Volume 8 Issue 5
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Article Navigation >  Green Energy&Environment  > 2023  >  8(5): 1371-1379
Jiamiao Ran, Hui Liu, Hongliang Dong, Peng Gao, Haowei Cheng, Jianing Xu, Hailun Wang, Zixing Wang, Qingfeng Fu, Jiaxu Yan, Jilei Liu. Accurate quantification of TiO2(B)'s phase purity via Raman spectroscopy. Green Energy&Environment, 2023, 8(5): 1371-1379. doi: 10.1016/j.gee.2022.02.008
Citation: Jiamiao Ran, Hui Liu, Hongliang Dong, Peng Gao, Haowei Cheng, Jianing Xu, Hailun Wang, Zixing Wang, Qingfeng Fu, Jiaxu Yan, Jilei Liu. Accurate quantification of TiO2(B)'s phase purity via Raman spectroscopy. Green Energy&Environment, 2023, 8(5): 1371-1379. doi: 10.1016/j.gee.2022.02.008
shu

Accurate quantification of TiO2(B)'s phase purity via Raman spectroscopy

doi: 10.1016/j.gee.2022.02.008

  • a. College of Materials Science and Engineering, Hunan Joint International Laboratory of Advanced Materials and Technology of Clean Energy, Hunan Province Key Laboratory for Advanced Carbon Materials and Applied Technology, Hunan University, Changsha, 410082, China;

  • b. College of Chemistry and Material Science, Hunan Agricultural University, Changsha, 410128 China;

  • c. Center for High Pressure Science and Technology Advanced Research, Pudong, Shanghai, 201203, China;

  • d. State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 201899, China;

  • e. Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM), Nanjing Tech University (Nanjing Tech), 30 South Puzhu Road, Nanjing, 211800, China

Funds:

This work was financially supported by the National Natural Science Foundation of China (22075074), Outstanding Young Scientists Research Funds from Hunan Province (2020JJ2004), Major Science and Technology Program of Hunan Province (2020WK2013), Natural Science Foundation of Hunan Province (2020JJ5035), National Natural Science Foundation of China (Grant No. 11704185) and the Opening Project of State Key Laboratory of High Performance Ceramics and Superfine Microstructure (SKL201802SIC). Beijing Synchrotron Radiation Facility (BSRF) and National Synchrotron Radiation Research Center (NSRRC) are greatly acknowledged for providing us beamtime for the XRD measurements.

  • Received date 08 November 2021, Accepted date 15 February 2022, RevRecd date 12 February 2022, Publish date 22 February 2022,
    Abstract
  • Bronze phase titanium dioxide (TiO2(B)) could be a promising high-power anode for lithium ion battery. However, TiO2(B) is a metastable material, so the as-synthesized samples are inevitably accompanied by the existence of anatase phases. It has been found that the TiO2(B)'s purity is positively correlated with its electrochemical performance. Herein, we have established an accurate quantification of the TiO2(B)/anatase ratio, by figuring out the function between the purity of TiO2(B) phase in the high purity range and its Raman spectra features in combination of the calibration by the synchrotron radiation X-ray diffraction (XRD). Compared with the time-consuming electrochemical method, the rapid, sensitive and non-destructive features of Raman spectroscopy have made it a promising candidate for determining the purity of TiO2(B). Further, the correlations developed in this work should be instructive in synthesizing pure TiO2(B) and furthermore optimizing its electrochemical charge storage properties.

     

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