Volume 8 Issue 6
Dec.  2023
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Article Navigation >  Green Energy&Environment  > 2023  >  8(6): 1703-1710
Xue-Qian Wu, Peng-Dan Zhang, Xin Zhang, Jing-Hao Liu, Tao He, Jiamei Yu, Jian-Rong Li. Ethylene purification in a metal-organic framework over a wide temperature range via pore confinement. Green Energy&Environment, 2023, 8(6): 1703-1710. doi: 10.1016/j.gee.2022.03.015
Citation: Xue-Qian Wu, Peng-Dan Zhang, Xin Zhang, Jing-Hao Liu, Tao He, Jiamei Yu, Jian-Rong Li. Ethylene purification in a metal-organic framework over a wide temperature range via pore confinement. Green Energy&Environment, 2023, 8(6): 1703-1710. doi: 10.1016/j.gee.2022.03.015
shu

Ethylene purification in a metal-organic framework over a wide temperature range via pore confinement

doi: 10.1016/j.gee.2022.03.015

  • a. Beijing Key Laboratory for Green Catalysis and Separation and Department of Environmental Chemical Engineering, Faculty of Environment and Life, Beijing University of Technology, Beijing, 100124, China;

  • b. The Key Laboratory of Advanced Functional Materials, Ministry of Education, Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China

Funds:

The authors gratefully acknowledge the financial support of the National Natural Science Foundation of China (No. 22038001).

  • Received date 28 December 2021, Accepted date 31 March 2022, RevRecd date 21 March 2022, Publish date 12 April 2022,
    Abstract
  • The separation of C2H4 from C2H6/C2H4 mixture is of great importance but difficult and energy intensive. Adsorptive separation provides an alternative approach to ameliorate this situation. Here, we report a microporous metal-organic framework (MOF) BUT-315-a as a C2H6-selective adsorbent for the separation of C2H6/C2H4 gas mixture. BUT-315-a combines good IAST selectivity of 2.35 with high C2H6 uptake of 97.5 cm3 g-1, giving superior high separation potential ΔQ (2226 mmol L-1) for equimolar C2H6/C2H4 at 298 K. Impressively, such excellent performance can be preserved at higher temperatures of 313 and 323 K to accommodate industrial conditions. Efficient dynamic separation performance of BUT-315-a has been demonstrated by column breakthrough experiments under varied temperatures and gas ratios. Theoretical calculations further reveal multiple synergistic interactions between C2H6 and the framework. This work highlights a new benchmark material for C2H6/C2H4 separation and provides guidance for designing adsorbent for separation applications.

     

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