Volume 7 Issue 6
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Article Navigation >  Green Energy&Environment  > 2022  >  7(6): 1228-1240
Jae-Gyoung Seong, Tae Hoon Ko, Danyun Lei, Woong-Ki Choi, Yun-Su Kuk, Min-Kang Seo, Byoung-Suhk Kim. Engineered NiCo-LDH nanosheets- and ZnFe2O4 nanocubes-decorated carbon nanofiber bonded mats for high-rate asymmetric supercapacitors. Green Energy&Environment, 2022, 7(6): 1228-1240. doi: 10.1016/j.gee.2021.01.015
Citation: Jae-Gyoung Seong, Tae Hoon Ko, Danyun Lei, Woong-Ki Choi, Yun-Su Kuk, Min-Kang Seo, Byoung-Suhk Kim. Engineered NiCo-LDH nanosheets- and ZnFe2O4 nanocubes-decorated carbon nanofiber bonded mats for high-rate asymmetric supercapacitors. Green Energy&Environment, 2022, 7(6): 1228-1240. doi: 10.1016/j.gee.2021.01.015
shu

Engineered NiCo-LDH nanosheets- and ZnFe2O4 nanocubes-decorated carbon nanofiber bonded mats for high-rate asymmetric supercapacitors

doi: 10.1016/j.gee.2021.01.015

  • a. Department of Organic Materials & Fiber Engineering, Jeonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju-si, Jeollabuk-do, 54896, Republic of Korea;

  • b. Department of BIN Convergency Technology, Jeonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju-si, Jeollabuk-do, 54896, Republic of Korea;

  • c. Korea Institute of Carbon Convergence Technology, Jeonju, 54852, Republic of Korea;

  • d. Department of Environmental Biology and Water Engineering, College of Urban Construction, Wuchang Shouyi University, Wuhan, 430064, China

Funds:

This work was supported by the National Research Foundation of Korea grant funded by the Korea government (MSIT) (No. 2020R1A2C2012356) and also by the National Research Foundation of Korea grant funded by the Korea government (MSIT) (2020R1I1A1A01073937).

  • Received date 29 July 2020, Accepted date 19 January 2021, RevRecd date 31 December 2020, Publish date 31 December 2022,
    Abstract
  • In this work, we have prepared the hierarchically nanostructured core–shell NiCo layered double hydroxide (NiCo-LDH) nanosheets- and ZnFe2O4 nanocubes-decorated polyacrylonitrile (PAN)/pitch-based carbon nanofibers (PPCNs) webs (NiCo-LDH@PPCNs as cathode and ZnFe2O4@PPCNs as anode materials) with the bonded network structure by a facile and scalable hydrothemal method. Herein, the low-cost pitch with lower softening point (∼90 °C) as co-precursor was utilized to produce the PAN/pitch-based carbon nanofibers (PPCNs) with enhanced electrical conductivity. The obtained PPCNs with pitch content of 30% (PP30CNs) electrode material delivered higher specific capacitance (∼67 F g-1) than that (∼48 F g-1) of the PAN-based carbon nanofibers (PCNs) at 1 A g-1, due to the increased electrical conductivity and lower interfacial charge transfer resistance (RCT) of ∼0.16 Ω. Further, the NiCo-LDH-decorated PP30CNs (NiCo-LDH@PP30CNs) as cathode material showed superior specific capacitance of 1162 F g-1 at 1.0 A g-1 and ultra-high retention rate of 91.56% at 10 A g-1. The ZnFe2O4@PP30CNs as anode material also showed higher specific capacitance of 282 F g-1 at 1 A g-1 and good rate capability with capacitance retention of 56.73% at 10 A g-1. The as-fabricated asymmetric NiCo-LDH@PP30CNs//ZnFe2O4@PP30CNs hybrid supercapacitor device delivered a specific capacitance of ∼98 F g-1 at 1 A g-1 and excellent capacitance retention of ∼88% after 5000 charge–discharge cycles.

     

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    • References(44)
  • [1]
    G. Liu, B. Wang, L. Wang, W. Wei, Y. Quan, C. Wang, W. Zhu, H. Li, J. Xia, Green Energy Environ. 7 (2022) 423–431.
    [2]
    C.H. Chen, D. Wu, Z. Li, R. Zhang, C.G. Kuai, X.R. Zhao, C.K. Dong, S.Z. Qiao, H. Liu, X.W. Du, Adv. Energy Mater. 9 (2019) 1803913.
    [3]
    G. Liu, Y. Wu, R. Yao, F. Zhao, J. Li, Green Energy Environ. 6 (2021) 496–505.
    [4]
    D. Ouyang, J. Xiao, F. Ye, Z. Huang, H. Zhang, L. Zhu, J. Cheng, W.C.H. Choy, Adv. Energy Mater. 8 (2018) 1702722.
    [5]
    X. Gao, H. Zhang, Q. Li, X. Yu, Z. Hong, X. Zhang, C. Liang, Z. Lin, Angew. Chem. Int. Ed. 55 (2016) 6290–6294.
    [6]
    L. Kumar, M. Chauhan, P.K. Boruah, M.R. Das, S.A. Hashmi, S. Deka, ACS Appl. Energy Mater. 3 (2020) 6793–6804.
    [7]
    J. Wang, T. Qiu, X. Chen, Y. Lu, W. Yang, J. Power Sources 268 (2014) 341–348.
    [8]
    S. Farhadi, J. Safabakhsh, J. Alloys Compd. 515 (2012) 180–185.
    [9]
    X. Ge, C.D. Gu, Y. Lu, X.L. Wang, J.P. Tu, J. Mater. Chem. A 1 (2013) 13454–13461.
    [10]
    Y. Li, B. Tan, Y. Wu, Chem. Mater. 20 (2008) 567–576.
    [11]
    Y. Chen, T.C. Mu, Green Energy Environ. 4 (2019) 95–115.
    [12]
    G.M. Thorat, H.S. Jadhav, A. Roy, W.J. Chung, J.G. Seo, ACS Sustain. Chem. Eng. 6 (2018) 16255–16266.
    [13]
    A.P. Abbott, G. Capper, D.L. Davies, K.J. McKenzie, S.U. Obi, J. Chem. Eng. Data 51 (2006) 1280–1282.
    [14]
    H.Y. Mou, J.F. Wang, D.K. Yu, D.L. Zhang, F. Lu, L. Chen, D.B. Wang, T.C. Mu, J. Mater. Chem. A 7 (2019) 13455–13459.
    [15]
    W.Y. Tang, K.H. Row, J. Clean. Prod. 268 (2020) 122306.
    [16]
    G.Z. Li, K.H. Row, J. Separ. Sci. 41 (2018) 3424–3431.
    [17]
    W.Y. Tang, G.Z. Li, B.Q. Chen, T. Zhu, K.H. Row, Separ. Sci. Technol. 52 (2017) 91–99.
    [18]
    R.H. Lee, K.H. Row, J. Ind. Eng. Chem. 39 (2016) 87–92.
    [19]
    L.L. Liu, W.Y. Tang, B.K. Tang, D.D. Han, K.H. Row, Tao Zhu, J. Separ. Sci. 40 (2017) 1887–1895.
    [20]
    X.H. Zhao, Z.M. Xue, W.J. Chen, Y.Q. Wang, T.C. Mu, ChemSusChem 13 (2020) 2038–2042.
    [21]
    H.Y. Mou, J.F. Wang, D.L. Zhang, D.K. Yu, W.J. Chen, D.B. Wang, T.C. Mu, J. Mater. Chem. A 7 (2019) 5719–5725.
    [22]
    C. Zhang, T. Chen, H. Zhang, Z. Li, J. Hao, Chem. Asian J. 14 (2019) 2995–3002.
    [23]
    S. Liu, C. Zhang, B. Zhang, Z. Li, J. Hao, ACS Sustain. Chem. Eng. 7 (2019) 8964–8971.
    [24]
    S. Liu, T. Chen, H. Ying, Z. Li, J. Hao, Adv. Sustainable Syst. 4 (2020) 2000038.
    [25]
    C. Zhang, B. Zhang, Z. Li, J. Hao, ACS Appl. Energy Mater. 2 (2019) 3343–3351.
    [26]
    J.M. Zhang, S.N. Sun, Y. Li, X.J. Zhang, P.Y. Zhang, Y.J. Fan, Int. J. Hydrogen Energy 42 (2017) 26744–26751.
    [27]
    A.P. Abbott, K. El Ttaib, G. Frisch, K.J. McKenzie, K.S. Ryder, Phys. Chem. Chem. Phys. 11 (2009) 4269–4277.
    [28]
    J. Niu, H. Liu, Y. Zhang, X. Wang, J. Han, Z. Yue, E. Duan, Chemosphere 259 (2020) 127427.
    [29]
    J. Hartley, C. Ip, G. Forrest, K. Singh, S.J. Gurman, K.S. Ryder, A.P. Abbott, G. Frisch, Inorg. Chem. 53 (2014) 6280–6288.
    [30]
    J.M. Terrasse, H. Pqulet, J.P. Mathieu, Spectrochim. Acta 20 (1964) 305–315.
    [31]
    K. Fominykh, J.M. Feckl, J. Sicklinger, M. Döblinger, S. Böcklein, J. Ziegler, L.M. Peter, J. Rathousky, E. Scheidt, T. Bein, D. FattakhovaRohlfing, Adv. Funct. Mater. 24 (2014) 3123–3129.
    [32]
    J. Li, Z. Xia, X. Zhou, Y.B. Qin, Y. Ma, Y. Qu, Nano Res 10 (2017) 814–825.
    [33]
    J. Jiang, C. Yan, X. Zhao, H. Luo, Z. Xue, T. Mu, Green Chem. 19 (2017) 3023–3031.
    [34]
    B. Cui, H. Lin, J. Li, X. Li, J. Yang, J. Tao, Adv. Funct. Mater. 18 (2008) 1440–1447.
    [35]
    O.S. Hammond, K.J. Edler, D.T. Bowron, L. Torrentemurciano, Nat. Commun. 8 (2017) 14150.
    [36]
    A.P. Abbott, R.C. Harris, K.S. Ryder, C. D'Agostino, L.F. Gladden, M.D. Mantle, Green Chem. 13 (2011) 82–90.
    [37]
    Z. Peng, D. Jia, A.M. Al-Enizi, A.A. Elzatahry, G. Zheng, Adv. Energy Mater. 5 (2015) 1402031.
    [38]
    C. Broicher, F. Zeng, J. Artz, H. Hartmann, A. Besmehn, S. Palkovits, R. Palkovits, ChemCatChem 11 (2019) 412–416.
    [39]
    L. Fang, Z. Jiang, H. Xu, L. Liu, Y. Guan, X. Gu, Y. Wang, J. Catal. 357 (2018) 238–246.
    [40]
    A.R. Jadhav, H.A. Bandal, A.A. Chaugule, H. Kim, Electrochim. Acta 240 (2017) 277–287.
    [41]
    Z. Zhang, X. Liang, J. Li, J. Qian, Y. Liu, S. Yang, Y. Wang, D. Gao, D. Xue, ACS Appl. Mater. Interfaces 12 (2020) 21661–21669.
    [42]
    S. Chen, S.Z. Qiao, ACS Nano 7 (2013) 10190–10196.
    [43]
    H. Wang, Y. Hsu, R. Chen, T. Chan, H.M. Chen, B. Liu, Adv. Energy Mater. 5 (2015) 1500091.
    [44]
    Z.L. Wang, J. Phys. Chem. B 104 (2000) 1153–1175.
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