Volume 8 Issue 4
Aug.  2023
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Article Navigation >  Green Energy&Environment  > 2023  >  8(4): 1071-1080
Chengwei Ma, Xinyu Zhang, Chengcai Liu, Yuanxing Zhang, Yuanshen Wang, Ling Liu, Zhikun Zhao, Borong Wu, Daobin Mu. Nano silica aerogel-induced formation of an organic/alloy biphasic interfacial layer enables construction of stable high-energy lithium metal batteries. Green Energy&Environment, 2023, 8(4): 1071-1080. doi: 10.1016/j.gee.2021.12.006
Citation: Chengwei Ma, Xinyu Zhang, Chengcai Liu, Yuanxing Zhang, Yuanshen Wang, Ling Liu, Zhikun Zhao, Borong Wu, Daobin Mu. Nano silica aerogel-induced formation of an organic/alloy biphasic interfacial layer enables construction of stable high-energy lithium metal batteries. Green Energy&Environment, 2023, 8(4): 1071-1080. doi: 10.1016/j.gee.2021.12.006
shu

Nano silica aerogel-induced formation of an organic/alloy biphasic interfacial layer enables construction of stable high-energy lithium metal batteries

doi: 10.1016/j.gee.2021.12.006

  • a. Beijing Key Laboratory of Environmental Science and Engineering, School of Materials Science and Engineering, Beijing Institute of Technology, Beijing, 100081, China;

  • b. Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing, 100081, China

Funds:

The authors are grateful for the support from National Natural Science Foundation of China (22179006), International Science &

Technology Cooperation Program of China under Contract No. 2019YFE0100200, National Natural Science Foundation of China (52072036), NSAF (No. U1930113), Guangdong Key Laboratory of Battery Safety, China (No. 2019B121203008), China Postdoctoral Science Foundation (No. 2021TQ0034).

  • Received date 03 November 2021, Accepted date 31 December 2021, RevRecd date 28 December 2021, Available online 07 July 2023, Publish date 05 January 2022,
    Abstract
  • Lithium metal batteries represent promising candidates for high-energy-density batteries, however, many challenges must still be overcome, e.g., interface instability and dendrite growth. In this work, nano silica aerogel was employed to generate a hybrid film with high lithium ion conductivity (0.6 mS cm-1 at room temperature) via an in situ crosslinking reaction. TOF-SIMS profile analysis has revealed conversion mechanism of hybrid film to Li–Si alloy/LiF biphasic interface layer, suggesting that the Li–Si alloy and LiF-rich interface layer promoted rapid Li+ transport and shielded the Li anodes from corrosive reactions with electrolyte-derived products. When coupled with nickel-cobalt-manganese-based cathodes, the batteries achieve outstanding capacity retention over 1000 cycles at 1 C. Additionally the developed film coated on Li enabled high coulombic efficiency (99.5%) after long-term cycling when coupled with S cathodes. Overall, the results presented herein confirm an effective strategy for the development of high-energy batteries.

     

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