Volume 7 Issue 6
Dec.  2022
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Article Navigation >  Green Energy&Environment  > 2022  >  7(6): 1377-1389
Yan Zhang, Yixiao Wu, Liang Wan, Wenfeng Yang, Huijun Ding, Chongyang Lu, Weihao Zhang, Zipeng Xing. Double Z-Scheme g-C3N4/BiOI/CdS heterojunction with I3-/I- pairs for enhanced visible light photocatalytic performance. Green Energy&Environment, 2022, 7(6): 1377-1389. doi: 10.1016/j.gee.2021.08.004
Citation: Yan Zhang, Yixiao Wu, Liang Wan, Wenfeng Yang, Huijun Ding, Chongyang Lu, Weihao Zhang, Zipeng Xing. Double Z-Scheme g-C3N4/BiOI/CdS heterojunction with I3-/I- pairs for enhanced visible light photocatalytic performance. Green Energy&Environment, 2022, 7(6): 1377-1389. doi: 10.1016/j.gee.2021.08.004
shu

Double Z-Scheme g-C3N4/BiOI/CdS heterojunction with I3-/I- pairs for enhanced visible light photocatalytic performance

doi: 10.1016/j.gee.2021.08.004

  • a. College of Resource and Environmental Science, Hubei Biomass-Resource Chemistry and Environmental Biotechnology Key Laboratory, Wuhan University, Wuhan, 430072, China;

  • b. Department of Environmental Science, School of Chemistry and Materials Science, Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education of the People's Republic of China, Heilongjiang University, Harbin, 150080, China;

  • c. Jiangxi Provincial Key Laboratory of Water Resources and Environment of Poyang Lake, Jiangxi Institute of Water Sciences, Nanchang, Jiangxi, 330029, China

Funds:

We gratefully acknowledge the support of this work by the National Natural Science Foundation of China (51869006), Jiangxi Natural Science Foundation of China (20171BAB216050), Water Science and Technology Fund of Jiangxi Province in China (KT201702).

  • Received date 24 May 2021, Accepted date 30 August 2021, RevRecd date 17 August 2021, Publish date 31 December 2022,
    Abstract
  • The g-C3N4/BiOI/CdS double Z-scheme heterojunction photocatalyst with I3-/I- redox pairs is prepared using simple calcination, solvothermal, and solution chemical deposition methods. The photocatalyst comprised mesoporous, thin g-C3N4 nanosheets loaded on flower-like microspheres of BiOI with CdS quantum dots. The g-C3N4/BiOI/CdS double Z-scheme heterojunction has abundant active sites and in situ redox I3-/I- mediators and shows quantum size effects, which are all conducive to enhancing the separation of photoinduced charges and increasing the photocatalytic degradation efficiency for bisphenol A, a model pollutant. Specifically, the heterojunction photocatalyst achieves a photocatalytic degradation efficiency for bisphenol A of 98.62% in 120 min and photocatalytic hydrogen production of 863.44 μmol h-1g-1 on exposure to visible light. The excellent visible-light photocatalytic performance is as a result of the Z-scheme heterojunction, which extends absorption to the visible light region, as well as the I3-/I- pairs, which accelerate photoinduced charge carrier transfer and separation, thus dramatically boosting the photocatalytic performance. In addition, the key role of the charge transfer across the indirect Z-scheme heterojunction has been elucidated and the transfer mechanism is confirmed based on the detection of intermediate I3- ions. Thus, this study provides guidelines for the design of indirect Z-scheme heterojunction photocatalysts.

     

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