Volume 8 Issue 6
Dec.  2023
Turn off MathJax
Article Contents
Article Navigation >  Green Energy&Environment  > 2023  >  8(6): 1619-1629
Hui Liu, Jingsha Li, Feng Du, Luyun Yang, Shunyuan Huang, Jingfeng Gao, Changming Li, Chunxian Guo. A core-shell copper oxides-cobalt oxides heterostructure nanowire arrays for nitrate reduction to ammonia with high yield rate. Green Energy&Environment, 2023, 8(6): 1619-1629. doi: 10.1016/j.gee.2022.03.003
Citation: Hui Liu, Jingsha Li, Feng Du, Luyun Yang, Shunyuan Huang, Jingfeng Gao, Changming Li, Chunxian Guo. A core-shell copper oxides-cobalt oxides heterostructure nanowire arrays for nitrate reduction to ammonia with high yield rate. Green Energy&Environment, 2023, 8(6): 1619-1629. doi: 10.1016/j.gee.2022.03.003
shu

A core-shell copper oxides-cobalt oxides heterostructure nanowire arrays for nitrate reduction to ammonia with high yield rate

doi: 10.1016/j.gee.2022.03.003

  • a. Institute of Advanced Cross-field Science, College of Life Science, Qingdao University, Qingdao, 266071, China;

  • b. Institute of Materials Science and Devices, School of Materials Science and Engineering, Suzhou University of Science and Technology, Suzhou, 215011, China;

  • c. Jiangsu Key Laboratory for Micro and Nano Heat Fluid Flow Technology and Energy Application, Collaborative Innovation Center of Water Treatment Technology & Material, China

Funds:

We would like to acknowledge the financial support from National Natural Science Foundation of China (No. 21972102), National Key Research and Development Program of China (2021YFA0910400), Natural Science Foundation of Jiangsu Province (BK20200991), Suzhou Science and Technology Planning Project (SS202016), the USTS starting fund (No.332012104) and the Natural Science Foundation of Suzhou University of Science and Technology (No.342134401).

  • Received date 02 January 2022, Accepted date 03 March 2022, RevRecd date 28 February 2022, Publish date 11 March 2022,
    Abstract
  • Electrochemical nitrate reduction to ammonia (NRA) can realize the green synthesis of ammonia (NH3) at ambient conditions, and also remove nitrate contamination in water. However, the current catalysts for NRA still face relatively low NH3 yield rate and poor stability. We present here a core-shell heterostructure comprising cobalt oxide anchored on copper oxide nanowire arrays (CuO NWAs@Co3O4) for efficient NRA. The CuO NWAs@Co3O4 demonstrates significantly enhanced NRA performance in alkaline media in comparison with plain CuO NWAs and Co3O4 flocs. Especially, at -0.23 V vs. RHE, NH3 yield rate of the CuO NWAs@Co3O4 reaches 1.915 mmol h-1 cm-2, much higher than those of CuO NWAs (1.472 mmol h-1 cm-2), Co3O4 flocs (1.222 mmol h-1 cm-2) and recent reported Cu-based catalysts. It is proposed that the synergetic effects of the heterostructure combing atom hydrogen adsorption and nitrate reduction lead to the enhanced NRA performance.

     

    • FullText(HTML)
  • loading
    • References(56)
  • [1]
    Y.M. Huang, J. Long, Y.T. Wang, N.N. Meng, Y.F. Yu, S.Y. Lu, J.P. Xiao, B. Zhang, Acs Applied Materials & Interfaces 13 (2021) 54957-54963.
    [2]
    B.H.R. Suryanto, H.L. Du, D.B. Wang, J. Chen, A.N. Simonov, D.R. Macfarlane, Nature Catalysis 2 (2019) 290-296.
    [3]
    S.H. Ye, Z.D. Chen, G.K. Zhang, W.D. Chen, C. Peng, X.Y. Yang, L.R. Zheng, Y.L. Li, X.Z. Ren, H.Q. Cao, D.F. Xue, J.S. Qiu, Q.L. Zhang, J.H. Liu, Energy & Environmental Science.
    [4]
    Y. Xu, M.Z. Wang, K.L. Ren, T.L. Ren, M.Y. Liu, Z.Q. Wang, X.N.A. Li, L. Wang, H.J. Wang, Journal of Materials Chemistry A 9 (2021) 16411-16417.
    [5]
    P.P. Huang, T.T. Fan, X.T. Ma, J.G. Zhang, Y.P. Zhang, Z. Chen, X.D. Yi, ChemSusChem.
    [6]
    X. Zhao, X. Li, H.B. Zhang, X. Chen, J. Xu, J. Yang, H.C. Zhang, G.Z. Hu, J. Hazard. Mater. 424 (2022).
    [7]
    J.S. Li, J.F. Gao, T.Z. Feng, H.H. Zhang, D.P. Liu, C.M. Zhang, S.Y. Huang, C.H. Wang, F. Du, C.M. Li, C.X. Guo, Journal of Power Sources 511 (2021).
    [8]
    A. Santos, J. Restivo, C.A. Orge, M.F.R. Pereira, O. Soares, C-J. Carbon Res. 6 (2020) 18.
    [9]
    O. Soares, J.J.M. Orfao, E. Gallegos-Suarez, E. Castillejos, I. Rodriguez-Ramos, M.F.R. Pereira, Environ. Technol. 33 (2012) 2353-2358.
    [10]
    M.V. Peter, D.A. John, W.H. Robert, E.L. Gene, A.M. Pamela, W.S. David, H.S. Williami, G.T. David, Water Research 32 (1998) 0-2264.
    [11]
    Z. Mumtarin, M.M. Rahman, H.M. Marwani, M.A. Hasnat, Electrochim. Acta 346 (2020) 9.
    [12]
    S.J. Guo, C.D. Powell, D. Villagran, M.S. Wong, Environ. Sci.-Nano 7 (2020) 2681-2690.
    [13]
    H.B. Liu, T.H. Chen, D.Y. Chang, D. Chen, Y. Liu, H.P. He, P. Yuan, R. Frost, Mater. Chem. Phys. 133 (2012) 205-211.
    [14]
    J.F. Su, I. Ruzybayev, I. Shah, C.P. Huang, Appl. Catal. B-Environ. 180 (2016) 199-209.
    [15]
    M. Kobune, D. Takizawa, J. Nojima, R. Otomo, Y. Kamiya, Catal. Today 352 (2020) 204-211.
    [16]
    Y.X. Li, J.Y. Ling, P.C. Chen, J.L. Chen, R.Z. Dai, J.S. Liao, J.J. Yu, Y.B. Xu, Front. Env. Sci. Eng. 15 (2021) 10.
    [17]
    H.M. Cheng, Q. Zhu, A.W. Wang, M.M. Weng, Z.P. Xing, Environ. Res. 184 (2020) 10.
    [18]
    F. Labarca, R. Borquez, Sci. Total Environ. 723 (2020) 12.
    [19]
    A.E. Zorgani, M. Crimi, A. Cibati, C. Trois, Water Air Soil Pollut. 231 (2020) 9.
    [20]
    H. Xu, J. Wu, W. Luo, Q. Li, W.X. Zhang, J.P. Yang, Small 16 (2020) 16.
    [21]
    X. Zhang, Y.T. Wang, C.B. Liu, Y.F. Yu, S.Y. Lu, B. Zhang, Chem. Eng. J. 403 (2021) 16.
    [22]
    T.H. Zhu, Q.S. Chen, P. Liao, W.J. Duan, S. Liang, Z. Yan, C.H. Feng, Small 16 (2020).
    [23]
    D. Kim, D. Shin, J. Heo, H. Lim, J.A. Lim, H.M. Jeong, B.S. Kim, I. Heo, I. Oh, B. Lee, M. Sharma, H. Lim, H. Kim, Y. Kwon, Acs Energy Letters 5 (2020) 3647-3656.
    [24]
    J.T. Ren, Y.L. Yao, Z.Y. Yuan, Green Energy & Environment 6 (2021) 620-643.
    [25]
    G.A. Cerron-Calle, A.S. Fajardo, C.M. Sanchez-Sanchez, S. Garcia-Segura, Appl. Catal. B-Environ. 302 (2022).
    [26]
    B.P. Dash, S. Chaudhari, Water Research 39 (2005) 4065-4072.
    [27]
    E. Lacasa, P. Canizares, J. Llanos, M.A. Rodrigo, J. Hazard. Mater. 213 (2012) 478-484.
    [28]
    P.L. Kuang, K. Natsui, C.P. Feng, Y. Einaga, Chemosphere 251 (2020) 11.
    [29]
    K. Bouzek, M. Paidar, A. Sadilkova, H. Bergmann, J. Appl. Electrochem. 31 (2001) 1185-1193.
    [30]
    M. Machida, K. Sato, I. Ishibashi, M. Abul Hasnat, K. Ikeue, Chem. Commun. (2006) 732-734.
    [31]
    G.E. Dima, A.C.A. De Vooys, M.T.M. Koper, J. Electroanal. Chem. 554 (2003) 15-23.
    [32]
    O. Brylev, M. Sarrazin, L. Roue, D. Belanger, Electrochim. Acta 52 (2007) 6237-6247.
    [33]
    Z.H. Shen, D.R. Liu, G.G. Peng, Y.H. Ma, J.S. Li, J.L. Shi, J.B. Peng, L.J. Ding, Sep. Purif. Technol. 241 (2020) 9.
    [34]
    C. M. Zhang, J. S. Li, C. M. Li, W. Chen, C. X. Guo, J. Mater. Chem. A 9 (2021) 25706-25730.
    [35]
    C. H. Wang, C. M. Li, J. L. Liu, C. X. Guo, Materials Reports:Energy 1 (2021) 100006.
    [36]
    M. Zeng, Y.Z. Li, M.Y. Mao, J.L. Bai, L. Ren, X.J. Zhao, Acs Catalysis 5 (2015) 3278-3286.
    [37]
    Y.J. Ji, Z.Y. Jin, J. Li, Y. Zhang, H.Z. Liu, L.S. Shi, Z.Y. Zhong, F.B. Su, Nano Research 10 (2017) 381-396.
    [38]
    Y. Liu, J.G. Guo, Y. Wang, Y.J. Hao, R.H. Liu, F.T. Li, Green Energy & Environment 6 (2021) 244-252.
    [39]
    J.Y. Ma, Q. Wang, L.L. Li, X.H. Zong, H. Sun, R. Tao, X.X. Fan, Journal of Colloid and Interface Science 602 (2021) 32-42.
    [40]
    Y.T. Wang, W. Zhou, R.R. Jia, Y.F. Yu, B. Zhang, Angew. Chem.-Int. Edit. 59 (2020) 5350-5354.
    [41]
    H. Pang, G.J. Yang, L. Li, J.H. Yu, Green Energy & Environment 5 (2020) 405-413.
    [42]
    M.X. Yang, J.T. Wang, C.D. Shuang, A.M. Li, Chemosphere 255 (2020) 8.
    [43]
    Y.H. Wang, A. Xu, Z.Y. Wang, L.S. Huang, J. Li, F.W. Li, J. Wicks, M.C. Luo, D.H. Nam, C.S. Tan, Y. Ding, J.W. Wu, Y.W. Lum, C.T. Dinh, D. Sinton, G.F. Zheng, E.H. Sargent, J. Am. Chem. Soc. 142 (2020) 5702-5708.
    [44]
    Z.K. Xie, Y.Y. Xu, D. Li, L.J. Chen, S.C. Meng, D.L. Jiang, M. Chen, Journal of Alloys and Compounds 858 (2021).
    [45]
    X.M. Li, N.N. Xu, H.R. Li, M. Wang, L. Zhang, J.L. Qiao, Green Energy & Environment 2 (2017) 316-328.
    [46]
    X.H. Deng, Y.P. Yang, L. Wang, X.Z. Fu, J.L. Luo, Advanced Science 8 (2021).
    [47]
    T.F. Beltrame, M.C. Gomes, L. Marder, F.A. Marchesini, M.A. Ulla, A.M. Bernardes, J. Water Process. Eng. 35 (2020) 8.
    [48]
    J.N. Gao, B. Jiang, C.C. Ni, Y.F. Qi, Y.Q. Zhang, N. Oturan, M.A. Oturan, Appl. Catal. B-Environ. 254 (2019) 391-402.
    [49]
    C. Li, K. Li, C. Chen, Q.L. Tang, T.H. Sun, J.P. Jia, Sep. Purif. Technol. 237 (2020) 14.
    [50]
    X.J. Ma, M. Li, C.P. Feng, W.W. Hu, L.L. Wang, X. Liu, J. Electroanal. Chem. 782 (2016) 270-277.
    [51]
    L. Mattarozzi, S. Cattarin, N. Comisso, N. El Habra, P. Guerriero, M. Musiani, L. Vazquez-Gomez, Electrochim. Acta 346 (2020) 8.
    [52]
    L. Mattarozzi, S. Cattarin, N. Comisso, P. Guerriero, M. Musiani, L. Vazquez-Gomez, E. Verlato, Electrochim. Acta 89 (2013) 488-496.
    [53]
    L.H. Su, K. Li, H.B. Zhang, M.H. Fan, D.W. Ying, T.H. Sun, Y.L. Wang, J.P. Jia, Water Research 120 (2017) 1-11.
    [54]
    C.H. Wang, Z.Y. Liu, T. Hu, J.S. Li, L.Q. Dong, F. Du, C.M. Li, C.X. Guo, ChemSusChem 14 (2021) 1825-1829.
    [55]
    Y.T. Wang, Y.F. Yu, R.R. Jia, C. Zhang, B. Zhang, Natl. Sci. Rev. 6 (2019) 730-738.
    [56]
    Z.X. Wang, S.D. Young, B.R. Goldsmith, N. Singh, J. Catal. 395 (2021) 143-154.
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Get Citation
    PDF
    XML

    Article Metrics

    Article views (365) PDF downloads(11) Cited by()
    Proportional views

    Publish With GEE

    Contact

    • Email：gee@ipe.ac.cn
    • Tel：010-82627075
    • Address：North 2nd street, Zhongguancun, Haidian District, Beijing, China

    Links

    京ICP备10002620号-1京公网安备 11010802039050号

    Supported by: Beijing Renhe Information Technology Co. Ltd    

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return