Volume 7 Issue 6
Dec.  2022
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Article Navigation >  Green Energy&Environment  > 2022  >  7(6): 1327-1339
Tengfei Wang, Danning Zheng, Beibei An, Yi Liu, Tiegang Ren, Hans Ågren, Li Wang, Jinglai Zhang, Mårten S.G. Ahlquist. Dual-ionic imidazolium salts to promote synthesis of cyclic carbonates at atmospheric pressure. Green Energy&Environment, 2022, 7(6): 1327-1339. doi: 10.1016/j.gee.2021.02.011
Citation: Tengfei Wang, Danning Zheng, Beibei An, Yi Liu, Tiegang Ren, Hans Ågren, Li Wang, Jinglai Zhang, Mårten S.G. Ahlquist. Dual-ionic imidazolium salts to promote synthesis of cyclic carbonates at atmospheric pressure. Green Energy&Environment, 2022, 7(6): 1327-1339. doi: 10.1016/j.gee.2021.02.011
shu

Dual-ionic imidazolium salts to promote synthesis of cyclic carbonates at atmospheric pressure

doi: 10.1016/j.gee.2021.02.011

  • a. Henan Engineering Research Center of Green Anticorrosion Technology for Magnesium Alloys, Henan University, Kaifeng, Henan, 475004, China;

  • b. Henan Engineering Research Center of Corrosion and Protection for Magnesium Alloys, Henan University, Kaifeng, Henan, 475004, China;

  • c. College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, 475004, China;

  • d. Department of Theoretical Chemistry & Biology, School of Biotechnology, KTH Royal Institute of Technology, 10691 Stockholm, Sweden

Funds:

We thank the National Supercomputing Center in Shenzhen (Shenzhen Cloud Computing Center) and the National Supercomputing Center in Changsha (Changsha Cloud Computing Center) for providing computational resources. This work was supported by the National Natural Science Foundation of China (21975064), Program of Henan Center for Outstanding Overseas Scientists (GZS2020011), Henan University's first-class discipline science and technology research project (2018YLTD07, 2018YLZDYJ11, 2019YLZDYJ09), and the Excellent Foreign Experts Project of Henan University

  • Received date 18 September 2020, Accepted date 22 February 2021, RevRecd date 03 February 2021, Publish date 31 December 2022,
    Abstract
  • Novel dual-ionic imidazolium salts are shown to display excellent catalytic activity for cycloaddition of carbon dioxide and epoxides under room temperature and atmospheric pressure (0.1 MPa) without any solvent and co-catalyst leading to 96.1% product yield. It can be reused five times to keep the product yield over 90%. These intriguing results are attributed to a new reaction mechanism, which is supported by theoretical calculations along with the measurements of 13C NMR spectrum and Fourier transform infrared spectroscopy (FT-IR). The excellent catalytic activity can be traced to a CO2-philic group along with an electrophilic hydrogen atom. Our work shows that incorporation of CO2-philic group is an feasible pathway to develop the new efficient ionic liquids.

     

    • • A series of novel Dual-ionic imidazolium salts are synthesized. • The 98.9% CPC yield could be achieved under 50 °C and 1 bar CO2. • A new reaction mechanism is proposed.
    These authors contributed equally to this work.
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