Volume 7 Issue 5
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Article Navigation >  Green Energy&Environment  > 2022  >  7(5): 1084-1092
Duan-Jian Tao, Xin Zhao, Yanxin Wang, Xixi Liu, Hong-Ping Li, Zhang-Min Li, Yan Zhou, Ziliang Yuan, Zehui Zhang. Vitamin B9 derived nitrogen-doped graphene for metal-free aerobic oxidation of biomass-derived chemicals. Green Energy&Environment, 2022, 7(5): 1084-1092. doi: 10.1016/j.gee.2021.01.008
Citation: Duan-Jian Tao, Xin Zhao, Yanxin Wang, Xixi Liu, Hong-Ping Li, Zhang-Min Li, Yan Zhou, Ziliang Yuan, Zehui Zhang. Vitamin B9 derived nitrogen-doped graphene for metal-free aerobic oxidation of biomass-derived chemicals. Green Energy&Environment, 2022, 7(5): 1084-1092. doi: 10.1016/j.gee.2021.01.008
shu

Vitamin B9 derived nitrogen-doped graphene for metal-free aerobic oxidation of biomass-derived chemicals

doi: 10.1016/j.gee.2021.01.008

  • a College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang, 330022, China;

  • b Key Laboratory of Catalysis and Materials Sciences of the Ministry of Education, South-Central University for Nationalities, Wuhan, 430074, China;

  • c Institute for Energy Research, Jiangsu University, Zhenjiang, 212013, China

Funds:

We are grateful for financial support from the National Natural Science Foundations of China (22068013,31570560),and 21922513the Natural Science Foundations of Jiangxi Province (20192ACBL20025), and the Science and Technology Programs of Jiangxi Province Department of Education (GJJ160272).

  • Received date 03 August 2020, Accepted date 08 January 2021, RevRecd date 25 December 2020, Publish date 13 January 2021,
    Abstract
  • A superior carbocatalyst ultrahigh N-doped graphene (NG) was prepared by a novel self-sacrificial templating method of one-step annealing vitamin B9. The NG catalyst with pyrolysis temperature of 800 ℃ (abbreviated VB9-NG-800) has an ultrahigh nitrogen content of 13.5 wt% and demonstrated the highest activity for the oxidation of bio-based alcohols and terpenes with molecular oxygen without any additives. Systematic characterizations and quantum-chemical calculations further manifested that high contents of graphitic N and pyridinic N species in VB9-NG-800 promoted the generation of ·O2- active species from molecular oxygen effortlessly, resulting in excellent catalytic performance for aerobic oxidation.

     

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