Volume 8 Issue 2
Apr.  2023
Turn off MathJax
Article Contents
Article Navigation >  Green Energy&Environment  > 2023  >  8(2): 354-359
Xi Zhang, Xiaohong Liu, Wei Zhang, Yingze Song. Tunable vacancy defect chemistry on free-standing carbon cathode for lithium-sulfur batteries. Green Energy&Environment, 2023, 8(2): 354-359. doi: 10.1016/j.gee.2022.03.006
Citation: Xi Zhang, Xiaohong Liu, Wei Zhang, Yingze Song. Tunable vacancy defect chemistry on free-standing carbon cathode for lithium-sulfur batteries. Green Energy&Environment, 2023, 8(2): 354-359. doi: 10.1016/j.gee.2022.03.006
shu

Tunable vacancy defect chemistry on free-standing carbon cathode for lithium-sulfur batteries

doi: 10.1016/j.gee.2022.03.006

  • a. State Key Laboratory of Environment-Friendly Energy Materials, School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang, 621010, China;

  • b. National University of Singapore (Chongqing) Research Institute, Chongqing, 401123, China;

  • c. Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing, 400714, China

Funds:

The investigation was supported by the National Natural Science Foundation of China (52172239), Project of State Key Laboratory of Environment-Friendly Energy Materials, Southwest University of Science and Technology (Grant Nos. 21fksy24 and 18ZD320304), Chongqing Talents: Exceptional Young Talents Project (Grant No. CQYC201905041) and Natural Science Foundation of Chongqing China (Grant No. cstc2021jcyj-jqX0031).

  • Received date 13 February 2022, Accepted date 16 March 2022, RevRecd date 08 March 2022, Publish date 23 March 2022,
    Abstract
  • The defect chemistry is successfully modulated on free-standing and binder-free carbon cathodes for highly efficient Li–S redox reactions. Such rationally regulated defect engineering realizes the synchronization of ion/electron-conductive and defect-rich networks on the three-dimension carbon cathode, leading to its tunable activity for both relieving the shuttle phenomenon and accelerating the sulfur redox reaction kinetics. As expected, the defective carbon cathode harvests a high rate capacity of 1217.8 mAh g-1 at 0.2 C and a superior capacity retention of 61.7% at 2 C after 500 cycles. Even under the sulfur mass loading of 11.1 mg cm-2, the defective cathode still holds a remarkable areal capacity of 8.5 mAh cm-2.

     

    • FullText(HTML)
  • loading
    • References(40)
  • [1]
    J.M. Chen, The Innovation 2 (2021) 100127.
    [2]
    F. Wang, J.D. Harindintwali, Z. Yuan, M. Wang, F. Wang, S. Li, Z. Yin, L. Huang, Y. Fu, L. Li, S. Chang, L. Zhang, J. Rinklebe, Z. Yuan, Q. Zhu, L. Xiang, D.C.W. Tsang, L. Xu, X. Jiang, J. Liu, N. Wei, M. Kastner, Y. Zou, Y.S. Ok, J. Shen, D. Peng, W. Zhang, D. Barcelo, Y. Zhou, Z. Bai, B. Li, B. Zhang, K. Wei, H. Cao, Z. Tan, L. Zhao, X. He, J. Zheng, N. Bolan, X. Liu, C. Huang, S. Dietmann, M. Luo, N. Sun, J. Gong, Y. Gong, F. Brahushi, T. Zhang, C. Xiao, X. Li, W. Chen, N. Jiao, J. Lehmann, Y.G. Zhu, H. Jin, A. Schaffer, J.M. Tiedje, J.M. Chen, The Innovation 2 (2021) 100180.
    [3]
    W. Chen, C. Zhao, B. Li, Q. Jin, X. Zhang, T. Yuan, X. Zhang, Z. Jin, S. Kaskel, Q. Zhang, Energy Environ. Mater. 3 (2020) 160-165.
    [4]
    J. Zuo, Y. Gong, Tungsten 2 (2020) 134-146.
    [5]
    C.X. Zhao, W.J. Chen, M. Zhao, Y.W. Song, J.N. Liu, B.Q. Li, T. Yuan, C.M. Chen, Q. Zhang, J.Q. Huang, EcoMat 3 (2020) e12066.
    [6]
    Z. Cao, Y. Zhang, Y. Cui, B. Li, S. Yang, Tungsten 2 (2020) 162-175.
    [7]
    H. Peng, J. Huang, X. Cheng, Q. Zhang, Adv. Energy Mater. 7 (2017) 1700260.
    [8]
    J.G. Wang, K. Xie, B. Wei, Nano Energy 15 (2015) 413-444.
    [9]
    P. Wang, B. Xi, M. Huang, W. Chen, J. Feng, S. Xiong, Adv.Energy Mater. 11 (2021) 2002893.
    [10]
    C. Song, C. Peng, Z. Bian, F. Dong, H. Xu, J. Yang, S. Zheng, Energy Environ. Mater. 2 (2019) 216-224.
    [11]
    C. Yang, N. Gong, T. Chen, Y. Li, W. Peng, F. Zhang, X. Fan, Green Energy Environ. (2021) 2468-0257.
    [12]
    M. Zheng, Y. Chi, Q. Hu, H. Tang, X. Jiang, L. Zhang, S. Zhang, H. Pang, Q. Xu, J. Mater. Chem. A 7 (2019) 17204-17241.
    [13]
    L. Li, L. Chen, S. Mukherjee, J. Gao, H. Sun, Z. Liu, X. Ma, T. Gupta, C.V. Singh, W. Ren, H.M. Cheng, N. Koratkar, Adv. Mater. 29 (2017) 1602734.
    [14]
    M. Wang, Y. Song, N. Wei, Y. Shao, G. Sheng, J. Sun, Chem. Eng. J. 418 (2021) 129407.
    [15]
    J. Cai, J. Jin, Z. Fan, C. Li, Z. Shi, J. Sun, Z. Liu, Adv. Mater. 32 (2020) e2005967.
    [16]
    K. Lu, H. Zhang, S. Gao, H. Ma, J. Chen, Y. Cheng, Adv. Funct. Mater. 29 (2019) 1807309.
    [17]
    H. Zhang, D. Tian, Z. Zhao, X. Liu, Y. Hou, Y. Tang, J. Liang, Z. Zhang, X. Wang, J. Qiu, Energy Storage Mater. 21 (2019) 210-218.
    [18]
    H. Li, Y. Chen, Q. Jin, W. Xiang, B. Zhong, X. Guo, B. Wang, Green Energy Environ. 6 (2021) 506-516.
    [19]
    D. Cai, B. Liu, D. Zhu, D. Chen, M. Lu, J. Cao, Y. Wang, W. Huang, Y. Shao, H. Tu, W. Han, Adv. Energy Mater. 10 (2020) 1904273.
    [20]
    J. Jin, W. Cai, J. Cai, Y. Shao, Y. Song, Z. Xia, Q. Zhang, J. Sun, J. Mater. Chem. A 8 (2020) 3027-3034.
    [21]
    C.J. Huang, K.Y. Lin, Y.C. Hsieh, W.N. Su, C.H. Wang, G. Brunklaus, M. Winter, J.C. Jiang, B.J. Hwang, ACS Appl. Mater. Interfaces 13 (2021) 14230-14238.
    [22]
    Q. Pang, D. Kundu, M. Cuisinier, L.F. Nazar, Nat. Commun. 5 (2014) 4759.
    [23]
    W. Cai, Y. Song, Y. Fang, W. Wang, S. Yu, H. Ao, Y. Zhu, Y. Qian, Nano Res. 13 (2020) 3315-3320.
    [24]
    J. Liu, M. Jiao, B. Mei, Y. Tong, Y. Li, M. Ruan, P. Song, G. Sun, L. Jiang, Y. Wang, Z. Jiang, L. Gu, Z. Zhou, W. Xu, Angew. Chem. Int. Ed. 58 (2019) 1163-1167.
    [25]
    Y. Zhang, G. Li, J. Wang, G. Cui, X. Wei, L. Shui, K. Kempa, G. Zhou, X. Wang, Z. Chen, Adv. Funct. Mater. 30 (2020) 2001165.
    [26]
    Y. Zhang, L. Tao, C. Xie, D. Wang, Y. Zou, R. Chen, Y. Wang, C. Jia, S. Wang, Adv. Mater. 32 (2020) e1905923.
    [27]
    Y. Song, H. Gao, M. Wang, L. Chen, X. Cao, L. Song, X. Liu, W. Cai, J. Sun, W. Zhang, EcoMat (2022) e12182.
    [28]
    S. Wang, H. Chen, J. Liao, Q. Sun, F. Zhao, J. Luo, X. Lin, X. Niu, M. Wu, R. Li, X. Sun, ACS Energy Lett. 4 (2019) 755-762.
    [29]
    Y. Zhan, A. Buffa, L. Yu, Z.J. Xu, D. Mandler, Nano-Micro Lett. 12 (2020) 141.
    [30]
    Y. Zhong, D. Chao, S. Deng, J. Zhan, R. Fang, Y. Xia, Y. Wang, X. Wang, X. Xia, J. Tu, Adv. Funct. Mater. 28 (2018) 1706391.
    [31]
    R. Lu, M. Cheng, L. Mao, M. Zhang, H. Yuan, K. Amin, C. Yang, Y. Cheng, Y. Meng, Z. Wei, EcoMat. 2 (2020) e12010.
    [32]
    L. Chen, S. Yu, Y. Zhang, Y. Song, L. Song, J. Power Sources 514 (2021) 230607.
    [33]
    K. Ganesan, S. Ghosh, N. Gopala Krishna, S. Ilango, M. Kamruddin, A.K. Tyagi, Phys. Chem. Chem. Phys. 18 (2016) 22160-22167.
    [34]
    H. Kwon, J.H. Lee, Y. Roh, J. Baek, D.J. Shin, J.K. Yoon, H.J. Ha, J.Y. Kim, H.T. Kim, Nat. Commun. 12 (2021) 5537.
    [35]
    F.Y. Fan, W.C. Carter, Y.M. Chiang, Adv. Mater. 27 (2015) 5203-5209.
    [36]
    S. Yu, Y. Sun, L. Song, X. Cao, L. Chen, X. An, X. Liu, W. Cai, T. Yao, Y. Song, W. Zhang, Nano Energy 89 (2021) 106414.
    [37]
    T. Sun, X. Zhao, B. Li, H. Shu, L. Luo, W. Xia, M. Chen, P. Zeng, X. Yang, P. Gao, Y. Pei, X. Wang, Adv. Funct. Mater. 31 (2021) 2101285.
    [38]
    R. Wang, C. Luo, T. Wang, G. Zhou, Y. Deng, Y. He, Q. Zhang, F. Kang, W. Lv, Q.H. Yang, Adv. Mater. 32 (2020) e2000315.
    [39]
    T. Lei, W. Chen, W. Lv, J. Huang, J. Zhu, J. Chu, C. Yan, C. Wu, Y. Yan, W. He, J. Xiong, Y. Li, C. Yan, J.B. Goodenough, X. Duan, Joule 2 (2018) 2091-2104.
    [40]
    R. Razaq, N. Zhang, Y. Xin, Q. Li, J. Wang, Z. Zhang, EcoMat 2 (2020) e12020.
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Get Citation
    PDF
    XML

    Article Metrics

    Article views (341) PDF downloads(33) Cited by()
    Proportional views

    Publish With GEE

    Contact

    • Email：gee@ipe.ac.cn
    • Tel：010-82627075
    • Address：North 2nd street, Zhongguancun, Haidian District, Beijing, China

    Links

    京ICP备10002620号-1京公网安备 11010802039050号

    Supported by: Beijing Renhe Information Technology Co. Ltd    

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return