Volume 8 Issue 4
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Bolin Wang, Chunxiao Jin, Shujuan Shao, Yuxue Yue, Yuteng Zhang, Saisai Wang, Renqin Chang, Haifeng Zhang, Jia Zhao, Xiaonian Li. Electron-deficient Cu site catalyzed acetylene hydrochlorination. Green Energy&Environment, 2023, 8(4): 1128-1140. doi: 10.1016/j.gee.2022.01.005
Citation: Bolin Wang, Chunxiao Jin, Shujuan Shao, Yuxue Yue, Yuteng Zhang, Saisai Wang, Renqin Chang, Haifeng Zhang, Jia Zhao, Xiaonian Li. Electron-deficient Cu site catalyzed acetylene hydrochlorination. Green Energy&Environment, 2023, 8(4): 1128-1140. doi: 10.1016/j.gee.2022.01.005
shu

Electron-deficient Cu site catalyzed acetylene hydrochlorination

doi: 10.1016/j.gee.2022.01.005

  • a. School of Chemical Engineering, Northeast Electric Power University, Jilin, 132012, China;

  • b. Industrial Catalysis Institute of Zhejiang University of Technology, Hangzhou, 310014, China;

  • c. Research Center of Analysis Measurement, Zhejiang University of Technology, Hangzhou, 310014, China

Funds:

grant No. U20A20119, 21606199, 22078302, 52070035), the Science and Technology Department of Zhejiang Province (LGG20B060004), the China Postdoctoral Science Foundation (2020M671791), the Jilin Province Scientific and the Technological Planning Project of China (No. 20200403001SF), and the National Key Research and Development Program of China (2021YFA1501800, 2021YFA1501801, 2021YFA1501802) are gratefully acknowledged.

Financial support from the National Natural Science Foundation of China (NSFC

  • Received date 01 October 2021, Accepted date 12 January 2022, RevRecd date 29 December 2021, Available online 07 July 2023, Publish date 19 January 2022,
    Abstract
  • Rational design of catalytic sites to activate the C≡C bond is of paramount importance to advance acetylene hydrochlorination. Herein, Cu sites with electron-rich and electron-deficient states were constructed by controlling the impregnation solutions. The π electrons flowing from acetylene to Cu site are facilitated over the electron-deficient Cu sites, achieving high activation of C≡C bond. The contradiction between the increased activation of acetylene required for enhanced catalytic activity and the resistance of Cu site to reduction by acetylene required for maintaining catalytic stability can be balanced by establishing strong interactions of Cu site with pyrrolic-N species. The catalytic activity displays a volcano shape scaling relationship as a function of Cu particle size. Tribasic copper chloride is concomitantly generated with the construction of electron-deficient Cu sites. The H–Cl bond of HCl can be activated over the tribasic copper chloride, accelerating the surface reaction of vinyl chloride production. This strategy of inducing electron deficiency provides new insight into the rational design of catalysts for the synthesis of vinyl chloride with a high catalytic performance.

     

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