Volume 7 Issue 6
Dec.  2022
Turn off MathJax
Article Contents
Article Navigation >  Green Energy&Environment  > 2022  >  7(6): 1361-1376
Huanhuan Yang, Liguo Wang, Shuang Xu, Yan Cao, Peng He, Jiaqiang Chen, Zheng Zheng, Huiquan Li. Green and selective hydrogenation of aromatic diamines over the nanosheet Ru/g-C3N4-H2 catalyst prepared by ultrasonic assisted impregnation-deposition method. Green Energy&Environment, 2022, 7(6): 1361-1376. doi: 10.1016/j.gee.2021.01.003
Citation: Huanhuan Yang, Liguo Wang, Shuang Xu, Yan Cao, Peng He, Jiaqiang Chen, Zheng Zheng, Huiquan Li. Green and selective hydrogenation of aromatic diamines over the nanosheet Ru/g-C3N4-H2 catalyst prepared by ultrasonic assisted impregnation-deposition method. Green Energy&Environment, 2022, 7(6): 1361-1376. doi: 10.1016/j.gee.2021.01.003
shu

Green and selective hydrogenation of aromatic diamines over the nanosheet Ru/g-C3N4-H2 catalyst prepared by ultrasonic assisted impregnation-deposition method

doi: 10.1016/j.gee.2021.01.003

  • a. Key Laboratory of Green Process and Engineering, National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, 100190, China;

  • b. Chemical and Biochemical Engineering, Technical University of Denmark, Lyngby 2800 Kgs, Denmark;

  • c. Sino-Danish College, University of Chinese Academy of Sciences, Beijing, 100049, China;

  • d. Sino-Danish Center for Education and Research, University of Chinese Academy of Sciences, Beijing, 100049, China;

  • e. School of Chemical Engineering, University of Chinese Academy of Sciences, Beijing, 100049, China;

  • f. Dalian National Laboratory for Clean Energy, Dalian, 116023, China

Funds:

This work was financially supported by the National Nature Science Foundation of China (21576272), “Transformational Technologies for Clean Energy and Demonstration”, Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDA 21030600) and Science and Technology Service Network Initiative, Chinese Academy of Sciences (KFJ-STS-QYZD-138).

  • Received date 19 September 2020, Accepted date 06 January 2021, RevRecd date 22 December 2020, Publish date 31 December 2022,
    Abstract
  • In this study, nanosheet g-C3N4-H2 was prepared by thermal exfoliation of bulk g-C3N4 under hydrogen. A series of Ru/g-C3N4-H2 catalysts with Ru species supported on the nanosheet g-C3N4-H2 were synthesized via ultrasonic assisted impregnation-deposition method. Ultrafine Ru nanoparticles (<2 nm) were highly dispersed on nanosheet g-C3N4-H2. Strong interaction due to Ru-Nx coordination facilitated the uniform distribution of Ru species. Meanwhile, the involvement of surface basicity derived from abundant nitrogen sites was favourable for enhancing the selective hydrogenation performance of bi-benzene ring, i.e., almost complete 4,4′-diaminodiphenylmethane (MDA) conversion and >99% 4,4′-diaminodicyclohexylmethane selectivity, corresponding to a reaction activity of 35.7 molMDA molRu-1 h-1. Moreover, the reaction activity of catalyst in the fifth run was 36.5 molMDA molRu-1 h-1, which was comparable with that of the fresh one. The computational results showed that g-C3N4 as support was favorable for adsorption and dissociation of H2 molecules. Moreover, the substrate scope can be successfully expanded to a variety of other aromatic diamines. Therefore, this work provides an efficient and green catalyst system for selective hydrogenation of aromatic diamines.

     

    • FullText(HTML)
  • loading
    • References(52)
  • [1]
    S. Behar, N.-A. Gómez-Mendoza, M.-Á. Gómez-García, D. Świerczyński, F. Quignard, N. Tanchoux, Appl. Catal. A-Gen. 504 (2015) 203–210.
    [2]
    J. Łojewska, A. Kołodziej, J. Zak, J. Stoch, Appl. Catal. B Environ. 105 _ (2005) 655–661.
    [3]
    S.A. Hosseini, A. Niaei, D. Salari, S.R. Nabavi, Ceram. Int. 38 (2012) 1655–1661.
    [4]
    J. Zhong, Y. Zeng, D. Chen, S. Mo, M. Zhang, M. Fu, J. Wu, Z. Su, P. Chen, D. Ye, J. Hazard. Mater. 386 (2020) 121957.
    [5]
    Y. Zhang, M. Wua, Y. Wang, Y. Kwok, W. Pan, W. Szeto, H. Huang, D.Y.C. Leung, Appl. Catal. B Environ. 28 (2019) 225–231.
    [6]
    S.A. Hosseini, M.T. Sadeghi, A. Alemi, A. Niaei, D. Salari, L. KafiAhmadi, Chinese J. Catal. 31 (2010) 747–750.
    [7]
    U. Menon, V.V. Galvita, G.B. Marin, J. Catal. 283 (2011) 1–9.
    [8]
    L. Zhao, Z. Zhang, Y. Li, X. Leng, T. Zhang, F. Yuan, X. Niu, Y. Zhu, Appl. Catal. B Environ. 245 (2019) 502–512.
    [9]
    F. Dong, W. Han, H. Zhao, G. Zhang, Z. Tang, Nanoscale 11 (2019) 9937–9948.
    [10]
    C. Zhang, J. Wang, S. Yang, H. Liang, Y. Men, J. Colloid Interface Sci. 539 (2019) 65–75.
    [11]
    X. Wang, Y. Liu, T. Zhang, Y. Luo, Z. Lan, K. Zhang, J. Zuo, L. Jiang, R. Wang, ACS Catal. 7 (2017) 1626–1636.
    [12]
    Z. Zhang, Z. Fan, H. Guo, W. Fang, M. Chen, W. Shangguan, Catal. Today 332 (2019) 139–143.
    [13]
    M. Luo, Y. Cheng, X. Peng, W. Pan, Chem. Eng. J. 369 (2019) 758–765.
    [14]
    X. Jiang, W. Xu, S. Lai, X. Chen, RSC Adv. 9 (2019) 6533–6541.
    [15]
    S. Zhao, F. Hu, J. Li, ACS Catal. 6 (2016) 3433–3441.
    [16]
    S. Li, H. Wang, W. Li, X. Wu, W. Tang, Y. Chen, Appl. Catal. B Environ. 166–167 (2015) 260–269.
    [17]
    Y. Li, F. Liu, Y. Fan, G. Cheng, W. Song, J. Zhou, Appl. Surf. Sci. 462 (2018) 207–212.
    [18]
    X. Fu, Y. Liu, W. Yao, Z. Wu, Catal. Commun. 83 (2016) 22–26.
    [19]
    H. Huang, Y. Xu, Q. Feng, D.Y.C. Leung, Catal. Sci. Technol. 5 (2015) 2649–2669.
    [20]
    J. Mei, J. Xie, Z. Qu, Y. Ke, X. Hu, N. Yan, Mol. Catal. 461 (2018) 60–66.
    [21]
    H. Peng, T. Dong, L. Zhang, C. Wang, W. Liu, J. Bao, X. Wang, N. Zhang, Z. Wang, P. Wu, P. Zhang, S. Dai, Appl. Catal. B Environ. 256 (2019) 117807.
    [22]
    C.H. Wang, S.S. Lin, C.L. Chen, H.S. Weng, Chemosphere 64 (2006) 503–509.
    [23]
    Z. Sihai, F. Puleo, J.M. Garcia-Vargas, L. Retailleau, C. Descorme, L.F. Liotta, J.L. Valverde, S. Gil, Appl. Catal. B Environ. 209 (2017) 689–700.
    [24]
    F. Liu, M. Zeng, Y. Li, Y. Yang, M. Mao, X. Zhao, Adv. Funct. Mater. 26 (2016) 4518–4526.
    [25]
    Y. Xia, L. Xia, Y. Liu, T. Yang, J. Deng, H. Dai, J. Environ. Sci. 256 (2019) 276–288.
    [26]
    H. Zhang, S. Sui, X. Zheng, R. Cao, P. Zhang, Appl. Catal. B Environ. 257 (2019) 117878.
    [27]
    Y. Wang, H. Arandiyan, Y. Liu, Y. Liang, Y. Peng, S. Bartlett, H. Dai, S. Rostamnia, J. Li, ChemCatChem 10 (2018) 3429–3434.
    [28]
    S. Zhao, T. Liu, D. Hou, W. Zeng, B. Miao, S. Hussain, X. Peng, M.S. Javed, Appl. Surf. Sci. 356 (2015) 259–265.
    [29]
    T. Chang, Z. Shen, Y. Huang, J. Lu, D. Ren, J. Sun, J. Cao, H. Liu, Chem. Eng. J. 348 (2018) 15–25.
    [30]
    Q. Zhao, L. Liu, R. Liu, L. Zhu, Chem. Eng. J. 353 (2018) 311–318.
    [31]
    H.S. Saroyan, A. Arampatzidou, D. Voutsa, N.K. Lazaridis, E.A. Deliyanni, Colloid. Surface. A 566 (2019) 166–175.
    [32]
    C. He, J. Li, P. Li, J. Cheng, Z. Hao, Z.-P. Xu, Appl. Catal. B Environ. 96 (2010) 466–475.
    [33]
    J. Wang, J. Li, C. Jiang, P. Zhou, P. Zhang, J. Yu, ACS Appl. Mater. Interfaces 204 (2017) 147–155.
    [34]
    B.A. Pinaud, Z. Chen, D.N. Abram, T.F. Jaramillo, J. Phys. Chem. C 21 (2011) 11830–11838.
    [35]
    L. Yue, C. He, X. Zhang, P. Li, Z. Wang, H. Wang, Z. Hao, J. Hazard. Mater. 244–245 (2013) 613–620.
    [36]
    G. Liu, Y. Tian, B. Zhang, L. Wang, X. Zhang, J. Hazard. Mater. 367 (2019) 568–576.
    [37]
    Z. Hao, Z. Shen, Y. Li, H. Wang, L. Zheng, R. Wang, G. Liu, S. Zhan, Angew. Chem. Int. Ed. 58 (2019) 6351–6356.
    [38]
    H. Xia, J. Feng, H. Wang, M.O. Lai, L. Lu, J. Power Sources 195 (2010) 4410–4413.
    [39]
    Y. Wan, W. Zhao, Y. Tang, L. Li, H. Wang, Y. Cui, J. Gu, Y. Li, J. Shi, Appl. Catal. B Environ. 148–149 (2014) 114–122.
    [40]
    M. Wu, W. Zhan, Y. Guo, Y. Guo, Y. Wang, L. Wang, G. Lu, Appl. Catal. A Gen. 523 (2016) 97–106.
    [41]
    X. Cui, Y. Xu, L. Chen, M. Zhao, S. Yang, Y. Wang, Appl. Catal. B Environ. 244 (2019) 957–964.
    [42]
    X.J. Zhang, Z.A. Ma, Z.X. Song, H. Zhao, W. Liu, M. Zhao, J.G. Zhao, J. Phys. Chem. C 123 (2019) 17255–17264.
    [43]
    X.L. Zou, J.F. Chen, Z.B. Rui, H.B. Ji, Appl. Catal. B Environ. 273 (2020) 119071.
    [44]
    J.Y. Parka, Y. Zhang, S. Hoon Jooc, Y. Jung, G.A. Somorjai, Catal. Today 181 (2012) 133–137.
    [45]
    Z. Feng, M. Zhang, Q. Ren, S. Mo, R. Peng, D. Yan, M. Fu, L. Chen, J. Wu, D. Ye, Chem. Eng. J. 369 (2019) 18–25.
    [46]
    Z. Rui, C. Chen, Y. Lu, H. Ji, Chinese J. Chem. Eng. 22 (2014) 882–887.
    [47]
    K.-J. Kim, S.-I. Boo, H.-G. Ahn, J. Ind. Eng. Chem. 15 (2009) 92–97.
    [48]
    J. Zhang, C. Rao, H. Peng, C. Peng, L. Zhang, X. Xu, W. Liu, Z. Wang, N. Zhang, X. Wang, Chem. Eng. J. 334 (2018) 10–18.
    [49]
    M. Popova, Á. Szegedi, Z. Cherkezova-Zheleva, A. Dimitrova, I. Mitov, Appl. Catal. A Gen. 381 (2010) 26–35.
    [50]
    H.-F. Lu, Y. Zhou, W.-F. Han, H.-F. Huang, Y.-F. Chen, Catal. Sci. Technol. 3 (2013) 1480–1484.
    [51]
    T. Gan, X. Chu, H. Qi, W. Zhang, Y. Zou, W. Yan, G. Liu, Appl. Catal. B Environ. 257 (2019) 117943.
    [52]
    H. Wang, W. Yang, P. Tian, J. Zhou, R. Tang, S. Wu, Appl. Catal. A Gen. 529 (2017) 60–67.
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Get Citation
    PDF
    XML

    Article Metrics

    Article views (80) PDF downloads(46) Cited by()
    Proportional views

    Publish With GEE

    Contact

    • Email：gee@ipe.ac.cn
    • Tel：010-82627075
    • Address：North 2nd street, Zhongguancun, Haidian District, Beijing, China

    Links

    京ICP备10002620号-1京公网安备 11010802039050号

    Supported by: Beijing Renhe Information Technology Co. Ltd    

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return