Volume 8 Issue 2
Apr.  2023
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Article Navigation >  Green Energy&Environment  > 2023  >  8(2): 567-578
Kai Feng, Liang Zhang, Jiang Gong, Jinping Qu, Ran Niu. Visible light triggered exfoliation of COF micro/nanomotors for efficient photocatalysis. Green Energy&Environment, 2023, 8(2): 567-578. doi: 10.1016/j.gee.2021.09.002
Citation: Kai Feng, Liang Zhang, Jiang Gong, Jinping Qu, Ran Niu. Visible light triggered exfoliation of COF micro/nanomotors for efficient photocatalysis. Green Energy&Environment, 2023, 8(2): 567-578. doi: 10.1016/j.gee.2021.09.002
shu

Visible light triggered exfoliation of COF micro/nanomotors for efficient photocatalysis

doi: 10.1016/j.gee.2021.09.002

  • a. Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, Hubei Engineering Research Center for Biomaterials and Medical Protective Materials, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan, 430074, China;

  • b. The State Key Laboratory Breeding Base of Basic Science of Stomatology (Hubei-MOST) & Key Laboratory of Oral Biomedicine Ministry of Education, School and Hospital of Stomatology, Wuhan University, Wuhan 430079, China;

  • c. National Engineering Research Center of Novel Equipment for Polymer Processing, Key Laboratory of Polymer Processing Engineering, Ministry of Education, Guangdong Provincial Key Laboratory of Technique and Equipment for Macromolecular Advanced Manufacturing, School of Mechanical and Automotive Engineering, South China University of Technology, Guangzhou, 510641, China

Funds:

The present work is supported by Huazhong University of Science and Technology (No. 2021XXJS036 and 3004013134), National Natural Science Foundation of China (No. 51903099, 82002879 and 22102059), the Innovation and Talent Recruitment Base of New Energy Chemistry and Device (No. B21003), and China Postdoctoral Science Foundation (2021M692475, 2021T140524, XJ2021037).

  • Received date 15 June 2021, Accepted date 14 September 2021, RevRecd date 26 August 2021, Publish date 17 September 2021,
    Abstract
  • We report a new facile light-induced strategy to disperse micron-sized aggregated bulk covalent organic frameworks (COFs) into isolated COFs nanoparticles. This was achieved by a series of metal-coordinated COFs, namely COF-909-Cu, -Co or -Fe, where for the first time the diffusio-phoretic propulsion was utilized to design COF-based micro/nanomotors. The mechanism studies revealed that the metal ions decorated in the COF-909 backbone could promote the separation of electron and holes and trigger the production of sufficient ionic and reactive oxygen species under visible light irradiation. In this way, strong light-induced self-diffusiophoretic effect is achieved, resulting in good dispersion of COFs. Among them, COF-909-Fe showed the highest dispersion performance, along with a drastic decrease in particle size from 5 μm to 500 nm, within only 30 min light irradiation, which is inaccessible by using traditional magnetic stirring or ultrasonication methods. More importantly, benefiting from the outstanding dispersion efficiency, COF-909-Fe micro/nanomotors were demonstrated to be efficient in photocatalytic degradation of tetracycline, about 8 times faster than using traditional magnetic stirring method. This work opens up a new avenue to prepare isolated nanosized COFs in a high-fast, simple, and green manner.

     

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