Volume 7 Issue 4
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Xinru Tang, Nan Li, Huan Pang. Metal-organic frameworks-derived metal phosphides for electrochemistry application. Green Energy&Environment, 2022, 7(4): 636-661. doi: 10.1016/j.gee.2021.08.003
Citation: Xinru Tang, Nan Li, Huan Pang. Metal-organic frameworks-derived metal phosphides for electrochemistry application. Green Energy&Environment, 2022, 7(4): 636-661. doi: 10.1016/j.gee.2021.08.003
shu

Metal-organic frameworks-derived metal phosphides for electrochemistry application

doi: 10.1016/j.gee.2021.08.003

  • School of Chemistry and Chemical Engineering, Institute for Innovative Materials and Energy, Yangzhou University, Yangzhou, 225009, Jiangsu, China

Funds:

This work was supported by the National Natural Science Foundation of China (U1904215), Natural Science Foundation of Jiangsu Province (BK20200044), Changjiang scholars program of the Ministry of Education (Q2018270).

  • Received date 19 March 2021, Accepted date 28 August 2021, RevRecd date 04 August 2021, Publish date 01 September 2021,
    Abstract
  • Metal-organic frameworks (MOFs) with high porosity and variable structure have attracted extensive attention in the field of electrochemistry, but their poor conductivity and stability have limited their development. Materials derived from MOFs can maintain the structural diversity and porosity characteristics of MOFs while improving their electrical conductivity and stability. Metal phosphides play an important role in electrochemistry because they possess rich active sites, unique physicochemical properties, and a porous structure. Published results show that MOF-derived metal-phosphides materials have great promise in the field of electrochemistry due to their controllable structure, high specific surface area, high stability and excellent electrical conductivity. MOF-derived metal-phosphides with significant electrochemical properties can be obtained by simply, economical and scalable synthetic methods. This work reviews the application of MOF-derived metal phosphides in electrochemistry. Specifically, the synthesis methodology and morphological characterization of MOFs derived metal-phosphides and their application in electrochemistry are described. Based on recent scientific advances, we discuss the challenges and opportunities for future research on MOF-derived metal-phosphides materials.

     

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