Volume 7 Issue 6
Dec.  2022
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Article Navigation >  Green Energy&Environment  > 2022  >  7(6): 1289-1297
Lingxia Zheng, Weiqing Ye, Pengju Yang, Jianlan Song, Xiaowei Shi, Huajun Zheng. Manganese doping to boost the capacitance performance of hierarchical Co9S8@Co(OH)2 nanosheet arrays. Green Energy&Environment, 2022, 7(6): 1289-1297. doi: 10.1016/j.gee.2021.02.002
Citation: Lingxia Zheng, Weiqing Ye, Pengju Yang, Jianlan Song, Xiaowei Shi, Huajun Zheng. Manganese doping to boost the capacitance performance of hierarchical Co9S8@Co(OH)2 nanosheet arrays. Green Energy&Environment, 2022, 7(6): 1289-1297. doi: 10.1016/j.gee.2021.02.002
shu

Manganese doping to boost the capacitance performance of hierarchical Co9S8@Co(OH)2 nanosheet arrays

doi: 10.1016/j.gee.2021.02.002

  • a. State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, Zhejiang University of Technology, Hangzhou, 310014, China;

  • b. Department of Applied Chemistry, Zhejiang University of Technology, Hangzhou, 310014, China

Funds:

The authors would like to acknowledge the financial support from Natural Science Foundation of Zhejiang Province (LY21B030005) and National Natural Science Foundation of China (51702287).

  • Received date 03 November 2020, Accepted date 04 February 2021, RevRecd date 03 February 2021, Publish date 31 December 2022,
    Abstract
  • Transition metal sulfides (TMSs) have been regarded as greatly promising electrode materials for supercapacitors because of abundant redox electroactive sites and outstanding conductivity. Herein, we report a self-supported hierarchical Mn doped Co9S8@Co(OH)2 nanosheet arrays on nickel foam (NF) substrate by a one-step metal–organic-framework (MOF) engaged approach and a subsequent sulfurization process. Experimental results reveal that the introduction of manganese endows improved electric conductivity, enlarged electrochemical specific surface area, adjusted electronic structure of Co9S8@Co(OH)2 and enhanced interfacial activities as well as facilitated reaction kinetics of electrodes. The optimal Mn doped Co9S8@Co(OH)2 electrode exhibits an ultrahigh specific capacitance of 3745 F g-1 at 1 A g-1 (5.618 F cm-2 at 1.5 mA cm-2) and sustains 1710 F g-1 at 30 A g-1 (2.565 F cm-2 at 45 mA cm-2), surpassing most reported values on TMSs. Moreover, a battery-type asymmetric supercapacitor (ASC) device is constructed, which delivers high energy density of 50.2 Wh kg-1 at power density of 800 W kg-1, and outstanding long-term cycling stability (94% capacitance retention after 8000 cycles). The encouraging results might offer an effective strategy to optimize the TMSs for energy-storage devices.

     

    • • Self-supported hierarchical Mn doped Co9S8/Co(OH)2 nanosheet arrays are fabricated. • Introduction of Mn dopants adjusts electronic structure and interfacial active sites. • The optimal electrode endows ultrahigh specific capacitance and excellent stability. • Asymmetric supercapacitor exhibits high energy density and outstanding cycle life.
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