [38]
    N. V. Chaenko, G. V. Kornienko, A. M. Kosheleva, N. G. Maksimov and V. L. Kornienko, Russian Journal of Electrochemistry, 2011, 47, 1146-1151.
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